• Title/Summary/Keyword: O:N ratio

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Effect of Styrene and Maleic Anhydride Content on Properties of PP/Pulp Composites and Reactive Extrusion of Random PP (랜덤 PP의 반응압출 및 PP/Pulp 복합체 특성에 대한 스티렌과 무수말레인산 함량의 영향)

  • Lee, Jong Won;Kim, Ji Hyun;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.318-323
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    • 2014
  • In order to analyze the effect of maleic anhydride (MAH) content and styrene monomer (SM)/MAH mole ratio on reactive extrusion of maleic anhydride grafted random polypropylenes (MAH-g-rPP), MAH-g-rPPs were prepared by using a twin screw extruder. MAH contents were 0.5, 1.0, 3.0, and 5.0 phr and SM/initiator mole ratio was 0.0, 1.0, and 2.0. Dicumyl peroxide (DCP) was used as an initiator. The graft degree of MAH was confirmed by the existence of carbonyl group (C = O) stretching peak at $1700cm^{-1}$ from FT-IR spectrum. The degree of graft reaction increased up to 3.0 phr MAH and showed the optimum value at 1.0 SM/MAH mole ratio from the area ratio of C = O and C-H stretching peak. Thermal and crystallization properties of MAH-g-rPP and PP/MAH-g-rPP/pulp composites were investigated by DSC, TGA, XRD, and POM. There was a decrease in non-isothermal crystallization temperature of PP/MAH-g-PP/pulp composites. Based on tensile properties and SEM pictures for the fractured surface of PP/MAH-g-PP/pulp composites, MAH content of 1.0 wt% and SM/MAH mole ratio of 1.0 were the optimum formulation as the compatibilizer. The rheological properties of the composites were measured by dynamic Rheometer to compare the processability of the composites with and without compatibilizer. The power law index showed slightly low value at the composites with compatibilizer.

Application of Geostatistical Methods for the Analysis of Groundwater Contamination in Pusan (부산지역 지하수 오염현황 분석을 위한 지구통계 기법의 응용)

  • 정상용;강동환;박희영;심병완
    • The Journal of Engineering Geology
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    • v.10 no.3
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    • pp.247-261
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    • 2000
  • The geostatistical analyses for the chemical components of pH, TS, KMnO4 Demand, Cl, SO$_4$ and NO$_3$-N are carried out to understand the groundwater contamination in Pusan. The average values of each component are 7.2 for pH, 336.4mg/$\ell$ for TS, 2.3mg/$\ell$ for KMnO$_4$ Demand, 44.3mg/$\ell$ for Cl, 36.0mg/$\ell$ for SO$_4$, and 4.6mg/$\ell$ for NO$_3$-N. The ratios over the drinking standard of each component are 0.34% for pH, 2.27% for TS, 1.55% for KMnO$_4$ Demand, 1.59% for Cl, 0.57% for SO$_4$, and 3.7% for NO$_3$-N. The highest ratio of NO$_3$-N results from the municipal sewage and exhaust gas of vehicles. The isopleth maps of 6 chemical components show that the high values of groundwater contamination come from the inland of Pusan, and that some high values appear at the coastal area. The isopleth maps of Cl and SO$_4$ related with seawater intrusion also show that the high values appear only at the particular coastal area, not at the whole area. On the isopleth maps of Cl and SO$_4$, the anomalies of the concentration contours were compared with the directions of two large fault zones, the Ilkwang Fault and the Dongrae Fault. Apparently, they don't have the particular correlation. Therefore, it is concluded that the main source of groundwater contamination in Pusan is not the seawater, but the municipal sewage and other sources such as the exhaust gas of vehicles, the contaminated surface water, the waste water of factories, and the leachate of waste landfills.

