• Title/Summary/Keyword: Nuclear Hydrogen

검색결과 636건 처리시간 0.535초

EFFECT OF CYCLIC STRAIN RATE AND SULFIDES ON ENVIRONMENTALLY ASSISTED CRACKING BEHAVIORS OF SA508 GR. 1A LOW ALLOY STEEL IN DEOXYGENATED WATER AT 310℃

  • Jang, Hun;Cho, Hyun-Chul;Jang, Chang-Heui;Kim, Tae-Soon;Moon, Chan-Kook
    • Nuclear Engineering and Technology
    • /
    • 제40권3호
    • /
    • pp.225-232
    • /
    • 2008
  • To understand the effect of the cyclic strain rate on the environmentally assisted cracking behaviors of SA508 Gr.1a low alloy steel in deoxygenated water at $310^{\circ}C$, the fatigue surface and a sectioned area of specimens were observed after low cycle fatigue tests. On the fatigue surface of the specimen tested at a strain rate of 0.008 %/s, unclear ductile striations and a blunt crack tip were observed. Therefore, metal dissolution could be the main cracking mechanism of the material at this strain rate. On the other hand, on the fatigue surfaces of the specimens tested at strain rates of 0.04 and 0.4 %/s, brittle cracks and flat facets, which are evidences of the hydrogen induced cracking, were observed. In addition, a tendency of linkage between the main crack and the micro-cracks was observed on the sectioned area. Therefore, at higher strain rates, the main cracking mechanism could be hydrogen induced cracking. Additionally, evidence of the dissolved MnS inclusions was observed on the fatigue surface from energy dispersive x-ray spectrometer analyses. Thus, despite the low sulfur content of the test material, the sulfides seem to contribute to environmentally assisted cracking of SA508 Gr.1a low alloy steel in deoxygenated water at $310^{\circ}C$.

Study on nuclear magnetic resonance of superionic conductor NH4HSeO4 in rotating frame

  • Choi, Jae Hun;Lim, Ae Ran
    • Journal of the Korean Magnetic Resonance Society
    • /
    • 제18권1호
    • /
    • pp.41-46
    • /
    • 2014
  • In order to obtain information on the structural geometry of $NH_4HSeO_4$ near the phase transition temperature, the spectrum and spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for the ammonium and hydrogen-bond protons were investigated through $^1H$ MAS NMR. $T_{1{\rho}}$ for the hydrogen-bond protons abruptly decreased at high temperature and it is associated with the change in the structural geometry in $O-H{\cdots}O$ bonds. This mobility of the hydrogen-bond protons may be the main reason for the high conductivity.

The Influence of Hydrogen Loading on Radiation Sensitivity of Fiber Bragg Gratings (광섬유 브래그 격자의 방사선 민감도에 대한 수소로딩의 영향)

  • Kim, Jong-Yeol;Lee, Nam-Ho;Jung, Hyun-Kyu
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • 제17권10호
    • /
    • pp.2461-2465
    • /
    • 2013
  • This paper investigates the influence of hydrogen loading process on the radiation sensitivity of fiber Bragg gratings (FBG). We made the FBG inscribed in the same commercial Ge-doped fiber with different hydrogen loading periods. We measured the Bragg wavelength shift (BWS) of the FBG exposed to gamma-radiation up to a dose of 18 kGy, and evaluated the change of full width at half maximum (FWHM) and the FBG temperature sensitivity coefficient after irradiation. Varying hydrogen loading parameter led to BWS differences up to nearly a factor of two.

Assessment of $13{\sim}19%Cr$ Ferritic Oxide Dispersion Strengthened Steels for Fuel Cladding Applications

  • Lee, J.S.;Kim, I.S.;Kimura, A.;Choo, K.N.;Kim, B.G.;Choo, Y.S.;Kang, Y.H.
    • Proceedings of the Korean Nuclear Society Conference
    • /
    • 한국원자력학회 2004년도 추계학술발표회 발표논문집
    • /
    • pp.911-912
    • /
    • 2004
  • 1. Cathodic hydrogen charging considerably reduced the tensile ductility of ODS steels and a 9Cr-2W RMS. The hydrogen embrittlement of ODS steels was strongly affected by specimen sampling orientation, showing significant embrittlement in the T-direction. This comes from the microstructural anisotropy caused by elongated grains of ODS steels in L-direction. 2. The ODS steels contained a higher concentration of hydrogen than 9Cr-2W RMS at the same cathodic charging condition, and the critical hydrogen concentration required to transition from ductile to brittle fracture was in the range of $10{\sim}12$ wppm, which approximately 10 times larger than that of a 9Cr-2W martensitic steel. 3. The ODS steels showed a typical ductile to brittle transition behavior and it strongly depended on the specimen sampling direction, namely L- and T-direction. In T-direction, the SP-DBTT was about 170 L, irrespective of the ODS materials, and L-direction showed a lower SP-DBTT than that of T-direction.

  • PDF

Allowable peak heat-up cladding temperature for spent fuel integrity during interim-dry storage

  • Jang, Ki-Nam;Cha, Hyun-Jin;Kim, Kyu-Tae
    • Nuclear Engineering and Technology
    • /
    • 제49권8호
    • /
    • pp.1740-1747
    • /
    • 2017
  • To investigate allowable peak cladding temperature and hoop stress for maintenance of cladding integrity during interim-dry storage and subsequent transport, zirconium alloy cladding tubes were hydrogen-charged to generate 250 ppm and 500 ppm hydrogen contents, simulating spent nuclear fuel degradation. The hydrogen-charged specimens were heated to four peak temperatures of $250^{\circ}C$, $300^{\circ}C$, $350^{\circ}C$, and $400^{\circ}C$, and then cooled to room temperature at cooling rates of $0.3^{\circ}C/min$ under three tensile hoop stresses of 80 MPa, 100 MPa, and 120 MPa. The cool-down specimens showed that high peak heat-up temperature led to lower hydrogen content and that larger tensile hoop stress generated larger radial hydride fraction and consequently lower plastic elongation. Based on these out-of-pile cladding tube test results only, it may be said that peak cladding temperature should be limited to a level < $250^{\circ}C$, regardless of the cladding hoop stress, to ensure cladding integrity during interim-dry storage and subsequent transport.

