• Title/Summary/Keyword: Nuclear materials

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Effect of Cr on Flow Accelerated Corrosion of Carbon Steel (탄소강의 유동가속부식에 미치는 크롬의 영향)

  • Lee, Eun Hee;Kim, Kyung Mo;Kim, Hong Pyo;Kim, Dong Jin
    • Corrosion Science and Technology
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    • v.14 no.1
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    • pp.25-32
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    • 2015
  • The alloy content of structural materials of nuclear power plants has been recognized an important factor in predicting flow accelerated corrosion (FAC). In particular, many literature data reported that chromium content is one of the most important alloying element and even a small amount of chromium is effective to suppress FAC. This report reviewed and compared chromium models of Ducreux, Bouchacourt, and Kastner which were used in predicting FAC rates. The plant data indicate that Ducreux model may be conservative for the specimen containing 0.15 wt% chromium. The related articles were reviewed as follows. Combined effects of chromium content, pH, temperature, dissolved oxygen (DO), flow velocity, test time, and kinds of amine on the FAC rate were described. 0.1 wt% chromium in steel did not affect the FAC rate with changes in pH. The FAC rates pronounced with higher flow rate and increased with increasing test duration(600 d) for 0.013 wt% chromium. The FAC rates in mixed amine chemistry were higher than in ammonia chemistry, which may be lessened by the addition of chromium to the steel.

Distribution Analysis of TRISO-Coated Particles in Fully Ceramic Microencapsulated Fuel Composites

  • Lee, Hyeon-Geun;Kim, Daejong;Lee, Seung Jae;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.55 no.4
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    • pp.400-405
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    • 2018
  • FCM nuclear fuel, a concept proposed as an accident tolerant fuel in light water reactors, consists of TRISO fuel particles embedded in a SiC matrix. The uniform dispersion of internal TRISO fuel particles in the FCM fuel is very important for improving the fuel efficiency. In this study, FCM sintered pellets with various volume ratios of TRISO-coated particles were prepared by hot press sintering. The distribution of TRISO-coated particles was quantitatively analyzed using X-ray ${\mu}CT$ and expressed as a dispersion uniformity index. TRISO-coated particles were most uniformly dispersed in the FCM pellets prepared using only overcoated TRISO particles without mixing of additional SiC matrix powder. FCM pellets with uniformly dispersed TRISO particle volume fraction of up to 50% were prepared using overcoated TRISO particles with varying thickness.

Corrosion of Selected Materials in Boiling Sulfuric Acid for the Nuclear Power Industries

  • Kim, Dong-Jin;Lee, Han Hee;Kwon, Hyuk Chul;Kim, Hong Pyo;Hwang, Seong Sik
    • Corrosion Science and Technology
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    • v.6 no.2
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    • pp.37-43
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    • 2007
  • Iodine sulfur (IS) process is one of the promising processes for a hydrogen production by using a high temperature heat generated by a very high temperature gas cooled reactor(VHTR) in the nuclear power industries. Even though the IS process is very efficient for a hydrogen production and it is not accompanied by a carbon dioxide evolution, the highly corrosive environment of the process limits its application in the industry. Corrosion tests of selected materials were performed in sulfuric acid to select appropriate materials compatible with the IS process. The materials used in this work were Fe-Cr alloys, Fe-Ni-Cr alloys, Fe-Si alloys, Ni base alloys, Ta, Ti, Zr, SiC, Fe-Si, etc. The test environments were 50 wt% sulfuric acid at $120^{\circ}C$ and 98 wt% at $320^{\circ}C$. Corrosion rates were measured by using a weight change after an immersion. The surface morphologies and cross sectional areas of the corroded materials were examined by using SEM equipped with EDS. Corrosion behaviors of the materials were discussed in terms of the chemical composition of the materials, a weight loss, the corrosion morphology, the precipitates in the microstructure and the surface layer composition.

