• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.490-494
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• 2011

Nanocomposites of blends of polyethyleneterephthalate (PET) and polyamide66 (Nylon66) containing natural and organically modified montmorillonite clays (PM, $Cloisite^{(R)}$ 25A and 15A) were prepared by melt mixing. DSC results showed that the addition of clay changed the crystallization behavior of PET/Nylon66 nanocomposites. Clay C25A was observed to most significantly change the crystallization temperature than other clays in blends of PET and Nylon66, which may be caused by the difference in interaction with matrix polymers. AFM results also showed that the lowest value of surface roughness was observed for nanocomposites containing C25A indicating the smooth and relatively homogenous surface. Mechanical properties measurement showed the similar results. Contact angle was measured to study the difference in hydrophobicity. An increase in contact angle was observed for nanocomposites with C25A or C15A due to the increased hydrophobicity.

• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.1068-1075
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• 2012

Poly(butylene terephthalate) (PBT)/Nylon6,12 core/shell micro fiber were prepared by extrusion molding. To investigate their optimum extrusion conditions, compatibility of PBT/Nylon6,12 blend micro fiber in conformity to their weight ratio and manufacture temperature was explored with SEM morphology and DSC. The alterations in their mechanical properties by extrusion speed were compared and analyzed through a UTM. In comparison with SEM figures, the domain sizes of Nylon6,12 were gradually declined by increasing the extrusion temperature of blends. Furthermore, according to these SEM images, the phase separation between Nylon6,12 domain and PBT matrix became indistinct with increasing of weight percentage of Nylon6,12. In case of DSC, the boundaries of two peaks were almost disappeared when increasing the extrusion temperature and also intervals of each two melting peaks became narrow as increasing the Nylon6,12 ratio. The mechanical properties including tensile strength, elongation, flexural strength and flexural modulus were increased as the increase in the extrusion temperature until $260^{\circ}C$. However, the mechanical properties were actually deteriorated over $260^{\circ}C$. The tensile strength, elongation, flexural strength and flexural modulus at $260^{\circ}C$ were 560 $kg_f/cm^2$, 220%, 807 $kg_f/cm^2$ and 22,146 $kg_f/cm^2$, respectively. These values are more than intermediate values of mechanical properties of PBT and Nylon6,12. These results mean that there is compatibility between PBT and Nylon6,12. Based on the extrusion conditions that produced optimum compatibility of blend, as a result, our group obtained micro fibers with the core/shell structure.

• The Journal of the Korea Contents Association
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• v.19 no.7
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• pp.186-191
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• 2019

Introduction: In aged people, stroke incidence is increased. But standardized experimental animal protocol study for the research of stroke therapy is rare. There is little report on the success rate of cerebral artery occlusion model using standardized Nylon thread length of precise thread end-size controlled. Method: In this study, the operator intended the occlusion of middle cerebral artery (MCA) using $0.18{\pm}0.02mm$ end 5-0 Nylon thread. Middle cerebral artery occlusion was induced for 60min under isoflurane anesthesia. After 60min, the operator removed the Nylon thread and reperfusion was induced for 23hrs. The mice was killed 23hrs after reperfusion and infarction area of brain was confirmed by 1.5% TTC (2,3,5-tryphenyl tetrazolium chloride) staining. Results: According to end size and insert length of Nylon thread, Middle cerebral artery occlusion (n=50), internal carotid artery occlusion (n= 14), distal middle cerebral artery occlusion (n= 36), anterior cerebral artery (n= 1) were induced. And no infarction (n= 50) was observed. Conclusion: According to weight of mice, the operator induced reversible cerebral artery occlusion model by different insert length (30.0~36.9g : 9.0mm, 37.0~40.0g : 9.5mm) of Nylon thread. Success of cerebral artery occlusion model was confirmed by checking infarction area using TTC staining. The success rate (66.9%, 101/151) of reversible cerebral artery occlusion model in the mouse and the operational conditions are shown.

• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.481-484
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• 2002

nylon 6의 단점인 저온에서의 연성 및 내충격성 저하를 개선하는 동시에 nylon 6의 내후성도 개선시키는 방법의 하나로 유리전이온도가 매우 낮고, 내가수분해성, 내후성 및 연성(ductile property)이 뛰어난 불소함유 고분자계의 한 종류인 PVDF (polyvinylidene fluoride)를 nylon 6에 용융블렌드 하는 방법이 제안되었다. [1-5] 그런데 용융상태에서 두 고분자는 부분 혼화성만을 보이고, nylon 6과 PVDF는 모두 결정성 고분자이기 때문에 성형 후 냉각하는 동안 두 고분자의 결정화에 기인한 결정화유도 상분리가 일어나게 된다. (중략)

• Textile Coloration and Finishing
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• v.20 no.2
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• pp.47-52
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• 2008

Nylon textured yarn is usually manufactured by disk type false twist texturing. Dyeing properties of nylon textured yam have not been studied yet. In this study, dyeing properties of nylon textured yam according to draw ratio out of process parameters were investigated. The fact that microstructure of nylon textured yarn in amorphous region particularly is transformed by draw ratio was confirmed indirectly by measurement of dyeing rate because dyeing rate was affected by the structure of amorphous region. Dyeing rate at draw ratio 1.29 was the lowest because the higher draw ratio increase amorphous orientation and disturb dye diffusion into amorphous region. The microstructure according draw ratio was indirectly confirmed by 5% strength, tenacity, elongation. But difference in K/S value and fastness was insignificant.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.6
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• pp.1159-1168
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• 2002

Power-transmission Nylon pinions against steel gears fur different pitch line velocities was studied with a power circulating gear test rig under unlubricated condition by SEM(Scanning Electron Microscope). The wear characteristics of Nylon pinions varied significantly with the pitch line velocity and applied load. Wear occurred most severely at the regions including pitch circle and root circle of Nylon pinions. It is confirmed that Nylon pinions are able to be used fer power-transmission under limited conditions.

• Textile Coloration and Finishing
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• v.14 no.6
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• pp.335-341
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• 2002

The physical properties and the dyeability of the nylon S fibers Prepared by high speed spinning according to godet roller draw ratio form 1.1 to 1.6 were investigated. The strains of nylon 6 fibers were decreased against the increase of the godet roller draw ratio. The stresses of nylon 6 fibers were increased with the increase of the godet roller draw ratio. Birefringences, densities and crystallinities of the nylon 6 fibers were increased with the increase of godet roller draw ratio In DSC diagrams, the $\gamma$ form of crystal became dominant at higher godet roller draw ratio. The dye uptakes of C. 1. Acid Blue 113 on the fibers were decreased against the increase of godet roller draw ratio.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.03a
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• pp.49-49
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• 2011

최근 나일론 세섬 신축소재를 이용한 초경량 직물은 에 많이 사용되어지는 Nylon직물은 DTY 20~40d 소재를 이용한 rib조직과 이중조직 설계기술 및 염색가공기술에 의한 것으로 이들 제품은 조직의 한계점(이중조직, Rib), 신축특성의 저하, 품질 저하의 문제점이 대두되고 있어 아직까지 본격적으로는 상용화되지 못하고 있는 실정이다. 국내외적으로는 Polyester를 이용한 잠재권축 사는 일정수준으로 기술개발 진행 되어왔으나 아직까지 나일론 세섬사의 잠재권축 소재의 기술개발은 전무한 실정이다. 따라서 본 연구에서는 스포츠/레저용 초경량 Nylon 박지에 적합한 자발신장 개념인 Nylon6 잠재권축 소재를 개발하기 위하여 26D수준의 side by side형인 nylon6/Co-Nylon의 구조와 물성을 조사 검토하여 이를 실제 현장에 자료를 제공하는 것을 목적으로 하였다.

• Textile Coloration and Finishing
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• v.1 no.1
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• pp.63-68
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• 1989

It has been attempted to improve the anti-static property of Nylon 6 by means of Vapor-phase polymerization of thiophene in Nylon 6/PVA blend films impregnated with aluminium chloride as an oxident. After Polymerization of thiophene for two hours in Nylon 6/PVA blend films the conductivity increased from $10^{-12}-10^{-13}S/cm\;to\;10^{-5}-10^{-7}$S/cm, and the conductivity of composite films increased with increasing the concentration of aluminium chloride, the content of PVA annd polymerization time of thiophene. Polythiophene introduced in Nylon 6/PVA blend films has been confirmed by FT-IR spectra and scanning electron micrographs.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.2 no.3
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• pp.84-89
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• 2003

The joint method and characteristics of lubricant Impregnated MC nylon and metal are analyzed. Considering the productivity and economics, two materials are Joined with the process of turning, knurling, and induction heating. The Joint strength is determined by adhesion of the melted nylon, the size of knurl, and the interference from the difference of the diameters. The parameters affecting induction heating process are analyzed. The adhesion strength of the melted nylon is measured. Finally the joint strength is analyzed in the environments of low, room, and high temperature. The nylon/metal Joined material is expected to be widely used as the sliding machine elements with good friction and shear strength.