• Title/Summary/Keyword: O:N ratio

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Retrieval of LIDAR Aerosol Parameter Using Sun/Sky Radiometer at Gangneung, Korea

  • Shin, Sung-Kyun;Lee, Kwon-Ho;Lee, Kyu-Tae
    • Current Optics and Photonics
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    • v.1 no.3
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    • pp.175-185
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    • 2017
  • The aerosol optical properties such as depolarization ratio (${\delta}$) and aerosol extinction-to-backscatter ratios (S, LIDAR ratio) and ${\AA}ngstr{\ddot{o}m$ exponent (${\AA}$) derived from measurement with AERONET sun/sky radiometer at Gangneung-Wonju National University (GWNU), Gangneung, Korea ($37.77^{\circ}N$, $128.87^{\circ}E$) during a winter season (December 2014 - February 2015) are presented. The PM concentration measurements are conducted simultaneously and used to identify the high-PM events. The observation period was divided into three cases according to the PM concentrations. We analysed the ${\delta}$, S, and ${\AA}$ during these high PM-events. These aerosol optical properties are calculated by the sun/sky radiometer data and used to classify a type of aerosols (e.g., dust, anthropogenic pollution). The higher values of ${\delta}$ with lower values of S and ${\AA}$ were measured for the dust particles. The mean values of ${\delta}$, S, and ${\AA}$ at 440-870 nm wavelength pair (${\AA}_{440-870}$) for the Asia dust were 0.19-0.24, 36-56 sr, and 0.48, respectively. The anthropogenic aerosol plumes are distinguished with the lower values of ${\delta}$ and higher values of ${\AA}$. The mean values of spectral ${\delta}$ and ${\AA}_{440-870}$ for this case varied 0.06-0.16 and 1.33-1.39, respectively. We found that aerosol columnar optical properties obtained from the sun/sky radiometer measurement are useful to identify the aerosol type. Moreover, the columnar aerosol optical properties calculated based on sun/sky radiometer measurements such as ${\delta}$, S, and ${\AA}$ will be further used for the validation of aerosol parameters obtained from LIDAR observation as well as for quantification of the air quality.

The effect of composition ratio on the surface morphology and superconducting properties of SmBCO films prepared by thermal co-evaporation method (동시 열증발법으로 제조한 SmBCO 고온 초전도에서 박막 조성비가 표면형상 및 초전도 특성에 미치는 영향)

  • Lee, N.J.;Kim, H.S.;Ha, H.S.;Ko, R.K.;Song, K.J.;Ha, D.W.;Yang, J.S.;Kim, T.H.;Jeong, Y.H.;Youm, D.J.;Moon, S.H.;Park, C.;Oh, S.S.
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.1
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    • pp.5-8
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    • 2007
  • We have investigated the superconducting properties and surface morphology of $Sm_xBa_yCu_3O_{6+z}$ thin films deposited on LMO/IBAD-MgO/Hastelloy which prepared with different composition ratio by co-evaporation method(EDDC, Evaporation using Drum in Dual Chambers). We observed the composition ratio of SmBCO thin films by EDS analysis. We fabricated SmBCO thin film with critical current density of $1.5{\times}10^6A/cm^2$ at composition ratio of SM:Ba:Cu=1.10:2.01:3(at 77 K self-field). And, we confirmed that substitution of Sm-Ba did not occur at Cu rich phase by EDS analysis.

Enhanced Tumor-targeted Gene Delivery by Immunolipoplexes Conjugated with the Humanized Anti-TAG-72 Fab' Fragments

  • Kim, Keun-Sik;Park, Yong-Serk;Hong, Hyo-Jeong;Kim, Kwang-Pyo;Lee, Kwang-Hyun;Kim, Dong-Eun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.651-656
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    • 2012
  • Cationic immunoliposomes were prepared by conjugation of Fab' fragments of the recombinant humanized monoclonal antibody (HuCC49) against tumor-associated glycoprotein (TAG)-72 to sterically unilamella liposomes. The cationic immunoliposomes are composed of cationic lipid (O,O'-dimyristyl-N-lysyl aspartate, DMKD), cholesterol, and 1,2-dipalmitoyl-sn-glycero-3-phosphoethanolamine-N-[maleimide(polyethyleneglycol)$_{2000}$] (DPPE-PEG-maleimide) with a molar ratio of 0.5:0.47:0.03. Plasmid DNA was effectively condensed by addition of transferrin (Tf) during the formation of anti-TAG-72 PEG-immunolipoplexes (PILPs). These anti-TAG-72 PILPs were able to adhere to the surface of TAG-72-overexepressing LS174T human colon cancer cells more effectively than conventional liposomes, thereby facilitating gene delivery in vitro. Furthermore, intravenous administration of the anti-TAG-72 PILPs into the tumor-carrying mice exhibited efficient localization of the reporter gene in the tumor tissues.