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Effect of Several Kinds of Composts on Growth Status of Aerial Parts in Ginseng Seedlings (유기질비료가 묘삼 지상부 생육에 미치는 영향)

  • Lee, Gab-Soo;Lee, Sung-Sik;Chung, Jae-Dong
    • Journal of Ginseng Research
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    • v.27 no.1
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    • pp.24-31
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    • 2003
  • This experiment were conducted to select cheaper and more favorable compost among several kinds of composts which were produced by companies, farmers etc. instead of Yakto. Yakto was similar to Standard Yakto in the content of inorganic salts, but PL and HJ composts contained more P$_2$O$\_$5/, K$_2$O, CaO and MgO content compared with Standard Yakto and EC in Yakto was also higher than Standard Yakto did, but the phosphorus, magnesium content and EC of Mushroom compost was higher than that of Standard Yakto. On the other hands, Rice straw compost contained higher contents of phosphorus, potassium and magnesium than Yakto did. Germination rate and early growth of lettuce and C/N ratio were tested for checking decomposed degree. The compost of HJ, Mushroom and Rice straw revealed higher C/N ratio, lower germination rate and shorter shoot length than Yakto showed. It was guessed that these composts were not decomposed enough. Emergence and survival rate of ginseng seeds in Yakto were the highest, but its germination in the composts of Mushroom, PL, HJ and Rice straw, in order, was decreased, and its survival rate in the composts of PL, Mushroom, HJ and Rice straw, in order, was decreased. It was concluded that fully decomposed manure should be used and it needs to Investigate perfect decomposed composts of PL and Mushroom instead of Yakto.

Gasification Study of Datong Coal in a Bench Scale Unit of Entrained Flow Gasifier (Datong탄에 대한 Bench Scale Unit급 분류층 석탄가스화 연구)

  • Ryu, Si-Ok;Kim, Jae-Ho;Lee, Hyo-Jin;Lee, Jae-Goo;Park, Tae-Jun;An, Dal-Hong;Park, Ho-Young
    • Journal of Energy Engineering
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    • v.6 no.1
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    • pp.96-103
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    • 1997
  • Coal gasification experiments were performed to characterize the bench scaled unit of 0.5∼1.0 T/D entrained coal gasifier developed by KIER. Datong coal from China was selected for this study. The system was operated at the temperature range of 1300∼1550$^{\circ}C$, with 62.5% of coal water mixture on the basis of dry coal. Oxygen and slurry mixture were preheated prior to feeding into burner and the ratio of oxygen/coal was in the range of 0.8∼1.2. In the preparation of coal water mixture, 0.3 wt% of CWM1002 and 0.05 wt% of NaOH wire added to reduce viscosity as well as to enhance theological properties of slurry. The resultant gaseous products consist primarily of hydrogen, carbon monoxide, carbon dioxide, and minor amounts of methane. Formation of H$_2$and CO was increased, while CO$_2$was decreased as the reacting temperature being increased due to the char-CO$_2$reaction. Maximum production of H$_2$and CO occurred in the O$_2$/coal ratio of 0.9 at 1530$^{\circ}C$. Heating values of product gases were in the range of 1700∼2400 kcal/N㎥.

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Nano-scale Patterning on Diamond substrates using an FIB (FIB를 이용한 다이아몬드 기판 위의 나노급 미세 패턴의 형상 가공)

  • Song, Oh-Sung;Kim, Jong-Ryul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.6
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    • pp.1047-1055
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    • 2006
  • We patterned nano-width lines on a super hard bulk diamond substrate by varying the ion beam current and ion beam sources with a dual beam field ion beam (FIB). In addition, we successfully fabricated two-dimensional nano patterns and three-dimensional nano plate modules. We prepared nano lines on a diamond and a silicon substrate at the beam condition of 30 kV, 10 pA $\sim$ 5 nA with $Ga^+$ ion and $H_2O$ assisted ion sources. We measured each of the line-width, line-depth, etched line profiles, etch rate, and aspect ratio, and then compared them. We confirmed that nano patterning was possible on both a bulk diamond and a silicon substrate. The etch rate of $H_2O$ source can be enhanced about two times than that of Ga source. The width of patterns on a diamond was smaller than that on a silicon substrate at the same ion beam power The sub-100 nm patterns on a diamond were made under the charge neutralization mode to prevent charge accumulation. We successfully made a two-dimensional, 240 nm-width text of the 300-lettered Lord's Prayer on a gem diamond with 30 kV-30 pA FIB. The patterned text image was readable with a scanning electron microscope. Moreover, three dimensional nano-thick plate module fabrication was made successfully with an FIB and a platinum deposition, and electron energy loss spectrum (EELS) analysis was easily performed with the prepared nano plate module.