Characterization of Glass Melts Containing Simulated Low and Intermediate Level Radioactive Waste

  • Jung, Hyun-Su;Kim, Ki-Dong;Lee, Seung-Heon;Kwon, Sung-Ku;Kim, Cheon-Woo;Park, Jong-Kil;Hwang, Tae-Won;Ahn, Zou-Sam
    • Journal of the Korean Ceramic Society
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    • v.43 no.3 s.286
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    • pp.148-151
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    • 2006
  • In order to examine the process parameters for the vitrification of Low and Intermediate Level radioactive Waste (LILW) generated from nuclear power plants, measurements of several melt properties was performed for four selected glasses containing simulated waste. Electrical conductivity and viscosity were determined at temperatures ranging from 1123 to $1673^{\circ}C$. The temperature dependences of both properties in the molten state showed a similar behavior in which their values decrease as the temperature increases. The values of the electrical conductivity and viscosity at a temperature of 1423K adopted in an induction cold crucible melter process were $0.27{\sim}0.42$ S/cm and $9.8{\sim}42$ dPas, respectively.

Specimen Geometry Effects on Oxidation Behavior of Nuclear Graphite

  • Cho, Kwang-Youn;Kim, Kyung-Ja;Lim, Yun-Soo;Chung, Yun-Joong;Chi, Se-Hwan
    • Carbon letters
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    • v.7 no.3
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    • pp.196-200
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    • 2006
  • Graphite has hexagonal closed packing structure with two bonding characteristics of van der Waals bonding between the carbon layers at c axis, and covalent bonding in the carbon layer at a and b axis. Graphite has high tolerant to the extreme conditions of high temperature and neutron irradiations rather than any other materials of metals and ceramics. However, carbon elements easily react with oxygen at as low as 400C. Considering the increasing production of today of hydrogen and electricity with a nuclear reactor, study of oxidation characteristics of graphite is very important, and essential for the life evaluation and design of the nuclear reactor. Since the oxidation behaviors of graphite are dependent on the shapes of testing specimen, critical care is required for evaluation of nuclear reactor graphite materials. In this work, oxidation rate and amounts of the isotropic graphite (IG-110, Toyo Carbon), currently being used for the Koran nuclear reactor, are investigated at various temperature. Oxidation process or principle of graphite was figured out by measuring the oxidation rate, and relation between oxidation rate and sample shape are understood. In the oxidation process, shape effect of volume, surface area, and surface to volume ratio are investigated at $600^{\circ}C$, based on the sample of ASTM C 1179-91.

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Evaluation of Characteristics of Simulated Radioactive Vitrified Form Using Cooling Methods (냉각 방법에 따른 모의 방사성폐기물 유리고화체의 특성평가)

  • Lee, Kang-Taek;Lee, Kyu-Ho;Yoon, Duk-Ki;Ryu, Bong-Ki;Kim, Cheon-Woo;Park, Jong-Kil;Hwang, Tae-Won
    • Journal of the Korean Ceramic Society
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    • v.43 no.12 s.295
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    • pp.865-871
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    • 2006
  • In order to examine and compare the characteristics of two vitrified forms (AG8W1 and DG2) simulated for the operation of a commercial vitrification facility being constructed in Ulchin nuclear power plant, the vitrified forms were cooled by the natural cooling and annealing methods respectively. And the Product Consistency Test (PCT), compressive strength, thermal conductivity, specific heat, phase stability, softening point and Coefficient of Thermal Expansion (CTE) of the vitrified farms were experimented. Consequently, it was shown that there were no significant differences on the physiochemical properties of the vitrified forms performed the natural cooling and annealing.