Factors influencing the prognosis after total correction of tetralogy of Fallot (Fallot 4징증의 근치수술후 예후에 영향을 미치는 요소)

  • Min, Yong-Il;O, Bong-Seok;Lee, Dong-Jun
    • Journal of Chest Surgery
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    • v.20 no.1
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    • pp.71-80
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    • 1987
  • Twenty six patients were operated a total correction of tetralogy of Fallot between Jan., 1984 and July, 1985 at the Dept. of thoracic and cardiovascular surgery, Chonnam University Medical School, and a comparison between the survived group [n = 18] and the dead group [n = B was performed to detect factors influencing laboratory data, cineangiographic findings, operative findings and methods, and pump time. Following results were obtained, 1. There was no significant difference between two groups in the preoperative P.O2 and hematocrit level. 2. The size of the interventricular defect was not related to the operative mortality. 3. There was a significant difference in mortality rate between combined type of stenosis of pulmonary artery, valve and infundibulum and other types of right ventricular outflow tract stenosis. 4. There was a significant difference in mortality rate between the transannular patch reconstruction and other types of operative procedure. 5. There was no significant difference between two groups in total bypass time and aortic time. 6. There was no significant difference between two groups in left ventricular end diastolic volume and right ventricular end diastolic volume. 7. The operative mortality was related to the ratio of the diameter of the pulmonary valve annulus or each pulmonary artery to the ascending or descending aorta in cineangiographic findings, but there was no statistical significance of which probably is due to the lack of the total number of patients.

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Effect of Chitosan and N. O-Carboxymethyl Chitosan of Different Sources and Molecular Weights on Lipid Metabolism (급원과 분자량이 다른 Chitosan 과 N, O-Carboxymethyl Chitosan이 지방대사에 미치는 영향)

  • 배계원
    • Journal of Nutrition and Health
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    • v.30 no.7
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    • pp.770-780
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    • 1997
  • This study was performed to investigate the effect of chitosan and NOCC from different sources and of different molecular weights on lipid metabolism. Sprague-Dawley rats were blocked into 26 groups according to body weight, and were raised for 4 weeks. Cadmium chloride was given at the level of 0 or 400 ppm in diet. Various chitosan and NOCC sources were given at the level of 0%(w/w) of diet. Total serum cholesterol and serum triglyceride concentrations were little affected by chitosan and NOCC supplements. However, HDL-cholesterol concentration and HDL : total cholesterol ratio were increased , and liver lipid, cholesterol , and triglyceride concentration were decreased by chitosan and NOCC supplements. The cholesterol and lipid lowering activity depends on fiber sources(crab and shrimp); type (chitosan and NOCC); and molecular weight(low , medium , and high). Among cadmium-free groups, chitosan-fed groups showed greater activity than NOCC -fed groups in lowering cholesterol and lipid levels, and greater fecal excretion of lipids and bile acids. Crab chitosans were more effective in cholesterol and lipid lowering activity than shrimp chitosans. The group fed high molecular weight crab chitosan showed the highest fecal excretion of lipids and bile acids. This indicated that high molecular weight crab chitosan was most effective in interfering with cholesterol and lipid absorption.

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Physicochemical properties of Ginkgetin and Isoginkgetin extracted from Ginko leaves (은행잎 추출물 유래 Ginkgetin 및 Isoginkgetin의 융복합 특성 연구)

  • Min, Kyung-Nam
    • Journal of the Korea Convergence Society
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    • v.9 no.6
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    • pp.89-98
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    • 2018
  • To confirm the feasibility as raw materials for cosmetic formulation, ethanol, n-hexane, ethylacetate and normal butyl alcohol were extracted from 1kg of Ginko leaves. Ultimately, investigated chemical structure and physicochemical properties of ginkgetin and isoginkgetin. The purity of those two components have been evaluated higher than 99%. They are isomers with molecular weight as 566 and a molecular formular, $C_{32}H_{22}O_{10}$. Flavonoid's frame and NMR spectrum exhibited the existence of aromatic proton and the proper ratio of the carbon, which were expected structures exactly corresponded to the reported references.

Effects of Functional Ingredients Supplementation as a Bulking Agent in Composting of Swine Manure (돈분의 퇴비화에 있어 악취 제거 기능성 물질의 첨가 효과)

  • 이상환;김인호;홍종욱;권오석;김정우
    • Korean Journal of Organic Agriculture
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    • v.9 no.4
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    • pp.113-121
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    • 2001
  • This study was conducted to evaluate the effects of functional ingredients with supplementation as a bulking agent in composting of swine manure. Treatments were T1 & T5 ; Swine mature+Vermiculite, T2 & T6 ; Swine manure+Perlite, T3 & T7 ; Swine manure+Vermiculite+Perlite, T4 & T8 ; Swine manure+Bark. T1, T2, T3 and T4 were supplemented with functional ingredients on d 0 of composting, T5, T6, T7 and T8 were supplemented with functional ingredients on d 3 of composting. Functional ingredients were Fermkito and Yucca. During the composting period, changes of temperature were showed traditionally composting trend. Volatile fatty acids were decreased regardless of treatments in functional ingredients supplementation. Organic matter, T-N and C/N ratio were showed higher bark treatments than other treatments. pH and EC were net differences among the treatments. P$_2$O$_{5}$ and $K_2$O were showed level of 1-3%. In heavy metal, Cr were showed higher in vermiculite treatment than other treatments. In conclusion, vermiculite and perlite treatments were greater composting effects than bark.

