• Title/Summary/Keyword: Nonionic

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Characterization of Emulsion Properties for D-limonene (D-리모넨 오일의 유화특성)

  • 하윤식;장윤호;문현수;이정경;서무룡
    • Journal of Environmental Science International
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    • v.7 no.6
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    • pp.875-881
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    • 1998
  • Microemulsion is prepared by the method of phase inversion emulsification with d-limonene that is environmental friendly substance and nontoxic to human body as dispersed phase. Emulsifier used for preparation of microemulsion is nonionic surfactants, polyoxyethylene nonylphenyl ether. Stability of prepared microemulsion was estimated by the various method of ξ-potential, hydrodynamic diameter and electric conductivity. When d-limonene is emulsified by NP series, microemulsion is most stable and narrowly distributed at HLB value of 12.3(either one emulsifier or mixed emulsifiers). Stability of microemulsion is increased as the amount of emulsifiers is increased at same HLB value of 12.3. In the case of using the same amount of emulsifiers, number of produced micelle are relatively large as hydrodynamic diameter is small. Therefore, the state of microemulsion is stable and the electric conductivity is increased. One can determine that higher electric conductivity value means that microemulsion has more micelles and is more stable.

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Influence of Conductivity and Anionic Trashes on Adsorption Behavior of Cationic Starches (전기전도도와 음이온성 트래쉬에 따른 양상전분의 흡착 거동변화)

  • 허동명;이학래
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.3
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    • pp.10-18
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    • 1999
  • The influence of simple electrolyte or anionic trashes on cationic starch adsorption was examined using deinked pulp and bleached thermomechniical pulp. Adsorbed amounts of cationic starches increased slightly , then decreased abruptly as the concentration of simple electrolyte increased. This phenomenon was discussed based on the compression of electrical double layer and conformation change of starch molecules. Also, the effect of the type of simple electrolytes on starch adsorption was examined and discussed. Addition of sodium slilicate increased starch adsorption since it increased surface charge density of fibers. On the other hand, addition of kraft lignin decreased cationic demand of the pulp slurries and adsorbed amounts of cationic starches. Nonionic surfactant did not show any significant effect on the cationic demand of pulp slurries. When simple electrolytes were added to the stock , grater adsorption or cationic starches was obtained with starches of lower degree of substitution . On t도 other hand, amount of adsorbed starches decreased for lower DS starches when the concentration of anionic trashes increased.

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Deinking of Laser-printed Paper Using Enzyme (효소를 이용한 레이저 인쇄된 고지의 탈묵)

  • 안병준;백기현
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.2
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    • pp.16-24
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    • 1997
  • This experiment was mainly performed with a biological treatment of laser printed paper using enzyme, We got the following conclusions : In the case of nonionic surfactant treatment, brightness, residual ink contents and several strength properties of deinked paper were excellent at the low dosage of cellulase 0.05%. When mixed cellulase and xylanase was used, yield was increased as the dosage increased up to 0.2%, but brightness was decreased at the same condition. In contrast, deinking efficiency of anionic type was reduced in terms of brightness, residual ink contents, and tensile strength. As flotation time was increased, yield decreased and brightness increased slightly. On the other hand, the addition of surfactant during repulping process showed better result than that during flotation process.

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Improving the Color Fastness of the Madder Extract on Tencel Nonwoven (인도 꼭두서니로 염색한 텐셀 부직포의 염색 견뢰도 향상에 관한 연구)

  • Lee, Bum Hoon
    • Textile Coloration and Finishing
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    • v.31 no.4
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    • pp.241-248
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    • 2019
  • In this study, improving the wash and rubbing fastness of a natural coloring matter from Madder extract dyed on Tencel nonwoven. The cationic finishing agent(RBP), nonionic finishing agent(HPX) and mordant(PAW) were used to improving the color fastness. The two types(exhaustion and pad-dry-cure) finishing process were investigated with various finishing agent concentration. The color strength, wash and rubbing fastness of Tencel nonwoven dyed with Madder extract have been evaluated by various dye concentration and finishing agent. The exhaustion process treated with the cationic finishing agent(RBP) was effective to improving washing and rubbing fastness.

