• 한국산업융합학회 논문집
• /
• 제6권4호
• /
• pp.269-275
• /
• 2003

A non-thermal plasma process combined with $Cr_2O_3/TiO_2$ catalyst was applied to the decomposition of trichloroethylene (TCE). A dielectric barrier discharge reactor operated with AC high voltage was used as the non-thermal plasma reactor. The effects of reaction temperature and input power on the decomposition of TCE and the formation of byproducts including HCl, $Cl_2$, CO, NO, $NO_2$ and $O_3$ were examined. At an identical input power, the increase in the reaction temperature from 373 K to 473 K decreased the decomposition of TCE in the plasma reactor. The presence of the catalyst downstream the plasma reactor not only enhanced the decomposition of TCE but also affected the distribution of byproducts, significantly. However, synergistic effect as a result of the combination of non-thermal plasma with catalyst was not observed, i.e., the TCE decomposition efficiency in this plasma-catalyst combination system was almost similar to the sum of those obtained with each process.

• 한국연소학회지
• /
• 제11권3호
• /
• pp.1-7
• /
• 2006

A reaction mechanism of methane partial oxidation, which consists of thermal and plasma chemistry reaction pathways, has been investigated using with an arc-jet reactor. The reaction zone of the arc-jet reactor is spatially separated into thermal and non-thermal plasma zone. Methane conversion rates, selectivity of $H_2$ and $C_2$ chemicals in each zone are obtained, which reveals clearly different characteristics of reaction pathways depending on the temperature conditions. The conversion rates obtained in thermal plasma zone is higher than those in non-thermal plasma zone. The selectivity, however, obtained in non-thermal plasma zone is significantly higher than those in thermal plasma zone. Further parametric study on $O_2/C$ ratio, arc length and SED shows that the present process is mainly governed by thermal chemistry pathways.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 1998년도 제17회 KOSCI SYMPOSIUM 논문집
• /
• pp.31-36
• /
• 1998

An experimental study has been performed to characterize fundamental aspects of VOCs removal using non-thermal palsma technique. The removed VOCs in the present study are toluene ($C_6H_5CH_3$), ethene ($C_2H_4$), propene ($C_3H_6$) which are typical air pollutants generated from industry and automobile engines. The non-thermal plasma used in the present experiments has been produced in a wire-cylinder reactor with pulsed corona or a packed-bed reactor filled with ceramic bead. These differently generated non-thermal plasma have been visualized with an intensified CCD. The images of non-thermal plasma have been used for optimal design of a corona reactor used in the present study. The experimental results show that the removal efficiencies of VOCs with non-thermal plasma are dependant on the reactivity of VOCs with OH, O, and $O_3$. The results also show that the removal efficiencies of VOCs decrease significantly when VOCs are treated with NO that is also oxidized in the presence of OH, O, and $O_3$.

• Korean Chemical Engineering Research
• /
• 제50권2호
• /
• pp.343-347
• /
• 2012

충전형 저온 플라즈마 반응기 내에서의 가스 상 시안화합물의 분해특성을 반응기로 투입되는 방전 전력, 시안화합물의 유입농도, 운반기체인 공기의 습도 및 반응기 내의 충전물질 등을 변수로 연구하였다. 저온플라즈마 방전의 경우 시안화합물들의 분해는 트리클로로에틸렌에 비하여 상대적으로 매우 낮은 효율을 보였다. 그러나 플라즈마 방전 영역에 알루미나 또는 백금/알루미나 구슬을 충전한 경우 분해효율이 크게 높아졌으며 이는 플라즈마 반응과 더불어 백금/알루미나의 촉매작용에 의한 촉매 반응이 동시에 작용함에 기인한 것으로 판단된다.

• 한국대기환경학회지
• /
• 제16권3호
• /
• pp.247-256
• /
• 2000

Basic characteristics of non-thermal plasma process to remove C2H4 and NO have been experimentally investigated with a packed-bed type reactor and an ac power supply. The performance of the non-thermal plasma generated by ac power supply was compared with that of a wire-plate type reactor equipped with a pulsed power supply. The result shows that the non-thermal plasma can be effectively generated with an AC power supply that can be easily fabricated with conventional techniques. In order to understand the basic reaction mechanisms of the non-thermal plasma process, parametric tests for different carrier gases(air and nitrogen) and for different reaction pathways have been performed. The test results show that O3 generated by non-thermal plasma plays an dominant role to oxidize C2H4 and NO over N and O radicals when these pollutant gases are carried by dry air under room temperature condition. Experimental observations, however, indicate that N and O radicals can significantly affect on the removal process of the pollutant gases under certain conditions.

• 한국대기환경학회지
• /
• 제19권2호
• /
• pp.157-165
• /
• 2003

A combined process of non-thermal plasma and catalytic technique has been investigated to treat $CH_3$CN gas in the atmosphere. A planar type dielectric barrier discharge (DBD) reactor has been used to generate the non-thermal plasma that produces various chemically active species, such as O, N, OH, $O_3$, ion, electrons, etc. Several different types of the beads. which are Molecular Sieve (MS) 5A, MS 13X, Pt/alumina beads, are packed into the DBD reactor, and have been tested to characterize the effects of adsorption and catalytic process on treating the $CH_3$CN gas in the DBD reactor. The test results showed that the operating power consumption and the amounts of the by-products of the non-thermal plasma process can be reduced by the assistance of the adsorption and catalytic process.