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Copper(II) Coordination Polymers Assembled from 2-[(Pyridin-3-ylmethyl)amino]ethanol: Structure and Magnetism

  • Han, Jeong-Hyeong;Shin, Jong-Won;Min, Kil-Sik
    • Bulletin of the Korean Chemical Society
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    • v.30 no.5
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    • pp.1113-1117
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    • 2009
  • The one-dimensional coordination polymers, $[Cu^{II}(L)(NO_3)_2]_n$ (1) and {$[Cu^{II}(L)(NO_3)]{\cdot}2H_2O}_{2n} (2), were synthesized from $Cu(NO_3)_2{\cdot}3H_2O$ and 2-[(pyridin-3-ylmethyl)amino]ethanol (L, PMAE) in methanol by controlling the molar ratio of copper(II) salt. Copper(II) ion in 1 has one pyridine group of PMAE whose an aminoethanol group coordinates adjacent copper(II) ion. As the pyridine group is bonded to neighboring copper(II) ion, 1 becomes a one-dimensional chain. Contrary to 1, the structure of 2 shows that the oxygen atom of ethoxide group is bridged between two copper(II) ions, which forms a dinuclear complex. Additionally, the pyridine group of PMAE included one dinuclear unit is coordinated to the other dimeric one each other, which leads to a one-dimensional polymer. Due to the structural differences, 1 exhibits weak antiferromagnetic interaction, while 2 shows strong antiferromagnetic interaction. Due to direct spin exchange via oxygen of PMAE 2 has a much strong spin coupling than 1.

CHEMICAL ABUNDANCE ANALYSIS OF M31 AND M33 BASED ON THE SPECTRUM OF HII REGIONS (HII 영역 분광자료를 통한 M31과 M33의 화학원소 결정)

  • HAN SOO RYEON;HYUNG SIEK;PARK HONG-SUH;LEE WOO-BAlK
    • Journal of The Korean Astronomical Society
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    • v.34 no.2
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    • pp.67-80
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    • 2001
  • Chemical evolution of galaxies can be understood by studying the spatial distribution of heavy elements. We selected two nearby galaxies, M31 and M33 and investigated spectrum of their HII regions: a) the elec-tron densities have been derived from the [S II] 6717/6731 ratio along with the most recent atomic constants (Hyung & Aller 1996); b) the electron temperatures were determinated from the Pagel's empirical method. Nebula Model (Hyung 1994) has been employed to predict the spectral line intensities which gives the proper chemical abundances. The model would predict the line intensities correctly only when various input parameters such as the effective central star temperatures, gravity log g, model atmosphere as well as the geometry and the nebula physical condition are appropriate. Thus, the determination of chemical abundances of O, S, N of the two nearby galaxies M31 and M33 has been done, which shows a radial dependance of O/H and N/H: decrease with the distance, or increasing electron temperature due to the elemental deficiency. Abundances of M31 appear to be enhanced than those of M33.

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A Study on Characteristics of Insulation Breakdown and Surface Discharge by the Oxygen Concentration in the Dry Air in Quasi-Uniform Field (준평등전계중 Dry Air내 산소의 농도에 따른 절연파괴 및 연면방전 특성 연구)

  • Beak, Jong-Hyun;Seok, Jeong-Hoo;Choi, Byoung-Ju;Bae, Sungwoo;Kim, Ki-Chai;Park, Won-Zoo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.11
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    • pp.41-46
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    • 2015
  • This study was conducted to discover a substitute of $SF_6$ gas. $SF_6$ gas is widely used across the industries. Thanks to superior electrical properties, in particular, it has been commonly used in electrical industry. However, there have been a lot of studies on its serious effect on global warming. As a substitute of this synthetic gas, a mixture of dry air and $N_2/O_2$ was chosen in this study. In case of $N_2/O_2$, dielectric strength differs depending on the mixing ratio. This study examined dielectric breakdown and flashover after adjusting oxygen percentage in the dry air. This test was conducted in a quasi-uniform electric field depending on pressure, oxygen concentration and gas mixtures. The test results found that dielectric voltage and flashover voltage were the highest at a certain oxygen concentration. It is the results of this photoionization and electron attachment of oxygen.