Studies on the Viscoelasticities of Acetal Type Nonionic Surfactants (아세탈형(型) 비(非)이온성(性) 계면활성제(界面活性劑)의 점탄성(粘彈性)에 관한 연구(硏究))

  • Shon, Joo-Hwan;Lee, Seung-Youl;Nam, Ki-Dae;Kim, Yu-Bae
    • Journal of the Korean Applied Science and Technology
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    • v.5 no.1
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    • pp.53-62
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    • 1988
  • Properties of aqueous solution, that is, the viscosities and solubilities of benzene were observed in relation to critical micelle concentration of each alkyl aldehyde polyoxyethylene glycol acetal type surfactant. These showed that the mininum points in specific viscosity/concentration-concentration curves were corresponded with the critical micelle concentration obtained by surface tension and appeared the remarkable increase of non-Newtonics according to the increase of the number of carbon in hydrophobic groups. The fluidity of non-Newtonics is not observed by a little increase of the degree of polymerization in polyoxyethylene glycol groups.

A Molecular Associating Lattice Model for Mixtures Containing Amphiphiles (양친매성 물질을 함유한 혼합물을 위한 회합성 격자모델)

  • Shin, Moon-Sam
    • Proceedings of the KAIS Fall Conference
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    • 2012.05a
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    • pp.177-181
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    • 2012
  • Association is an important contribution to the overall hydrogen bonding in surfactant systems, especially in systems of colloidal and biological interest. Amphiphile systems, especially micelle and microemulsion systems, showed highly non-ideal behavior due to the intermolecular association and intramolecular association. The objective of this research is to present a lattice fluid equation of state that combines the quasi-chemical nonrandom lattice fluid model with modified Veytsman statistics for intra + inter molecular association to calculate phase behavior for mixture containing surfactant systems. The present EOS could correlate the literature data well for mixtures containing nonionic surfactant systems.

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Relation of $\Ca^{2+}$-ATPase and trigger peptidase(TPase) that are Membrane Proteins in a Differentiation Process on Heterobasidiomycerous Yeast (이담자 효모균의 성분화과정에서 막단백질 중 $\Ca^{2+}$-ATPase와 trigger peptidase(TPase)의 상호관계)

  • 정영기;이태호;정경태
    • Microbiology and Biotechnology Letters
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    • v.22 no.1
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    • pp.1-6
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    • 1994
  • We have studied the relation between Ca$^{2+}$-ATPase and trigger peptidase(TPase) which are membeane protein well known as their significant role for signal transduction of mating pheromone in heterobasidiomycetous yeast. Rhodosporidium toruloides. We found out that there were Ca $^{2+}$-ATPase and TPase together in isolated calmodulim binding protein(CBP), usion calmodulin affinity column chromatography after solubilization of mation type a cell membrane protein, and that the dependence of enzyme activity of both the enzymes on Ca$^{2+}$, phospholipid and nonionic detergent are similar. However, Ca$^{2+}$-ATPase hed quite absolute dependence on calmodulin and, on the other hand, TPase didn't have any dependence. Judging from the fact that there are both enzymes in CBP which the dependence of calmodulin are quite different, we found out that both enzymes were made to their compound and existed in mating type a cell membrane.

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Polymers with Phosphodiester Bonds: from Models of Biopolymers to Liquid Membranes and Polymer-Inorganic Hybrids

  • Penczek, Stanislaw
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.89-89
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    • 2006
  • Polyalkylene phosphates - polymers that are built on the repeating unit of the diester of phosphoric acid: -[OP(O)(OH)Oalkylene]-, are known to form backbones of nucleic and teichoic acids. Various synthetic ways will be reported for the synthesis of the bare chains, where "alkylene" in the formula above means mostly two or three methylene groups. Some other structures have also been prepared. Several applications of these polymers are to be discussed, namely as liquid membranes, as components of two-block copolymers (ionic-nonionic diblock dihydrophilic) used as modifiers of CaCO3 crystallization, and as components of the inorganic-polymer hybrid materials. Some other applications in the biomedical field will also be discussed.

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Solubility of methyl paraben and MIC to E. coli in non-ionic solutions (비이온성 계면활성제 용액에서 methyl paraben의 용해도와 대장균에 대한 최소억제농도의 변화)

  • 정교민
    • Korean Journal of Microbiology
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    • v.19 no.3
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    • pp.103-107
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    • 1981
  • Increasing the concentration of the nonionic surfactants the solubility of methyl paraben was increased. This is called the solubilization phenomenon and caused inactivation of the preservatives used. The MICs(minimum inhibitory concentrations) on E. coli were increased at the same time. So the relation between the solubility and the mic could be expressed as $S-S_0=R^{\prime}/R^{\prime\prime}\;(M-M_0)$ and in this case $R^{\prime}/R^{\prime\prime}$ was about 2.

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