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Effect of grading pattern and porosity on the eigen characteristics of porous functionally graded structure

  • Ramteke, Prashik Malhari;Panda, Subrata K.;Sharma, Nitin
    • Steel and Composite Structures
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    • v.33 no.6
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    • pp.865-875
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    • 2019
  • The current article proposed to develop a geometrical model for the analysis and modelling of the uniaxial functionally graded structure using the higher-order displacement kinematics with and without the presence of porosity including the distribution. Additionally, the formulation is capable of modelling three different kinds of grading patterns i.e., Power-law, sigmoid and exponential distribution of the individual constituents through the thickness direction. Also, the model includes the distribution of porosity (even and uneven kind) through the panel thickness. The structural governing equation of the porous graded structure is obtained (Hamilton's principle) and solved mathematically by means of the isoparametric finite element technique. Initially, the linear frequency parameters are obtained for different geometrical configuration via own computer code. The comparison and the corresponding convergence studies are performed for the unidirectional FG structure for the validation purpose. Finally, the impact of different influencing parameters like aspect ratio (O), thickness ratio (S), curvature ratio (R/h), porosity index (λ), type of porosity (even or uneven), power-law exponent (n), boundary condition on the free vibration characteristics are obtained for the FG panel and discussed in details.

Environmental factors Affecting Distribution of Heterotrophic Bacteria and Chlorophyll a Content in The (마산만과 행암만 수층의 종속양양세균과 엽록소 a 함량 분포에 미치는 환경요인)

  • Sohn Jae-Hak;Ahn Tae-Young;Kim Sang -Jin
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.4
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    • pp.65-75
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    • 2000
  • The roles of environmental factors affecting on heterotrophic bacterial distribution at Hangam Bay and Masan Bay in which occurred frequently red tide, during June to November 1996 were investigated. The aquatic environment of Masan Bay and Haengam Bay showed difference in the contents of inorganic nutrients. Haengam Bay may be defined as nitrogen limited aquatic environment. On the other hand, Masan Bay appeared to the appropriate N/P molar ratio of mean 15.9 during the periods of study. By the results of simple regression, chlorophyll a showed significant correlation with precipitation (r=0.813, P<0.05) and phosphorus (r=0.846, P<0.05) at Haengam Bay, but not showed significant correlation with parameters at Masan Bay. The heterotrophic bacteria showed significant correlation with many environmental parameters at Masan Bay (Precipitation, r=0.990, P<0.01 : NO₃-N, r=0.901, P<0.05 : Dissolved inorganic nitrogen, r=0.899, P<0.05 ; N/P molar ratio, r=0.952, P<0.05 : Salinity, r: -0.934, P<0.05) than Haengam Bay (SiO₃-Si, r=0.960, P<0.01). By the results of multiple regression, the chlorophyll a was varied with only 2 factors in Masan Bay (R²=0.100) and 3 factor in Haengam Bay (R²=0.903). The major factor which affected to chlorophyll a was SiO₃-Si (R²%=67.8) in Masan Bay, and -N/P (R²%=37.6) in Haengam Bay. The heterotrophic bacteria were varied with 4 factors in Masan Bay (R²=100) and 2 factor in Haengam Bay (R²%=0.878). The major factor, which affected to heterotrophic bacteria, was SiO₃-Si (R²%=42.3) and salinity (R²%=32.1) in Masan Bay, and SiO₃-Si (R²%=76.3) in Haengam Bay. Resultingly, the influx of freshwater in Masan and Haengam Bay was enriched in inorganic nutrients, and plays an important role in the change of heteroterophic bacteria and chlorophyll a during early summer to autumn.

