• Macromolecular Research
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• 제12권1호
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• pp.119-126
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• 2004

In this study, the influence of silane coupling agents, featuring different organo-functional groups on the interlaminar and thermal properties of woven glass fabric-reinforced nylon 6 composites, has been by means of short-beam shear tests, dynamic mechanical analysis, scanning electron microscopy, and thermogravimetric analysis. The results indicate that the fiber-matrix interfacial characteristics obtained using the different analytical methods agree well with each other. The interlaminar shear strengths (ILSS) of glass fabric/nylon 6 composites sized with various silane coupling agents are significantly improved in comparison with that of the composite sized commercially. ILSS of the composites increases in the order: Z-6076 with chloropropyl groups in the silanes > Z-6030 with methacrylate groups> Z-6020 with diamine groups; this trend is similar to that of results found in an earlier study of interfacial shear strength. The dynamic mechanical properties, the fracture surface observations, and the thermal stability also support the interfacial results. The improvement of the interfacial properties may be ascribed to the different chemical reactivities of the reactive amino end groups of nylon 6 and the organo-functional groups located at the ends of the silane chains, which results from the increased chemical reactivity in order chloropropyl > methacrylate > diamine.

• 한국의류산업학회지
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• 제15권3호
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• pp.437-443
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• 2013

This paper investigates the physical properties of aramid and aramid/nylon hybrid air jet textured filaments for protective garments relative to ATY nozzle diameters. Three types of para-aramids(840d, 1,000d, 1,500d) and nylon(420d) filaments were prepared; in addition, 840d aramid/420d nylon and three kinds of aramid filaments were texturized with a variation of air jet nozzle diameters(0.6, 0.75, 1 and 1.2 mm) on the AIKI air jet texturing machine. The measured physical properties of 16 specimens are as follows. The linear densities of aramid and aramid/nylon hybrid ATY increased with a larger nozzle diameter. The tenacity and initial modulus of aramid and hybrid ATY linearly decreased with a larger nozzle diameter; in addition, the breaking strain increased with the nozzle diameter. The dry and wet thermal shrinkage of hybrid ATY increased with a larger nozzle diameter from 0.6 mm to 1 mm and then decreased at a nozzle diameter of 1.2 mm (which seems to be a critical diameter). The wet and dry thermal shrinkage of aramid/nylon hybrid ATY are influenced by the nylon part of the hybrid yarns because the wet and dry thermal shrinkages of aramid ATY are less than 0.2%. The instabilities of aramid and aramid/nylon hybrid ATY were not influenced by the air jet nozzle diameter; however, they increased with the linear density of ATY.

• Fibers and Polymers
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• 제5권3호
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• pp.225-229
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• 2004

The effect of UV and $^60{Co}$ gamma radiations on the physical and mechanical properties of nylon 6 mono-filaments with different draw ratios has been studied. Specimens were exposed to either up to 25 Mrad of gamma or up to 168 hrs of intense UV irradiation. The results show that nylon mono-filaments exposed to gamma rays, with much higher quantum energy than UV, undergo a larger extent of molecular chain scission. Higher irradiation dose also results in the production of insoluble, macroscopic three-dimensional cross-linked network structure. The amorphous regions with a lower density of cohesive energy (lower molecular orientation) show a higher extent of cross linking reaction whereas amorphous regions with a higher density of cohesive energy (higher orientation) show higher extent of chain scission reaction, irrespective of UV ray or gamma ray irradiation.

• 한국식품저장유통학회지
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• 제6권4호
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• pp.351-356
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• 1999

CA 저장 사과로 제조한 신선절단 사과의 비타민 C 강화와 품질유지기간을 연장하기 위한 방법을 개발하기 위한 일환으로 신선절단 사과를 10% L-ascorbic acid 용액에 침지처리하고 0.03 mm LDPE, 0.04 mm PP 및 0.08 mm Nylon/PE(질소치환) 필름으로 포장하여 1$0^{\circ}C$에서 저장하면서 포장내 기체농도와 품질변화를 조사하였다. 저장 중 포장내 산소는 Nylon/PE 포장구에서 가장 낮게 l~3%로 유지되었고 다음으로 PP, LDPE 포장구 순이었다. 저장초기 포장내 에틸렌 농도의 증가속도는 Nylon/PE 포장구에서 가장 낮았다. 신선절단 사과의 비타민 C 함량은 241mg/100g으로 강화되었으며, 저장 중에는 저산소 조성 포장조건일수록 ascorbic acid 산화를 억제시켜서 Nylon/PE 포장구에서 가장 높게 유지되었다. 절단사과에서 갈변은 저산소 조성 포장조건일수록 억제하는 경향이었으며 LDPE, PP 및 무포장 절단사과는 저장 6일 후부터 발생되었으나 Nylon/PE 포장 절단사과는 저장 14일 후까지도 발생되지 않았다. 절단사과에서 부패와 이취는 LDPE, PP 및 무포장에서는 저장 9일 후에 인지되었으나 Nylon/PE 포장에서는 저장 14일 후까지도 인지되지 않았다. 이상의 결과에서 볼 때 장기간 CA 저장한 사과로 비타민 C 함량이 강화된 신선절단 사과의 제조가 가능하였고 이의 품질유지에 적합한 포장조건은 산소투과도가 낮은 포장재와 산소 제거 후 밀봉하는 것으로 나타났다.

