• 제목/요약/키워드: Nylon 12

Search Result 157, Processing Time 0.029 seconds

Preparation and Properties of Waterborne Polyurethanes Based on Ttiblock Glycol $(CL)_{4.5}$-PTMG-$(CL)_{4.5}$ for Water Vapor Permeable Coatings: Effect of Soft Segment Content

  • Kwak, Yong-Sil;Kim, Han-Do
    • Fibers and Polymers
    • /
    • v.3 no.4
    • /
    • pp.153-158
    • /
    • 2002
  • A series of waterborne polyurethanes (WBPU) were prepared from 4,4-dicyclohexylmethane diisocyanate ($H_{12}$MDI),2,2-bis(hydroxylmethyl) propionic acid (DMPA), othylenediarnine (EDA), triethylamine (TEA), and triblock glycol [TBG, ($\varepsilon$-caprolactone)$_{4.5}$-poly(tetramethylene ether) glycol (MW= 2000)-($\varepsilon$-caprolactone)$_{4.5}$: $(CL)_{4.5}$-PTMG-$(CL)_{4.5}$, MW=3000] as a soft segment. Two melting peaks of TBG at about 14$^{\circ}C$ and 38$^{\circ}C$ were observed indicating the presence of two different crystalline domains composed of CL and PTMG dominant component. The effect of soft segment content (60-75 wt%) on the colloidal properties of dispersion, and thermal and mechanical properties of WBPU films, the water vapor permeability (WVP) and water resistance (WR) of WBPU-coated Nylon fabrics, and the adhesive strength of WBPU- coated layer and Nylon fabrics was investigated. As soft segment contents increased, the water vapor permeability of WBPU- coated Nylon fabrics increased from 3615 to 4502 g/$m^2$day, however, the water resistances decreased from 1300 to 500 mm$H_2$O.O.

Mechanical and thermal properties of polyamide versus reinforced PMMA denture base materials

  • Soygun, Koray;Bolayir, Giray;Boztug, Ali
    • The Journal of Advanced Prosthodontics
    • /
    • v.5 no.2
    • /
    • pp.153-160
    • /
    • 2013
  • PURPOSE. This in vitro study intended to investigate the mechanical and thermal characteristics of Valplast, and of polymethyl methacrylate denture base resin in which different esthetic fibers (E-glass, nylon 6 or nylon 6.6) were added. MATERIALS AND METHODS. Five groups were formed: control (PMMA), PMMA-E glass, PMMA-nylon 6, PMMA-nylon 6.6 and Valplast resin. For the transverse strength test the specimens were prepared in accordance with ANSI/ADA specification No.12, and for the impact test ASTM D-256 standard were used. With the intent to evaluate the properties of transverse strength, the three-point bending (n=7) test instrument (Lloyd NK5, Lloyd Instruments Ltd, Fareham Hampshire, UK) was used at 5 mm/min. A Dynatup 9250 HV (Instron, UK) device was employed for the impact strength (n=7). All of the resin samples were tested by using thermo-mechanical analysis (Shimadzu TMA 50, Shimadzu, Japan). The data were analyzed by Kruskal-Wallis and Tukey tests for pairwise comparisons of the groups at the 0.05 level of significance. RESULTS. In all mechanical tests, the highest values were observed in Valplast group (transverse strength: $117.22{\pm}37.80$ MPa, maximum deflection: $27.55{\pm}1.48$ mm, impact strength: $0.76{\pm}0.03$ kN). Upon examining the thermo-mechanical analysis data, it was seen that the E value of the control sample was 8.08 MPa, higher than that of the all other samples. CONCLUSION. Although Valplast denture material has good mechanical strength, its elastic modulus is not high enough to meet the standard of PMMA materials.

