• Title/Summary/Keyword: Nuclear Fuel

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Thermal Conductivity of Compacted Bentonite and Bentonite-Sand Mixture (압축 벤토나이트 및 벤토나이트-모래 혼합물의 열전도도)

  • Cho, Won-Jin;Lee, Jae-Owan;Kwon, Sang-Ki
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.2
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    • pp.101-109
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    • 2008
  • For the Kyungju bentonite which is considered as a candidate material for the buffer and backfill in the high-level waste repository, the thermal conductivities of compacted bentonite and a bentonite-sand mixture were measured. The thermal conductivities of the compacted bentonites with a dry density of 1.2 to $1.8\;Mg/m^3$ and the bentonite-sand mixture with a dry density of 1.6 and $1.8\;Mg/m^3$ were measured within the gravimetric water content range of 10wt% to 20wt% and the sand fraction range of 10 to 30wt%. The thermal conductivity of compacted bentonite and a bentonite-sand mixture increases with increasing dry density and sand weight fraction in the case of constant water weight fraction, and increases with increasing water weight fraction and sand weight fraction in the case of constant dry density. The empirical correlations to describe the thermal conductivity of compacted bentonite and a bentonite-sand mixture as a function of water fraction at each dry density were suggested. These correlations can predict the thermal conductivities of bentonite and a bentonite-sand mixture with a difference below 10%.

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Dechlorination/Solidification of LiCl Waste by Using a Synthetic Inorganic Composite with Different Compositions (합성무기복합체 조성변화에 따른 모의 LiCl 염폐기물의 탈염소화/고형화)

  • Kim, Na-Young;Cho, In Hak;Park, Hwan-Seo;Ahn, Do-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.3
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    • pp.211-221
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    • 2016
  • Waste salt generated from a pyro-processing for the recovery of uranium and transuranic elements has high volatility at vitrification temperature and low compatibility in conventional waste glasses. For this reason, KAERI (Korea Atomic Energy Research Institute) suggested a new method to de-chlorinate waste salt by using an inorganic composite named SAP ($SiO_2-Al_2O_3-P_2O_5$). In this study, the de-chlorination behavior of waste salt and the microstructure of consolidated form were examined by adding $B_2O_3$ and $Fe_2O_3$ to the original SAP composition. De-chlorination behavior of metal chloride waste was slightly changed with given compositions, compared with that of original SAP. In the consolidated forms, the phase separation between Si-rich phase and P-rich phase decreases with the amount of $Al_2O_3$ or $B_2O_3$ as a connecting agent between Si and P-rich phase. The results of PCT (Product Consistency Test) indicated that the leach-resistance of consolidated forms out of reference composition was lowered, even though the leach-resistance was higher than that of EA (Environmental Assessment) glass. From these results, it could be inferred that the change in the content of Al or B in U-SAP affected the microstructure and leach-resistance of consolidated form. Further studies related with correlation between composition and characteristics of wasteform are required for a better understanding.

Review on Assessment Methodology for Human Intrusion Into a Repository for Radioactive Waste (방사성폐기물 처분장 인간침입 평가 방법론에 관한 고찰)

  • Cho, Dong-Keun;Kim, Jung-Woo;Jeong, Jong-Tae;Baik, Min-Hoon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.3
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    • pp.297-305
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    • 2016
  • An approach to assess inadvertent human intrusion into radwaste repository was proposed with the assumption that the intrusion occurs after a loss of knowledge of the hazardous nature of the disposal facility. The essential boundary conditions were derived on the basis of international recommendations, followed by an overall approach to deal with inadvertent human intrusion. The interrelation between societal factors, human intrusion scenarios, and protective measures is described to provide a concrete explanation of the approach, including the detailed procedures to set up the human intrusion scenario. The procedure for deriving protective measures is also explained with four steps, including how to derive a safety framework, general measures, potential measures, and eventual protective measures on the basis of stylized scenarios. It is expected that the approach proposed in this study will be used effectively to reduce the potential for and/or the consequences of human intrusion during the entire process of realizing a disposal facility.