• Nuclear Engineering and Technology
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• 제8권3호
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• pp.159-168
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• 1976

Ceric 염과 ${\gamma}$-선을 계기로 하여 Nylon 직포에 Acrylic acid를 접목반응 시켰다. 접목반응된 Polyacrylic acid의 분자량 분포를 측정한 결과 양 평균분자량과 수 평균분자량의 비는 낮은온도(-184$^{\circ}C$)dptj 보다는 상온에서 더 높았다는 것을 알았다. Polyacrylic acid의 양 평규 sqnswkfid은 Sodium hydroxide용액에서 점도를 측정하여 계산하였다. Nylon에 Acrylic acid가 중합반응될 때에 중합반응에 영향을 주는 요소들을 시험하였다. Nylon의 산화반응은 질소원자에 인접해 있는 methlene group에서 일어나 free-radical이 만들어 진다는 메카니즘을 논의 하였다.

• 한국염색가공학회지
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• 제6권3호
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• pp.67-73
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• 1994

The adsorption behaviors of acid dye and disperse dye on silk and nylon fabrics were examined, in one bath dyeing system on silk/nylon blend fabric with disperse dyes and acid dyes. In the dyeing of nylon fabric with C. I. Disperse Red 19 (Red 19) and C. I. Disperse Red 60 (Red 60), dye uptake of Red 19 was higher than that of Red 60. When silk/nylon blend fabric was dyed with Red 19 and Red 0, the dye uptake on nylon was influenced by the ffinity of the dye to the silk fabric. In the dyeing of silk/nylon with C. I. Acid Blue 80 and C. I. Acid Yellow 121, solid shade could not be obtained with the conventional method but could be obtained with the dyeing resist agent for nylon. There was not any relationship between K/S value and Munsell value, but Munsell value tended to change with the K/S value.

• 한국의류학회지
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• 제24권5호
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• pp.686-695
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• 2000

Recently, with a growing interest of health and environment, chitosan which was good in no harmful effect to human body and environment, has been watched as the finish treatment of hygiene and pleasantness. The purpose of this study is to develop multifunctional fabric that was improved antimicrobial activity and deodorization rate, water absorption, static voltage and dye absorption by treatment of nylon 6 grafted with acrylic acid added in chitosan. FT-IR spectra of the grafted with acrylic acid added in chitosan shows peaks of COOH and NH2. Antimicrobial activity and deodorization rate of chitosan and grafted with acrylic acid added in chitosan were increased greatly than the control, durability of laundry of grafted with acrylic acid added in chitosan was good. In case of chitosan was dyed acid dyes and grafted with acrylic acid added in chitosan was dyed basic dyes, dye absorption of them were increased than the control. Moisture regain, absorption time and tensile strength of grafted with acrylic acid added in chitosan was increased greatly than the control.

• 복식
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• 제58권1호
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• pp.1-8
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• 2008

The purpose of this study was to investigate the mechanical properties and hand values of polypropylene knit and to analyze its color-fastness for light, laundering and abrasion, comparing to nylon and polyester knits. The results of this study were as follows: 1. Polypropylene stretched more with less force than nylon and polyester and its elastic recovery and shape stability were better than nylon and polyester. 2. Polypropylene was more flexible than nylon and polyester. 3. Polypropylene stretched more easily for shearing but its recovery from shearing was less than nylon and polyester. 4. Polyester had smoother surface than nylon and polyester. 5. Polypropylene was compressed more easily than polyester with less force but less than nylon. Its recovery from compression was more than nylon and polyester. 6. Polypropylene had lower KOSHI and SHARI values and higher FUKURAMI value than nylon and polyester. It had better T.H.V. value than nylon but less than! polyester. 7. Color fastness of polypropylene for lanudering, light, and abrasion in wet and dry conditions was good except polypropylene dyed with red color.

• 폴리머
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• 제31권1호
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• pp.31-36
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• 2007

플라스마 표면처리는 전체적인 물성은 유지하고 표면의 특성만을 변화시킨다고 전해지고 있다. 이번 연구에서는 플라스마 처리에 의해 높은 발수성을 나타내는 나일론 6 섬유로의 개질을 시도하였다. 발수성을 나타내는 나일론 섬유는 가스 종류, 처리시간, 인가 파워를 변수로 하여 RF 진공 플라스마 시스템에서 처리되었다. 플라스마 처리된 섬유의 표면을 scanning electron microscopy(SEM)과 atomic force microscopy(AFM)으로 모폴로지 변화를 살펴보았으며, 기계적 특성과 고분자 고유의 특성을 인장강도와 Differential scanning calorimetry(DSC), thermo-gravimetric analysis (TGA)로 각각 분석하였다. 또한 나일론 섬유의 발수성 평가는 물방울 흡수시간으로 테스트를 실시하였다. 이러한 결과들은 플라스마 표면처리로 인해서 나일론 섬유의 발수성이 향상됨을 나타내었다.

• 폴리머
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• 제29권6호
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• pp.565-570
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• 2005

용융 점도 조절에 의한 나일론6(N6)의 melt impregnation공정에서의 용융가공 특성에 대하여 고찰하여 보았다. N6의 용융 점도를 조절하기 위하여 calcium stearate(CaST)를 윤활제로 사용한 결과, 1 wt$\%$의 윤활제의 첨가에 의하여 용융 점도가 감소함을 알 수 있었다. 아울러 폴리카프로락톤(PCL)을 N6에 반응 용융 블렌딩하여 N6의 용융 점도를 낮출 수 있었으며 phenyl phosphite(PP)와 diphenyl phosphite(DPP)를 첨가하여 블렌딩 시 상호에스테르 교환반응을 증가시켜 추가적인 용융 점도 감소를 확인하였다. 이러한 방법들은 N6의 고온 가공의 문제점으로 지적되는 열안정성 저하를 최소화하면서 melt impregnation 공정에서 필수적인 저점도 가공을 가능하게 할 수 있을 것으로 사료된다.