• 한국자동차공학회논문집
• /
• 제14권4호
• /
• pp.1-11
• /
• 2006

The aim in this study is to develop the combined EGR system with a non-thermal plasma reactor for reducing exhaust emissions and improving fuel economy in turbo intercooler ECU common-rail diesel engines. In this study, the characteristics of soot, CO and $CO_2$ emissions under four kinds of engine loads are experimentally investigated by using a four-cycle, four-cylinder, direct injection type, water-cooled turbo intercooler ECU common-rail diesel engine with a combined plasma exhaust gas recirculation(EGR) system operating at three kinds of engine speeds. The EGR and non-thermal plasma reactor system are used to reduce $NO_x$ emissions, and the non-thermal plasma reactor and turbo intercooler system are used to reduce soot and THC emissions. The plasma system is a flat-to-flat type reactor operated by a plasma power supply. The fuel is sprayed by pilot and main injections at the variable injection timing between BTDC $15^{\circ}$ and ATDC $1^{\circ}$ according to experimental conditions. It is found that soot emissions with increasing EGR rate are increased, but are decreased as the applied electrical voltage of the non-thermal plasma reactor is elevated at the same engine speed and load. Results also show that CO and $CO_2$ emissions are increased as EGR rate is elevated, and CO emissions are increased, but $CO_2$ emissions are decreased as the applied electrical voltage of the non-thermal plasma reactor is elevated at the same engine speed and load.

• 한국자동차공학회논문집
• /
• 제14권3호
• /
• pp.10-21
• /
• 2006

The aim in this study is to develop the combined EGR system with a non-thermal plasma reactor for reducing exhaust emissions and improving fuel economy in turbo intercooler ECU common-rail diesel engines. At the first step, in this paper, the characteristics of performance and $NO_x{\cdot}THC$ emissions under four kinds of engine loads are experimentally investigated by using a four-cycle, four-cylinder, direct injection type, water-cooled turbo intercooler ECU common-rail diesel engine with a combined plasma exhaust gas recirculation(EGR) system operating at three kinds of engine speeds. The EGR system is used to reduce $NO_x$ emissions, and the non-thermal plasma reactor and turbo intercooler system are used to reduce THC emissions. The plasma system is a flat-to-flat type reactor operated by a plasma power supply. The fuel is sprayed by pilot and main injections at the variable injection timing between BTDC $15^{\circ}$ and ATDC $1^{\circ}$ according to experimental conditions. It is found that the specific fuel consumption rate with EGR is increased, but the fuel economy is better than that of mechanical injection type diesel engine as compared with the same output. Results show that $NO_x$ emissions are decreased, but THC emissions are increased, as the EGR rate is elevated. $NO_x$ and THC emissions are also slightly decreased as the applied electrical voltage of the non-thermal plasma reactor is elevated. Thus one can conclude that the influence of EGR in $NO_x$ and THC emissions is larger than that of the non-thermal plasma reactor, but THC emissions are greatly influenced by the non-thermal plasma reactor as the EGR rate is elevated.

• 상하수도학회지
• /
• 제25권6호
• /
• pp.815-824
• /
• 2011

In this study, a non-thermal plasma system was employed to simultaneously remove odorous compounds and organic sludge. The system consisted of two reactors; the first one was the non-thermal plasma reactor where ozone was produced by the plasma reaction and the ozone oxidized hydrogen sulfide, the model odorous compound, and then the ozone-laden gas stream was introduced to the second reactor where wasted sludge was disintegrated and solubilized by ozone oxidation. In this study, the gas retention time (GRT) and the hydraulic retention time (HRT) were changed in the two-reactor system, and the effects of GRT and HRT on reduction efficiencies of odor and sludge were determined. As the GRT increased, the ozone concentration increased resulting in an increasing efficiency of hydrogen sulfide removal. However, the overall ozone loading rate to the second sludge reactor was the same at any GRT, which resulted in an insignificant change in sludge reduction rate. When HRTs in the sludge reactor were 1, 2, 4 hours, the sludge reduction rates were approximately 30% during the four-hour operation, while the rate increased to 70% at the HRT of 6 hours. Nevertheless, at HRTs greater than 4 hours, the solubilization efficiency was not proportionally increased with increasing specific input energy, indicating that an appropriate sludge retention time needs to be applied to achieve effective solubilization efficiencies at a minimal power consumption for the non-thermal plasma reaction.

• 한국대기환경학회지
• /
• 제12권4호
• /
• pp.487-494
• /
• 1996

Simultaneous effects of $C_2H_4$ injection and heterogeneous chemical reactions on non-thermal plasma process to remove $SO_2$ and NOx from flue gas were investigated in the present experimental study. The present results showed that 40% of the electrical power can be reduced in $C_2H_4$ injection and heterogeneous chemical reaction are simultaneously included in the non-thermal plasma precess. As an effort to apply the non-thermal plasma technique to practical flue gas treatment system, a wire-plate type reactor which has technically similar geometry of industrial electrostatic precipitators is used instead of other types of reactors, such as wire-cylinder, packed-bed and surface discharge which are inappropriate to industrial application. In the present study, the photo pictures of positive streamer corona taken by ICCD camera, voltage and current oscillograms, and design criteria of a wire-plate type reactor are also shown, which are needed for industrial application of the non-thermal plasma process.