Atomistic simulations of nanocrystalline U0.5Th0.5O2 solid solution under uniaxial tension

  • Xiao, Hongxing;Wang, Xiaomin;Long, Chongsheng;Tian, Xiaofeng;Wang, Hui
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1733-1739
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    • 2017
  • Molecular dynamics simulations were performed to investigate the uniaxial tensile properties of nanocrystalline $U_{0.5}Th_{0.5}O_2$ solid solution with the Born-Mayer-Huggins potential. The results indicated that the elastic modulus increased linearly with the density relative to a single crystal, but decreased with increasing temperature. The simulated nanocrystalline $U_{0.5}Th_{0.5}O_2$ exhibited a breakdown in the Halle-Petch relation with mean grain size varying from 3.0 nm to 18.0 nm. Moreover, the elastic modulus of $U_{1-y}Th_yO_2$ solid solutions with different content of thorium at 300 K was also studied and the results accorded well with the experimental data available in the literature. In addition, the fracture mode of nanocrystalline $U_{0.5}Th_{0.5}O_2$ was inclined to be ductile because the fracture behavior was preceded by some moderate amount of plastic deformation, which is different from what has been seen earlier in simulations of pure $UO_2$.

Effect of Dissolved Hydrogen on Fuel Crud Deposition (핵연료 피복관 부식생성물 부착에 대한 용존수소의 영향)

  • Baek, S.H.;Kim, U.C.;Shim, H.S.;Lim, K.S.;Won, C.H.;Hur, D.H.
    • Corrosion Science and Technology
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    • v.13 no.2
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    • pp.56-61
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    • 2014
  • The purpose of this work is to investigate the effect of dissolved hydrogen concentration on crud deposition onto the fuel cladding surface in the simulated primary environments of a pressurized water reactor. Crud deposition tests were conducted in the dissolved hydrogen concentration range of 5~70 cc/kg at $325^{\circ}C$ for 14 days. Needle-shaped NiO deposits were formed in the hydrogen range of 5~25 cc/kg, while polygonal nickel ferrite deposits were observed at a hydrogen concentration above 35 cc/kg. However, the dissolved hydrogen content seems to have little effect on the amount of crud deposits.

Oxidation Behaviors of SiCf/SiC Composites Tested at High Temperature in Air by an Ablation Method

  • Park, Ji Yeon;Kim, Daejong;Lee, Hyeon-Geun;Kim, Weon-Ju;Pouchon, Manuel
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.498-503
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    • 2018
  • Using the thermal ablation method, the oxidation behavior of $SiC_f/SiC$ composites was investigated in air and in the temperature range of $1,300^{\circ}C$ to $2,000^{\circ}C$. At the relatively low temperature of $1,300^{\circ}C$, passive oxidation, which formed amorphous phase, predominantly occurred in the thermal ablation test. When the oxidation temperature increased, SiO (g) and CO (g) were formed by active oxidation and the dense oxide layer changed to a porous one by vaporization of gas phases. In the higher temperature oxidation test, both active oxidation due to $SiO_2$ decomposition on the surface of the oxide layer and active/passive oxidation transition due to interfacial reaction between oxide and base materials such as SiC fiber and matrix phase simultaneously occurred. This was another cause of high temperature degradation of $SiC_f/SiC$ composites.

A Study on the Reliability Assesment of Solar Photovoltaic and Thermal Collector System (태양광열 시스템의 신뢰성 평가에 관한 연구)

  • Park, Tae-Kook;Bae, Seung-Hoon;Kim, Sang-Kyo;Kim, Seon-Min;Kim, Dae-Hwan;Eom, Hak-Yong;Lee, Keun-Hui
    • New & Renewable Energy
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    • v.16 no.4
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    • pp.49-64
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    • 2020
  • Photovoltaic and Thermal collector (PV/T) systems are renewable energy devices that can produce electricity and heat energy simultaneously using solar panels and heat exchangers. Since PV/T systems are exposed to the outdoors, their reliability is affected by various environmental factors. This paper presents a reliability test for a PV/T system and evaluates the test results. The reliability assessment entails performance, environment, safety, and life tests. The factor that had the greatest influence on the life of the system was the hydraulic pressure applied to the heat exchanger. A test was conducted by repeatedly applying pressure to the PV/T system, and a reliability analysis was conducted based on the test results. As a result, the shape parameter (β) value of 5.6658 and the B10life 308,577 cycles at the lower 95% confidence interval were obtained.