Dyeing Properties and Ultraviolet-cut Ability of Dyed Fabrics with Petasites japonicus Extract (머위 추출액에 의한 직물의 염색성과 자외선 차단성)

  • Choi, In-Ryu;Joen, Mi-Sun
    • The Research Journal of the Costume Culture
    • /
    • v.19 no.1
    • /
    • pp.96-103
    • /
    • 2011
  • It is well known that the Petasites japonicus has been used for a long time medicine for the treatment of allergic diseases such as lacquer poisoning. However, the exact components and dyeing properties of its effects is still not known. Therefore, the purpose of this study was to investigate the dyeing property and ultraviolet-cut ability of silk and nylon fabrics that was dyed variously with the Petasites japonicus. The Petasites japonicus extract was done by boiling with distilled water at $100^{\circ}C$ for 1 hour. As mordanting agent, we used Aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$), Copper(II) sulfate pentahydrate ($CuSO_5{\cdot}5H_2O$), Iron(II)Chloride ($FeCl_2{\cdot}4H_2O$). The best K/S value of dyeing temperature and time, all the fabrics were $100^{\circ}C$, 90min. Silk fabric was dyed yellow(0.8Y 7.6/2.2) and nylon fabric was dyed reddish yellow(10.1 YR 7.4/3.0). Silk fabric and nylon fabric was changed greenish yellow on mordanting with $CuSO_5{\cdot}5H_2O$ and $FeCl_2{\cdot}4H_2O$ respectively. And the colorfastness of washing and dry-cleaning was improved by using mordanting agent(4~5 grade). Ultraviolet-cut ability(UV-B) was showed more 90% in dyed nylon fabrics.

Application of Nylon Fiber for Performance Improvement of Recycled Coarse Aggregate Concrete (순환 굵은골재 사용 콘크리트의 성능향상을 위한 나일론 섬유의 적용성 연구)

  • Lee, Seung-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.18 no.12
    • /
    • pp.785-792
    • /
    • 2017
  • In recent times, the lack of good quality natural aggregate has led to the alternative use of recycled aggregate. However, the adhered mortars in recycled aggregate lower the performance of the concrete, such as by reducing its strength and causing deterioration and cracking. In this study, the effects of nylon fiber (NF) on the mechanical and durable performance of recycled coarse aggregate concrete (RAC) were experimentally examined. Concrete specimens with natural coarse aggregate (NA) or RA were produced by adding 0, 0.6 and $1.2kg/m^3$ of NF. Various mechanical properties and the durability of the RAC were measured and compared with those of the NAC. In addition, in order to observe the hydrates and ITZ, SEM observations were made of the 28-day concrete samples. From the test results, as expected, it was found that the RAC exhibited lower performance than the NAC. However, the addition of NF to the concrete was effective in significantly enhancing the performance of the RAC due to the bridge effect of the NF.

Functional Verification of the Solar Panel Separation Mechanism for Pico-Class Satellite Applications Using Spring-loaded Pogo-pin (포고핀을 활용한 극초소형 위성용 태양전지판 분리장치의 기능검증)

  • Kim, Su-Hyeon;Jeon, Young-Hyeon;Kim, Hong-Rae;Oh, Hyun-Ung
    • Journal of Aerospace System Engineering
    • /
    • v.12 no.5
    • /
    • pp.69-75
    • /
    • 2018
  • In this study, we proposed a nylon wire cutting-type solar panel separation mechanism for CubeSat applications using spring-loaded pogo-pins, which has been widely used as temporary electrical interface between two separate electronics. The mechanism proposed in this study has great advantages of higher holding capability, ability to constrain along in-plane and out-of-plane directions of solar panels, simplicity in tightening of nylon wire and synchronous separation of multiple panels. In addition, the pogo-pins used for the proposed mechanism act as electrical power interface, separation status switch and separation spring. In this study, the functionality of the proposed mechanism was validated through the separation tests with various number of nylon wire windings.

A study on using composite materials for automotive clutch connector reliability (복합소재를 이용한 자동차 클러치 커넥터 안정성에 관한 연구)

  • Yi, Chang-Heon;Lee, Jong-Hyung;Byun, Jae-Hyuk
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.12 no.3
    • /
    • pp.81-88
    • /
    • 2013
  • Recently, energy-saving technology is rapidly becoming a crucial issue for mankind due to the depletion of natural resources. From this perspective, every automobile manufactures are trying to develop light materials and to validate safety with environmental consideration. In this study, we developed clutch connector tube which is the parts of power transferring clutch with light materials to substitude for existing general steel materials. We also verified that the general steel materials can be replaced with nylon, fiberglass, stainless and plastic materials or not. As a result, we verified that the mixture of glass and nylon composite material can substitude the general steel.