Study of Classification and Disposal Method for Disused Sealed Radioactive Source in Korea (국내 폐밀봉선원 분류체계 및 처분방식 연구)

  • Kim, Sukhoon;Kim, Juyoul;Lee, Seunghee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.3
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    • pp.253-266
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    • 2016
  • In accordance with the classification system of radioactive waste in Korea, all the disused sealed radioactive sources (DSRSs) fall under the category of EW, VLLW or LILW, and should be managed in compliance with the restrictions for the disposal method. In this study, the management and disposal method are drawn in consideration of half-life of radionuclides contained in the source and A/D value (i.e. the activity A of the source dividing by the D value for the relevant radionuclide, which is used to provide an initial ranking of relative risk for sources) in addition to the domestic classification scheme and disposal method, based on the characteristic analysis and review results of the management practices in IAEA and foreign countries. For all the DSRSs that are being stored (as of March 2015) in the centralized temporary disposal facility for radioisotope wastes, applicability of the derivation result is confirmed through performing the characteristic analysis and case studies for assessing quantity and volume of DSRSs to be managed by each method. However, the methodology derived from this study is not applicable to the following sources; i) DSRSs without information on the radioactivity, ii) DSRSs that are not possible to calculate the specific activity and/or the source-specific A/D value. Accordingly, it is essential to identify the inherent characteristics for each of DSRSs prior to implementation of this management and disposal method.

Determinations of the Exposure Rate Using a NaI(Tl) Detector of the Environmental Radiation Monitor (환경방사선감시기의 NaI(Tl) 검출기를 이용한 조사선량률 결정방법)

  • Ji, Young-Yong;Lee, Wanno;Choi, Sang-Do;Chung, Kun Ho;Kang, Mun Ja;Choi, Geun-Sik
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.3
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    • pp.245-251
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    • 2013
  • The energy band and the G-factor method were compared to determine the exposure rate from the measured spectrum using a NaI(Tl) scintillation detector. First, G-factors of a 3"${\Phi}X3$" NaI(Tl) detector mounted to a EFRD 3300, which means the environmental radiation monitor, in Korea Atomic Energy Research Institute (KAERI) were calculated for several directions of incident photons through the MCNP modeling, and the optimum G-factor applicable to that monitor was then determined by comparing the results both the energy band method and the G-factor method. The results for these spectrometric determinations were also compared with the dose rate from a HPIC radiation monitor around a EFRD 3300. The measured value at the EFRD 3300 based on a 3"${\Phi}X3$" NaI(Tl) detector was $7.7{\mu}R/h$ and its difference was shown about $3{\mu}R/h$, when compared with the results from a HPIC radiation moditor. Since a HPIC is known to be able to measure cosmic rays with the relatively high energy, the difference between them was caused by cosmic rays which were not detected in a 3"${\Phi}X3$" NaI(Tl) detector.

A study on the electrodeposition of uranium using a liquid cadmium cathode at 440℃ and 500℃ (440℃와 500℃에서 액체카드뮴음극을 이용한 우라늄 전착에 관한 연구)

  • Yoon, Jong-Ho;Kim, Si-Hyung;Kim, Gha-Young;Kim, Tack-Jin;Ahn, Do-Hee;Paek, Seungwoo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.3
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    • pp.199-206
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    • 2013
  • Electrowinning process in pyroprocessing recovers U (uranium) and TRU (Trans Uranium) elements simultaneously from spent fuels using a liquid cadmium cathode (LCC). When the solubility limit of U deposits over 2.35wt% in Cd, U dendrites were formed on the LCC surface during the electrodeposition at $500^{\circ}C$. Due to the high surface area of dendritic U, the deposits were not submerged into the liquid cadmium pool but grow out of the LCC crucible. Since the U dendrites act as a solid cathode, it prevents the co-deposition of U and TRUs. In this study, the electrodeposition of U onto a LCC was carried out at 440 and $500^{\circ}C$ to compare the morphology and component of U deposits. The U deposits at $440^{\circ}C$ have a specific shape and were stacked regularly at the center of the LCC pool, while the U dendrites (i.e., ${\alpha}$-phase) at $500^{\circ}C$ were grow out of the LCC crucible. Through the microscopic observation and XRD analysis, the electrodeposits at $440^{\circ}C$, which have a round shape, were identified as an intermetallic compound such as $UCd_{11}$. It can be concluded that the LCC electrowinning operation at $440^{\circ}C$ achieves the co-recovery of U and TRU without the formation of U dendrites.

