• Macromolecular Research
• /
• 제12권6호
• /
• pp.581-585
• /
• 2004

A copolymer P[OSA-MI] was synthesized by copolymerization of its corresponding monomers, N-phenyl maleimide (MI) and 2-octen-l-ylsuccinic anhydride (OSA). The polymer (poly[2-[1-(2,5-dioxo-l-phenylpyrroli­din-3-ylmethyl)heptyl]-succinic acid 4-(2-$\{$ethyl-[4-(4-nitrophen-ylazo)phenyl]amino$\}$ethyl)ester]) P[DR1MA-MI] was obtained from the reaction of P[OSA-MI] with 2-[4-(4-nitrophenylazo)-N-ethylphenylamino] ethanol (DR1). A stable monolayer of P[DRIMA-MI] was formed by spreading the solution of the polymer in chloroform. In Y-type Langmuir-Blodgett (LB) films prepared using this Langmuir-Blodgett method, the second harmonic waves generated from adjacent mono layers canceled each other out. In X-and Z-type LB films, the second harmonic intensity increased upon increasing the number of monolayers, but this increase was somewhat smaller than predicted by the square law. This phenomenon is due to defects or imperfect alignment of the dipoles in the LB film. The generation of second harmonic waves from Y-type LB films having an even number of mono layers supports this argument. The degree of imperfection seemed to increase as the number of layers increased. The second-order nonlinear optical properties of spin-cast films of these polymers were also measured. The largest second harmonic coefficient of the poled P[DRIMA-MI] film coated on a glass plate was 19 pm/V.

• 한국광학회지
• /
• 제17권1호
• /
• pp.1-6
• /
• 2006

우리는 6.7 kPa의 네온 버퍼가스가 포함된 루비듐 증기셀을 이용하여 $^{87}Rb$원자 $D_1$ 전이선에서 레이저의 세기, 증기 셀의 온도, 전이 선에 따른 비선형 광자기 신호(NMOE)의 특성을 조사하였다. 비선형 광자기 신호는 레이저의 세기와 증기셀의 온도가 증가함에 따라 F=2$\to$F'=2 전이선에서는 광자기 신호의 크기와 선폭이 증가하였지만, F=2$\to$F'=1 전이선에서는 확대 없이 신호의 크기만 증가됨으로써 자장 측정 민감도가 향상되는 것을 확인하였으며, 이러한 효과를 자기부준위 사이에서의 원자결맞음 구도의 차이로 설명하였다. 관측된 최적 조건에서 자기장변화에 대한 민감도는 $70pT/\sqrt{Hz}$ 이하로 계산되었다.

• Journal of the Optical Society of Korea
• /
• 제2권2호
• /
• pp.64-73
• /
• 1998

We have theoretically analyzed and experimentally observed the effects of wavelength dependent birefringence inside a laser cavity on the output characteristics of fiber lasers with a figure eight geometry. The spectral and polarization characteristics of fiber lasers are found to be very susceptible to the resultant birefringence composed of the intrinsically existing wavelength dependent birefringence and the externally induced birefringences inside the fiber. For the variation of twist-induced birefringence inside the nonlinear amplifying loop mirror, the laser output power and center wave-length of continuous wave lasers change periodically, but the polarization characteristics remains nearly unchanged. The changes of the birefringence inside the linear loop has little effect on the spectral characteristics but changes the polarization properties such as the polarization direction.

• 한국세라믹학회지
• /
• 제35권5호
• /
• pp.493-498
• /
• 1998

ZnS doped borosilicate glass for nonlinear optical application was prepared by melting and precipitation process. The optical band gap of the precipitated ZnS particles ranged from 3.83 to 3.96 eV compared with the bulk ZnS energy gap of 3.53 eV. This result was interpreted in terms of a quantum confinement effect due to small crystal size. ZnS partilcle size estimated by effective mass approximation ranged from about 39 to 83 $\AA$ It increased wtih the increase of heat tratment time and temperature.

• 한국광학회:학술대회논문집
• /
• 한국광학회 2003년도 제14회 정기총회 및 03년 동계학술발표회
• /
• pp.232-233
• /
• 2003

Quasi-phase-match (QPM) can be realized by means of one-dimensional spatial modulation of second-order nonlinear susceptibility and has advantages over the conventional bulk phase-matching method because QPM can not only utilize the largest component of second-order nonlinear susceptibility tensor, but also can circumvent walk-off effect. (omitted)

• Bulletin of the Korean Chemical Society
• /
• 제24권11호
• /
• pp.1671-1674
• /
• 2003