Dyeing Properties of Protein and Polyamide Fabrics with Arrowroot Extract (칡뿌리를 이용한 단백질 및 폴리아미드 섬유의 염색성)

  • 이정은;이문철;최석철
    • Textile Coloration and Finishing
    • /
    • v.12 no.6
    • /
    • pp.353-360
    • /
    • 2000
  • In this article, arrowroot is extracted in distilled water, and its dyeing properties on wool, nylon, and silk were investigated. Also the effect of mordanting (Al, Cu, Sn, Fe and Cr compounds) on the wash fastness are measured. The wavelength of maximum absorption of the arrowroot extract appears at 250 and 300nm below pH 7, but they shifted to longer wavelength at higher pH values. It appears that the optimum condition of the dyeing of wool, nylon, and silk fabric with arrowroot extract is $60^\circ{C}$, 60 min, and pH 4.0. Mordant treatments are effective in improving wash fastness of polyamide fabrics.

  • PDF

Dyeing Properties of Protein and Synthetic Fibers with the Tumeric Extracts (울금 색소 추출물에 의한 단백질계 및 합성섬유의 염색성)

  • 한신영;최석철
    • Textile Coloration and Finishing
    • /
    • v.12 no.6
    • /
    • pp.396-403
    • /
    • 2000
  • The purpose of this study was to investigate the dyeing properties of silk, wool, nylon and poly(ethylene teraphtlate)〔PET〕 fabrics dyed with Tumeric(Curcuma longa) extracts. The dyeing property and color fastness were investigated by using the extracts and the post mordanting with Aluminum, Copper and Iron salts. In the UV-visible spectra, the maximum absorption of wavelength of the extract with methyl alcohol appeared at 420nm, and that of the extract with distilled water was at 415nm. Increasing the dyeing temperature, the K/S values of dyed fabrics were increased. The optimum dyeing condition was 30∼60 minute of dyeing time at pH 5∼5.6. Surface colors of silk and wool became dark by using mordants compared to those of nylon and PET fabrics. The drycleaning fastness of fabrics dyed with the extracts was good. The laundering and light fastness were improved by using mordants.

  • PDF

Determination of Ethanol in Alcoholic Beverages by Alcohol Oxidase Sensor (Alcohol oxidase 효소센서를 이용한 알코올 음료 중의 에탄올 정량)

  • Lee, Ok-Kyung;Kim, Tai-Jin;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
    • /
    • v.27 no.2
    • /
    • pp.266-269
    • /
    • 1995
  • In order to measure alcohol contents with speed and accuracy, alcohol sensor was prepared. Alcohol sensor was made by connecting with oxygen electrode after immobilized alcohol oxidase on nylon net with glutaraldehyde. Alcohol was determined by changing the rate of dissolved oxygen consumption using D.O. analyzer. Alcohol contents in alcoholic beverages were determined under the optimum conditions. The results were 0.71% in low-alcohol beverage, $4{\sim}5%$ in beers, 10.06% in wine, 16.12% in chungju, 25.71% in soju, and 6.18% in takju, respectively. The values by alcohol sensor showed an excellent correlation(r=0.999) with GC method.

  • PDF

Synthesis and Adhesion Properties of Aliphatic Polyurethane Adhesive (지방족 폴리우레탄 접착제의 합성과 접착 특성)

  • Park, Chang-Moo;Choi, Seung-Ok;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
    • /
    • v.27 no.4
    • /
    • pp.461-469
    • /
    • 2010
  • Polyurethane adhesive is used in various fields as flexible packaging materials including a food packaging field. Therefore, the purpose of this study is synthesis of polyurethane adhesive which uses aliphatic isocyanate, and compares with aromatic isocyanate. The isocyanates for this test are toluene-2,4-diisocyanate(TDI), hexamethylene diisocyanate(HDI), 4,4-dicyclohexyl ethane diisocyanate($H_{12}MDI$), and isophorone diisocyanate(IPDI). And, the effect of any other diisocyanate are evaluated by several methods as for curing rate test, accelerate weathering test, and peel strength test. The polyurethane adhesive using curing catalyst and HDI has adhesion strength of about 560 g/15 mm between aluminium foil and nylon, about 1,520 g/15 mm between nylon and CPP. Those parameters are similar to polyurethane adhesive with TDI. Also, in case of curing rate, those are similar to TDI type polyurethane adhesive. Moreover, data of ${\Delta}E$ as color variation by QUV tester is equal to 4.12, as 48% against those of TDI type.