• Title/Summary/Keyword: Nonionic

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The Effects of Solvents in Reservior Solution on Protein Crystallization Using Vapor Diffusion method (증기확산법에 의한 단백질 결정화에 미치는 Reservicr 용액의 영향)

  • 이정희;정용제
    • Korean Journal of Crystallography
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    • v.5 no.1
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    • pp.33-38
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    • 1994
  • 'Heterogeneous' vapor diffusion experiments were carried out using hen egg white Iysozyme and equine serum albumin as model proteins: droplets were equilibrated against reservoir solutiorls containing an alternative precipitant which is different from results showed that the use of polyethylene glycol as an alternative precipitant instead of NaCl or ammonium sulfate reduces equilibration rate between droplet and reservoir solution. By using the heterogeneous vapor diffusion techniqlue it is possible to control the equilibration rate by adjusting the relative amounts of ionic salts and nonionic yecipitants in reservoir solutions.

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The Effect of Nonionic Surfactants on the Solubility and Biodegradation of PAHs in Soil Slurry (PAHs의 용해도와 생분해에 미치는 비이온계 계면활성제의 영향)

  • 박종섭;김인수
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.174-177
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    • 1998
  • The effects of surfactants affecting polycyclic Aromatic Hydrocarbon(PAHs) solubility and biodegradation in soil slurry were investigated. The critical micelle concentration(CMC) values of surfactants used in this study were 12.7mg/L(Brij 30), 13.4mg/L(Tween 80), 13.6mg/t(Triton X-100). The solubility of PAH increased as the Hydrophile-Lipophile Balance(HLB) value of surfactant decrease. At surfactant biodegradation and toxicity experiement using respirometer, Brij 30 did not show any toxic effect and substrate inhibition upon the level of 1.5g/L. Also, biodegradation of Brij 30 gave no reduction on the phenanthrene biodegradation rate. When the desorption rate of phenanthrene between sand and clay is compared, lower percentage of phenanthrene was desorbed at clay because of the larger surface aera and higher organic content of clay. At the biodegradation experiments of phenanthrene in soil slurry phase, more than 90% of initial phenanthrene adsorbed onto both sand and clay were biodegraded by phenanthrene- acclimated cultures.

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An Experimental Study on the Characteristics of Evaluation with Feature of Self Levelling Primer (셀프레벨링 모르타르용 Primer 성상에 따른 특성평가에 관한 실험적 연구)

  • Kang, Dong-Gyun;Kim, Gyung-Yuk;Kim, Jung-Wan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.505-508
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    • 2006
  • Self-leveling mortar is walkable bottom mortar which can maintain the horizontality of self fluid and have the the quick-setting quality, the low-human-effort practicable material of high-quality bottom in construction. In accordance with more adhesive strength with bottom side and absorption control, Primer is used for purpose to prevent pin-hole occurrence by self leveling mortar application prior to construction. This study is composed measurement of absorption, adhesive strength. Used material is NP-40 as nonionic emulsifying agent, uses SA-210L as negative ion emulsifying agent, uses APS, SBS as ridical initiator. A result of test, in accordance with image of Primer, as low temperature and application frequency, indicates low absorption rate and adhesive strength, as solid powder and dryness time is increse, absorption rate and adhesive strength lowly shows figure.

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A study on the removal of triglyceride from cotton fabric (면포에서 Triglyceride 단독 오염의 세척성에 관한 연구)

  • 곽혜원
    • Journal of the Korean Home Economics Association
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    • v.23 no.1
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    • pp.19-24
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    • 1985
  • The effect of temperature, washing time, mechanical agitation and concentration on the removal from cotton fabrics of tripalmitin labelled with C\sup 14\ were studied. In order to correlate the detergency with the removal mechanism, solubilization and suspending power of surfactants were observed. RESULTS : 1. The detergency from cotton fabric was increased with elevating temperature and over the temperature of maximum detergency, the rate of soil removal was rather decreased. 2. The effects of washing time and mechanical agitation on the removal of triplamitin were obvious at lower temperature. 3. The removal of tripalmitin was remarkably increased at higher concentration over cmc for all surfactants. The detergency of nonionic surfactant -NPPG- was best, this was resulted from its large solubilization and suspending power.

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Synthesis, Characterization, and Properties of Ethoxylated Azo Dyes

  • Shen, Kaihua;Choi, Dong Hoon;Li, Zongshi
    • Fibers and Polymers
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    • v.4 no.1
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    • pp.32-37
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    • 2003
  • The nonionic surfactant properties of ethoxylated azo dyes, such ai cloud point and surface tension have been investigated. The synthesized ethoxylated azo dyes could dye polyester fabric without any special pre-treatment. When the average number of ethylene oxide (EO) in the ethoxylated azo dye reached 6, its fixation could exceed $90^{\circ}C$ from the thermosol dyeing process. The average degree of condensation of ethylene glycol in the chain was interrelated with the dyeing results and did not affect on the maximum absorption wavelength (λmax) of the polyoxyethylene dye. When the average length of polyoxyethylene chain decreased, the molecular weight of dyes became smaller and the fixation of dyes was improved.