The effects of amine donors ($a:NH_2,\;b:NMe_2,\;c:NMePh,\;d:NPh_2$) and conjugation length on the molecular hyperpolarizabilities of a series of dipolar molecules have been theoretically investigated by using CPHF/6-31G method. The first hyperpolarizabilities (${\beta}$) of p-nitrobenzene derivatives increase with the donor in the order, $NH_2\;<\;NMe_2\;<\;NMePh\;<\;NPh_2$, whereas slightly different order is observed in more conjugated derivatives, i.e., $NH_2\;<\;NPh_2\;<\;NMe_2\;<\;NMePh$. The result has been attributed to the extent of charge transfer and torsion angle. Moreover, the results show that "non-traditional" ${\pi}$-conjugation effect exists in small compounds and decreases as the conjugation length between donor and acceptor increases.

• 한국항행학회논문지
• /
• 제25권6호
• /
• pp.517-522
• /
• 2021

장거리 파장 분할 시스템을 위해 해결해야 하는 광 색 분산과 비선형 현상에 의한 광 신호 왜곡을 보상할 수 있는 광 위상 공액과 결합된 분산 제어 링크를 네트워크 토폴로지의 유연성 관점에서 제안하고 분석하였다. 비선형 효과에 의해 왜곡되는 광 신호의 보상을 위해 적용된 광 위상 공액기는 전체 전송로 중간이 아닌 곳에 위치시켰다. 그리고 광 위상 공액기를 중심으로 전반 전송 구획과 후반 전송 구획을 구성하는 각각의 중계 구간의 잉여 분산 (RDPS; residual dispersion per span)을 서로 다르게 한 분산 제어 링크를 적용하였다. 각 중계 구간의 RDPS가 전반 전송 구획과 후반 전송 구획의 전체 잉여 분산을 같게 만드는 값이 아닌 그 근처의 서로 다른 값으로 결정되어야 왜곡된 광 신호 보상에 효과적이라는 것을 시뮬레이션 결과를 통해 확인하였다.

• 대한화학회지
• /
• 제37권1호
• /
• pp.62-67
• /
• 1993

Quinoline계 화합물인 미시적 비선형 광학 특성을 설명하기 위해 반경험적인 AMI 방법을 사용하여 초분극률을 계사하였다. Quinoline 고리에서 이차 비선형 특성에 기여하는 전자공여체, 아미노기와 전자수여체, 니트로기의 반응 위치를 변경하여 미시적 비선형 상수에 대한 이론적 영향을 조사해 보았다. 이차와 삼차 비선형 주쇄고분자로서 물리적, 기계적 성질이 우수한 polyquinoline계 고분자를 이용하기 이해 polyquinoline계 반복단위와 유사한 단분자 quinoline들을 설계하여 각각의 미시적 비선형 상수 및 바닥상태의 쌍극자 모멘트 등을 유한 전기장하에서 계산하여 서로 평가 비교해 보았다.

• Journal of electromagnetic engineering and science
• /
• 제3권2호
• /
• pp.79-85
• /
• 2003

In this paper, we investigated the degree of compensation for distorted optical pulse of wavelength division multiplexed(WDM) channel with initial frequency chirp generated in optical transmitter. The WDM channel signal distortion is due to chromatic dispersion, self phase modulation(SPM) and cross phase modulation(XPM) in fiber. The considered system is 3 ${\times}$ 40 Gbps intensity modulation direct detection(IM/DD) WDM transmission systems, which adopted mid-span spectral inversion(MSSI) as compensation method. We confirmed that the effect of initial frequency chirp on compensation for signal distortion due to a SPM is gradually decreased as a dispersion coefficient of fiber becomes gradually small. But, in the aspect of a compensation for signal distortion due to both SPM and XPM, the effect of initial frequency chirp on compensation is gradually decreased as a dispersion coefficient of fiber becomes gradually large.

• Journal of information and communication convergence engineering
• /
• 제5권3호
• /
• pp.273-280
• /
• 2007

The numerical methods for finding the optimal parameters in 640 Gbps (16 channels $\times$ 40 Gbps) WDM system with optical phase conjugator (OPC) are proposed, which effectively compensate the distorted overall WDM channels. The considered optimal parameters are the OPC position and the dispersion coefficient of fibers. The numerical approaches are accomplished through two different procedures. One of these procedures is that the optimal OPC position is previously searched and then the optimal dispersion coefficient is searched at the obtained optimal OPC position. The other is the reverse of the above procedure. From the numerical results, it is confirmed that two optimal parameters depend on each other, but less related with the searching procedure. The methods proposed in this research will be expected to alternate with the method of making a symmetrical distribution of power and local dispersion in real optical link which is a serious problem of applying the OPC into multi-channels WDM system.