In Situ Solute Migration Experiments in Fractured Rock at KURT: Installation of Experimental System and In Situ Solute Migration Experiments (KURT 암반 단열에서 현장 용질이동 실험: 실험 장치 설치 및 현장 용질 이동 실험)

  • Lee, Jae-Kwang;Baik, Min-Hoon;Lee, Tae-Yeop;Park, Kyung-Woo;Jeong, Jongtae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.3
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    • pp.229-243
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    • 2013
  • An in situ solute migration system was designed and installed in KAERI Underground Research Tunnel (KURT) constructed in the site of Korea Atomic Energy Research Institute (KAERI) in order to investigate the migration and retardation of non-sorbing and sorbing tracers through a rock fracture. The system is composed of three main parts including injection, extraction, and data treatment. For the selection of a water-conducting fracture, boreholes were drilled. The fractures in the drilled boreholes were investigated using borehole image analysis using borehole image processing system (BIPS). The results of BIPS analysis showed that borehole YH 3-1 and YH 3-2 were connected each other. Moreover, hydraulic tests were carried out to determine the test section with connectivity for the in situ experiments. The in situ solute migration experiments were accomplished to understand the migration of solutes through fractures in KURT using non-sorbing tracers which were fluorescein sodium, eosin-B, bromide and sorbing tracers which were rubidium, nickel, zirconium, and samarium.

Influence of pH and Ionic Strength on Treatment of Radioactive Boric Acid Wastes by Forward Osmosis Membrane (정삼투막에 의한 붕산함유 방사성 폐액 처리를 위한 pH 및 이온강도 영향)

  • Choi, Hye-Min;Hwang, Doo-Seong;Lee, Kune-Woo;Moon, Jei-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.3
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    • pp.193-198
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    • 2013
  • In general, boron recovery of 40-90% could be achieved by Reverse Osmosis (RO) membranes in neutral pH condition. As an emerging technology, Forward Osmosis (FO) membrane has attracted growing interest in wastewater treatment and desalination. The objective of this study is to evaluate the possibility of the boron removal in radioactive liquid waste by FO. In this study, the performance of FO was investigated to remove boron in the simulated liquid waste as the factors such as pH, osmotic pressure, ionic strength of solution, etc. The pH of feed solution is a major operating parameter which strongly influences to the permeation of boron and more than 80% of boron content can be separated when conducted at pH values less than 7. The water flux is not influenced but the boron flux and permeation rate tends to decrease in the low salt concentration of 1,000 mg/L. The boron flux increases linearly, but the permeation ratio of reducing boron is nearly constant even with changes in the draw solution concentration.

Estimation of Groundwater Level Fluctuation of the Crystalline site Using Time Series Analyses in South Korea (시계열분석을 이용한 결정질암 지역의 지하수위 변동 평가)

  • Lee, Jeong-Hwan;Jung, Haeryong;Lee, Eunyong;Kim, Sujeong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.3
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    • pp.179-192
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    • 2013
  • This study is characterized the groundwater flow pattern near crystalline site of Yangbook-Myeon, Gyeong-ju City, South Korea. From the time series analyses, groundwater level could be classified into 4 types reflecting the hydrogeological characteristics and rainfall pattern. The type I (DB1-1, DB1-2) may be directly influenced by rainfall pattern. The type II (DB1-3, DB1-7, KB-1, KB-2, KB-3, KB-7, KB-14, KB-15) may be influenced by rainfall event as well as groundwater flow through water-conducting features. The type III (DB-5, DB1-6, DB2-2, KB-10, KB-11, KB-13) may be predominantly happens in the crystaline rock mass, groundwater in this type flows through the minor fracture networks rather than direct effect of rainfall event. The type IV (DB1-8, KB-9) may be influenced by irregular variation of the groundwater level due to anisotropy and heterogeneity of crystalline rock.

A Study on the Droplet Formation of Liquid Metal in Water-Mercury System as a Surrogate of Molten Salt-Liquid Metal System at Room Temperature (용융염-액체금속 계의 대용물인 물-수은 계에서 액체금속 액적의 생성에 대한 연구)

  • Kim, Yong-il;Park, Byung Gi
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.165-172
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    • 2018
  • As an approach for estimation of the droplet size in the molten salt-liquid metal extraction process, a droplet formation experiment at room temperature was conducted to evaluate the applicability of the Scheele-Meister model with water-mercury system as a surrogate that is similar to the molten salt-liquid metal system. In the experiment, droplets were formed through the nozzle and the droplet size was measured using a digital camera and image analysis software. As nozzles, commercially available needles with inner diameters (ID) of 0.018 cm and 0.025 cm and self-fabricated nozzles with 3-holes (ID: 0.0135 cm), 4-holes (ID: 0.0135 cm), and 2-holes (ID: 0.0148 cm) were used. The mercury penetration lengths in the nozzles were 1.3 cm for the needles and 0.5 cm for the self-fabricated nozzles. The droplets formed from each nozzle maintained stable spherical shape up to 20 cm below the nozzle. The droplet size measurements were within a 10% error range when compared to the Scheele-Meister model estimates. The experimental results show that the Scheele-Meister model for droplet size estimation can be applied to nozzles that stably form droplets in a water-mercury system.