Preparation and Dispersion Characteristics of Oil-based Magnetic Fluids with Synthesized Magnetite (합성마그네타이트를 이용한 유상자성유체의 제조 및 분산특성)

  • Cho, Myeong-Ho;Kim, Mahn;Min, Dong-Joon;Oh, Jae-Hyun
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.901-908
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    • 1996
  • The oil-based magnetic fluids were prepared with synthesized ultrafine magnette by allowing surfactactants such as sodium oleate and aliquat 336 to adsorb on the surface of magnetite particles. The dispersion ratio of oil-based magnetic fluids was higher than 90% when the amount of sodium oleate and aliqua 336 were more than 2.63$\times$10-2 mol and 6.56$\times$10-3 mol for 20g of magnetite respectively. The dispersion ratio of oil-based magnetic fluids with the amount of secondary surfactant addition was higher than 90% when oil-based magnetic fluids were prepared with aliquat 336 of cationic type. However oil-based magnetic fluids prepared with surfactants of anionic and nonionic type showed lower dispersion than whose with cationic surfac-tants.

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The Effect of Interface Activation Substances in Reduction Phenomena of Streaming Electrification for Transformer Oil (변압기유의 유동대전 감소현상에 미치는 계면활성제의 효과)

  • Kim, Yong-Woon;Lee, Duck-Chool;Watanabe, Shigeo
    • Proceedings of the KIEE Conference
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    • 2000.07e
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    • pp.48-51
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    • 2000
  • The purpose of this study is to find the way to reduce the electrostatics by interface activation substances added in the insulating oil with concentration[ppm]. As results, The streaming current, surface tension and viscosity of the samples added nonionic and hermaphrodic substances are decreased but the conductivity is increased at higher point than the 1[ppm](c.m.c.), the other side the same phenomena of the samples added cationic and anionic substances are discovered at the 10[ppm].

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The Effect of Nonionic Interface Activation Substances in Reduction Phenomenon of Streaming electrification (유동대전 감소현상에 미치는 비이온성 계면활성제의 효과)

  • Kim, Y.W.;Chung, K.H.;Yoo, K.M.;Yoo, J.H.;Lee, E.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1410-1412
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    • 1998
  • The purpose of this study is to find the way to prevent the electrostatics from the interface of liquid and solid by adding interface active substances to the insulating oil with concentration. As results, The streaming current, surface tension, and viscosity decreased and conductivity increased at the higher point than the c.m.c. which resulted from, the adding of the interface active substances.

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Free and Glycosidically Bound Volatile Components in Tobacco Leaves(Nicotiana tabacum L.) (잎담배중 유리 및 Glycoside형태로 존재하는 휘발성 향기성분)

  • 김영회;나도영;김옥찬;서철원;김용태
    • Journal of the Korean Society of Tobacco Science
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    • v.14 no.1
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    • pp.79-86
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    • 1992
  • Free and glycosidically bound volatiles from three green tobacco leaves(NC 82, KF 109 and Br-21) were separated by nonionic resin Amberlite XAD-2 adsorption column chromatography and election by selective solvents. Aglycones from the glycosidically bound fractions were released by enzymatic hydrolysis with almond B-glucosidase. A total of 20 components identified from free and glycosidically bound fractions, the major components were benzaldehyde, benzyl alcohol, 2-phenylethyl alcohol, 3-oxo- -ionol, 3-hydroxy-B-ionone, 3-oxo-7, 8-dihydro-n-ionol and scopoletin. Six Cl.B norisoprenoids identified in this study, which have been described to possess a characteristic tobacco aroma-enhancing effect, were not presented in free forms but rather bound glycosidic forms.

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Kinetic Studies on the Ligand Substitution Reactions of Cyanocobalt(II) Complexes in Micellar Solutions (미셀용액에서 Cyanocobalt(II) 착물의 리간드치환 반응에 대한 속도론적 연구)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.370-378
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    • 2009
  • Kinetic studies on the ligand substitution reactions of cyanocomplexes were performed in several micellar solutions. It showed the observed rate constants was found to be independent of the entering ligand concentration at high concentration of cyanopyridine and pyrazinecarboxylate. We could see also that in nonionic and anionic micellar solutions no influence of changes in the surfactant concentration on the observed rate constants was found. Taking into account the hydrophilic nature of the cobalt complex, the cobalt complex molecule was expected to be located in the aqueous phase of the micellar systems, where the reaction would take place. In cationic micellar solutions, a small increase in the observed rate constant was found when the cationic surfactant concentration increased. After reaching a maximum, the rate constant decreased on increasing surfactant concentration and subsequently it reached a plateau, where the observed rate constant was independent of changes in the surfactant concentration.