• Title/Summary/Keyword: Nylon66

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Market Trend of PET & Nylon Film (PET 필름 및 NYLON 필름 수급 동향)

  • Korea Packaging Association INC.
    • The monthly packaging world
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    • no.8 s.184
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    • pp.66-69
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    • 2008
  • 원자재 가격상승과 유가 폭등으로 인해 국내 폴리에스터 업계는 중국 제품에 가격 경쟁력이 밀리는 범용 제품 비중을 줄이고 부가가치가 높은 광학 및 특수용도 제품 비중을 높여나가는 등의 노력에 주력하고 있다. 유가 인상과 단가 하락 압력, 경쟁 격화 등으로 포장재 등에 쓰이는 범용 PET 필름은 물론 확산필름 등 일반 LCD용 광학필름의 수익성이 낮아지면서 수익성이 좋은 분야의 비중을 확대하려는 움직임에 따라 올해 폴리에스터(PET) 필름 업계의 화두는 광학 및 태양전지에의 PET 필름의 적용 및 응용이었다. SKC가 먼저 광학필름의 원자재로 쓰이는 고순도 후막 베이스필름이나 태양전지나 하이브리드 자동차 부품용 필름 분야로 진출을 계획중이며 코오롱도 후막 필름 라인을 1기 증설하고 기존 포장재 라인도 전환키로 했다. 또한 도레이새한도 후막 필름을 주력제품으로 끌어올릴 계획을 갖고 있다. 본 고에서는 PET 필름 및 나일론 필름 수급동향을 살펴보고, 업체별 상황 및 전망을 살펴보도록 한다.

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Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin - (II) The Effects of Terpene Resin - (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능향상 - (II) 테르펜수지의 영향 -)

  • Chung, Kyung-Ho;Hong, Young-Keun;Chun, Young-Sik
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.226-231
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    • 1998
  • Hot melt adhesive which is solventless type has been widely used due to the possibility of automated adhesion process. The main purpose of this study is the development of polyamide based hot melt adhesive to improve the property of conventional ethylene-vinyl acetate hot melt adhesive, which has an inherent problem against heat resistance. In this study, it was found that the terpolymers of nylon 6, nylon 66, and nylon 12(CM831, 843P types) instead of nylon homopolymer were suitable base resins for hot melt adhesive, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. According to the results, the optimum adhesion property could be obtained by the using 75/25~50/50 weight radio of CM831/843P resin as a base resin. Terpene resin was used as tackifier to improve adhesion and wetting properties. The best result can be obtained with the 10 wt.% addition of terpene resin. The terpene resin acted as proper tackifier in this system which decreased the melt temperature and viscosity, but increased the mechanical strength of adhesive itself. Also, the rheological property of the adhesive changed from typical non-Newtonian behavior to Newtonian behavior as terpene resin was added.

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Adhesion Properties of Rubber Composite with Direct Blending Technique and Adhesive Composition (직접블렌딩 기술과 접착제 조성이 고무복합체 물성에 미치는 영향)

  • Lee, Seong-Jae;Chang, Young-Wook;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.34 no.3
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    • pp.253-261
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    • 1999
  • The cure properties of rubber compounds containing different adhesive compositions were examined. As the amounts of tannin were increased in the adhesive composition, the scorch time was increased and cure rate was decreased due to the size and shape of tannin molecules. Also, the effect of adhesive composition on the adhesion between rubber and fiber was examined by TCAT(Tire Cord Adhesion Test), The reinforcing cords used in this study were mon ofilaments of nylon 610 and nylon 66. According to the results, the optimum adhesion strength between rubber and fiber could be obtained with adhesives whose molar ratios of formaldehyde/resorcinol were above 5/1 in the recipes. Although the level of dip pick-up(DPU) on the reinforcing cord affects the adhesion strength, the DPU of nylon 610 monofilament did not affect the adhesion strength because the level of DPU was constant regardless of the adhesive compositions. In this case, the adhesion strength with the adhesive composition could be explained with the behavior of tannin in the adhesive.

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Effects of steam heat treatment conditions on the swelling and physical properties of PBS (polybutylene succinate) copolymer monofilament gill net (습식 열처리 조건이 PBS 공중합체 모노필라멘트 그물감의 부풀음 및 물성변화에 미치는 영향)

  • Park, Seongwook;Kim, Seonghun;Do, Choonho;Lim, Jihyun;Choi, Haesun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.50 no.3
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    • pp.274-283
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    • 2014
  • Swelling of the heat-treated netting for gillnet was estimated through the netting height in square acrylic tank. Experimental Nylon netting and PBSAT netting were heat-treated by using the high-degree vacuum method in hot water after net making. Heat-treatment temperatures were conducted with Nylon netting $105^{\circ}C$ and PBSAT netting $62^{\circ}C$, $65^{\circ}C$, $66^{\circ}C$, $67^{\circ}C$. The swelling measurement method of a netting using the square tank was capable of the reduction measurement errors comparing with measurement methods of a mesh inner angle and the shortening rate of a mesh size. In addition, this method was available to comparison evaluation for each netting more easily. Wet type heat-treatment apparatus with high-degree vacuum was shown higher $7{\sim}8^{\circ}C$ inner side temperature than a setting temperature. The tensile strength and elongation of Nylon netting and PBSAT netting were shown higher wet condition than dry condition. The tensile strengths of PBSAT monofilaments in dry and wet condition were sharply decreased at heat-treatment temp. $75^{\circ}C$ than heat-treatment temp. $74^{\circ}C$.