Development of On-axis Raman Lidar System for Remotely Measuring Hydrogen Gas at Long Distance (원거리 수소 가스 원격 계측을 위한 On-axis 라만 라이다 장치 개발)

  • Choi, In Young;Baik, Sung Hoon;Lim, Jae Young;Cha, Jung Ho;Kim, Jin Ho
    • Korean Journal of Optics and Photonics
    • /
    • 제29권3호
    • /
    • pp.119-125
    • /
    • 2018
  • Hydrogen gas is an important and promising energy resource that has no emissions of pollutants during power generation. However, hydrogen gas is very dangerous because it is colorless, odorless, highly flammable, and explosive at low concentration. Conventional techniques for hydrogen gas detection are very difficult for measuring the hydrogen gas distribution at long distances, because they sample the gas to measure its concentration. Raman lidar is one of the techniques for remotely detecting hydrogen gas and measuring the range of the hydrogen gas distribution. A Raman lidar system with an on-axis optical receiver was developed to improve the range of hydrogen gas detection at long distance. To verify the accuracy and improvement in the range of detecting the hydrogen gas, experiments measuring the hydrogen gas concentration are carried out using the developed on-axis Raman lidar system and a gas chamber, to prevent explosion of the hydrogen gas. As a result, our developed on-axis Raman lidar system can measure a minimum hydrogen gas concentration of 0.66 volume percent at a distance of 50 m.

Segmented mandrel tests of as-received and hydrogenated WWER fuel cladding tubes

  • Kiraly, Marton;Horvath, Marta;Nagy, Richard;Ver, Nora;Hozer, Zoltan
    • Nuclear Engineering and Technology
    • /
    • 제53권9호
    • /
    • pp.2990-3002
    • /
    • 2021
  • The mechanical interaction between the fuel pellet and the cladding tube of a nuclear fuel rod is a very important for safety studies as this phenomenon could lead to fuel failure and release of radioactivity. To investigate the ductility of cladding tubes used in WWER type nuclear power plants, several mandrel tests were performed in the Centre for Energy Research (EK). This modified mandrel test was used to model the mechanical interaction between the fuel pellet and the cladding using a segmented tool. The tests were conducted at room temperature and at 300 ℃ with inactive as-received and hydrogenated cladding ring samples. The results show a gradual decrease in ductility as the hydrogen content increases, the ductile-brittle transition was seen above 1500 ppm hydrogen absorbed.

Formation and Growth Estimation of Blister in Zr-2.5Nb Pressure Tubes based on Finite Element Analysis (유한요소해석을 이용한 지르코늄 압력관의 블리스터 생성 및 성장 해석)

  • Huh, Nam-Su;Kim, Yun-Jae;Kim, Young-Jin;Kim, Young-Seok;Cheong, Yong-Moo
    • Proceedings of the KSME Conference
    • /
    • 대한기계학회 2003년도 추계학술대회
    • /
    • pp.1133-1138
    • /
    • 2003
  • The pressure tubes, which contain high temperature heavy water and fuel, are within the core of a CANDU nuclear reactor, and are thus subjected to high stresses, temperature gradient, and neutron flux. Further, it is well known that pressure tubes of cold-worked Zr-2.5Nb materials result in hydrogen diffusion, which create fully-hydrided regions (frequently called Blister). Thus a proper investigation of hydrogen diffusion within zirconium-alloy nuclear components, such as CANDU pressure tube and fuel channels is essential to predict the structural integrity of these components. In this respect, this paper presents numerical investigation of hydrogen diffusion to quantify the hydrogen concentration for blister growth of CANDU pressure tube. For this purpose, coupled temperature-hydrogen diffusion analyses are performed by means of two-dimensional finite element analysis. Comparison of predicted temperature field and blister with published test data shows good agreement.

  • PDF

Development and validation of diffusion based CFD model for modelling of hydrogen and carbon monoxide recombination in passive autocatalytic recombiner

  • Bhuvaneshwar Gera;Vishnu Verma;Jayanta Chattopadhyay
    • Nuclear Engineering and Technology
    • /
    • 제55권9호
    • /
    • pp.3194-3201
    • /
    • 2023
  • In water-cooled power reactor, hydrogen is generated in case of steam zirconium reaction during severe accident condition and later on in addition to hydrogen; CO is also generated during molten corium concrete interaction after reactor pressure vessel failure. Passive Autocatalytic Recombiners (PARs) are provided in the containment for hydrogen management. The performance of the PARs in presence of hydrogen and carbon monoxide along with air has been evaluated. Depending on the conditions, CO may either react with oxygen to form carbon dioxide (CO2) or act as catalyst poison, reducing the catalyst activity and hence the hydrogen conversion efficiency. CFD analysis has been carried out to determine the effect of CO on catalyst plate temperature for 2 & 4% v/v H2 and 1-4% v/v CO with air at the recombiner inlet for a reported experiment. The results of CFD simulations have been compared with the reported experimental data for the model validation. The reaction at the recombiner plate is modelled based on diffusion theory. The developed CFD model has been used to predict the maximum catalyst temperature and outlet species concentration for different inlet velocity and temperatures of the mixture gas. The obtained results were used to fit a correlation for obtaining removal rate of carbon monoxide inside PAR as a function of inlet velocity and concentrations.