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Studies on the Development of Bearing Capacity Reinforcement for the Foundation of Soil (기초지반의 지지력보강공법에 관한 연구)

  • 유동환;최예환;유연택
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.30 no.1
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    • pp.38-49
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    • 1988
  • This paper presented as follows results of laboratory model tests with various shaped footings on soil bed reinforced with the strips on the base of behaviour of soil structure according to the loads and triaxial test results reinforced with geotextiles. Their parameters studied were the effects on the bearing capacity of a footing of the first layer of reinforcement, horizontal and vertical spacing of layers, number of layers, tensile strength of reinforcement and iclination load to the vertical 1.Depending on the strip arrangement, ultimate bearing capacity values could be more improved than urreinforced soil and the failure of soil was that the soil structure was transfered from the macrospace to microspase and its arrangement, from edge to edge to face to face. 2.The reinforcement was produced the reinforcing effects due to controlling the value of factor of one and permeable reinforcement was never a barrier of drainage condition. 3.Strength ratio was decreased as a linear shape according to increment of saturation degree of soil used even though at the lower strength ratio, the value of M-factor was rot influenced on the strength ratio but impermeable reinforcement decreased the strength of bearing capacity. 4.Ultimate bearing capacity under the plane-strain condition was appeared a little larger than triaxial or the other theoretical formulars and the circular footing more effective. 5.The maximum reinforcing effects were obtained at U I B=o.5, B / B=3 and N=3, when over that limit only acting as a anchor, and same strength of fabric appeared larger reinforcing effects compared to the thinner one. 6.As the LDR increased, more and more BCR occurred and there was appeared a block action below Z / B=O.5, but over the value, decrement of BCR was shown linear relation, and no effects above one. 7.The coefficient of the inclination was shown of minimum at the three layers of fabrics, but the value of H / B related to the ultimate load was decreased as increment of inclination degree, even though over the value of 4.5 there wasn't expected to the reinforcing effects As a consequence of the effects on load inclination, the degree of inclination of 15 per cent was decreased the bearing capacity of 70 per cent but irnproved the effects of 45 per cent through the insertion of geotextile.

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Characteristics of the Pressure Instability in a Hydrazine Thruster with Various Length-to-Diameter Ratio of Catalyst-bed (하이드라진 추력기의 촉매대 길이직경비에 따른 압력 불안정 특성)

  • Jung, Hun;Kim, Jong Hyun;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.18 no.6
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    • pp.19-26
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    • 2014
  • A ground hot-firing test (HFT) was carried out to make a close examination into the pressure instability for the 70 N-class hydrazine thruster under development. Monopropellant grade hydrazine was adopted as a propellant for the HFT, and catalyst-bed was filled with $Ir/Al_2O_3$ catalyst. In order to investigate the effects of thrust-chamber diameter on combustion stability, evaluation tests for the development models were performed on three kinds of lower thrust chambers having the length-to-diameter ratio (L/D) of 1.03, 1.13, and 1.26. As results, it was found that low frequency instability (~ 50 Hz) was inherent in the models, and in addition, increase of the L/D and decrease of the operating pressure led to an amplification of pressure oscillation in the test condition specified.

The Properties of Livestock Waste Composts Tea Depending on Manufacturing Method and Their Effect on Chinese Cabbage Cultivation

  • Jang, Jae-Eun;Kang, Chang-Sung;Park, Jung-Soo;Kim, Sun-Jae;Kim, Hee-Dong
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.1
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    • pp.8-14
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    • 2015
  • Livestock waste compost tea is a liquid extract of compost obtained by mixing livestock compost. In this study, some chemical and microbiological characteristics of compost tea depending on the kind of raw materials used were examined, and several experiments to investigate the practical effects on Chinese cabbage cultivation were conducted. This experiment showed that livestock composts needed to be added into aerated water at the ratio between 1:100 and 1:10 (1 part compost to 10~100 parts water) to produce the high quality compost tea. Compost teas must be aerated more than 24 to 48 hours to be able to support aerobic organisms. In cultivation test with compost teas, swine manure compost teas were made by the extracting ratio of 50x, in the aerated condition for 24 hours in water and oil cake in the extracting ratio of 100x were added as supplements. Following the input of oil cake, the concentration of nitrogen and aerobic bacteria increased. Another experiment was conducted to determine the effect of different swine manure compost teas on plant growth and yield of Chinese cabbage. The fresh yield of Chinese cabbage was higher in the fertigated plots by compost tea with oil cake compared to those of N, $P_2O_5$, $K_2O$ fertilization plot with chemical fertilizer by soil test recommendation (Fert. NPK). The effect of compost tea on growth of Chinese cabbage was largely attributable to the increased number of microorganisms as well as nutrients.