Assessment of Radiation Degradation of Insulating Materials using Thermogravimetry Analysis (열중량 분석에 의한 유기절연재료의 방사선 열화 평가)

  • Kim, K.Y.;Ryu, B.H.;Lee, C.;Lim, K.J.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1537-1539
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    • 2001
  • The radiation degradation of five insulating materials such as silicone rubber, ethylene-propylene rubber polybutylene terephthalte, poly carbonate, nylon 66 were evaluated by using thermogravimetry analysis (TGA) and tensile properties as a function of radiation doses. The results of temperature at 5% weight loss and activation energy from TGA showed linearly decreasing and increasing tendency as radiation doses comparing with tensile properties. Consequently, the assessment of TGA for the radiation degradation of materials was effective.

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The Influence of Interphase Condition on Mechanical Properties of Short-Fiber Reinforced Rubber (계면상 조건이 단섬유 강화고무의 기계적 성질에 미치는 영향)

  • Ryu, Sang-Yeol;Lee, Dong-Ju
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.3 s.174
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    • pp.625-633
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    • 2000
  • The mechanical and curing properties of short nylon66 fiber reinforced Chloroprene rubber have been investigated as functions of interphase conditions and fiber content. The tensile strength exhibits a dilution effect at a low fiber content in each interphase. It is found that the interphase conditions have an important affect on the dilution ratio and critical fiber content. Double coatings of bonding agent 402 and rubber solution become the best interphase model in this study. The yield strength, tensile modulus, tear strength and fracture toughness at rupture, Jr are significantly improved due to fiber concentration.

The Fracture Toughness and Crack Propagation behavoir of Short-fiber Reinforced Ruber (단섬유 강화고무의 파괴인성 및 크랙진전 거동)

  • Ryu, Sang-Ryeoul;Lee, Dong-Joo
    • Proceedings of the KSME Conference
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    • 2000.04a
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    • pp.85-90
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    • 2000
  • The fracture toughness and crack propagation behaviors of short nylon66 fiber reinforced Chloroprene rubber nave been Investigated as functions of fiber aspect ratio, fiber content and interphase conditions. The J for crack initiation and rupture were determined for short-fiber reinforced rubber. The values of $J_c$ for most reinforced rubbers were low compared that of matrix. But, $J_r$ at rupture showed a higher value than that of matrix. The crack propagation behaviors were analyzed into 3 patterns with increasing fiber aspect ratio and fiber content. The tearing mechanisms of matrix and fiber reinforced rubber were observed by CCD camera focused on the tip of crack and load-displacement graph. Both cases showed a completely different behaviors

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Development of Engineering Plastic Gear Based on Injection Molding Process (사출성형공정에 의한 엔지니어링 플라스틱 기어 개발)

  • Min, Byeong-Hyeon
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.8
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    • pp.71-78
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    • 1999
  • The application range of injection molded parts is expanding by the development of engineering plastics with good mechanical properties. Plastic gears are specially used as automotive parts due to an excellent performance in the characteristics of a strength vs. weight, and the study of injection molding process of plastic gear using Nylon66 is performed in this study. Filling, packing and cooling analyses were done by using the simulation software like Moldflow, and a mold was designed by following the simulation results. Pin-point gates with three points were taken to satisfy the design guides like a full-shot, and lower clamping force and uniform shrinkage. Characteristics of shrinkage of molded gear and temperature difference between cavity and core sides of a mold were shown.

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Lifetime Prediction of Automotive Airbag Fabrics (자동차 에어백용 원단의 수명예측)

  • Koo, Hyun-Jin;Cho, Hang-Won;Chang, Gap-Shik
    • Journal of Applied Reliability
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    • v.9 no.4
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    • pp.319-329
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    • 2009
  • The airbag module is an inflatable restraint system that inflates within 0.05 seconds automatically in a collision to protect the occupants. The airbag fabrics used in the module are required to have the good resilience and strength and also to have retained at least 80% of mechanical properties after using longer than 10 years. In this study, we develop an accelerated test method in order to predict the lifetimes of airbag. In this test, we select temperature and humidity as environmental stresses by analyzing the failure mechanisms of coated and uncoated nylon 66 fabrics. It is found that the degradation of airbag fabrics is effectively accelerated under the combined conditions of high temperature and humidity. Analyzing the results of the accelerated test, the lifetimes of airbag fabrics are predicted to be longer than 10 years.

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Evaluation of Impact Resistance Performance of Fiber Reinforced Preplace Grout Mortar (섬유를 혼입한 프리플레이스 모르타르의 내충격 성능 평가)

  • Lee, Sang-Gyu;Kim, Gyu-Yong;Choe, Gyeong-Cheol;Kim, Hong-Seop;Lee, Young-Wook;Hwang, Eui-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.65-66
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    • 2015
  • In this study, it evaluate mecahnical performance and impact resistance performance of fiber reinforced concrete, fiber reinforced mortar and preplace grout mortar. steel fiber, nylon fiber and polypropylene fiber are reinforced 1vol.% 2vol.% 10vol.% by each fiber type. It evaluate impact resistance performance to use projectile 10mm of 400m/s velocity. As a result, mechnical performance and impact resistance performance of fiber reinforced preplace grout mortar are improved a lot by 10% fiber reinforced ratio.

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