• Journal of Magnetics
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• v.16 no.3
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• pp.308-311
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• 2011

In order to obtain mono-dispersed Fe NPs with high saturation magnetization, quantitative analysis method to investigate the growth dynamics of the Fe NPs synthesized by a conventional thermal decomposition method has been developed. As a result, fast nucleation process promotes formation of ~4 nm of initial nucleus with a non-equilibrium phase, resulting in low saturation magnetization. And slow particle growth with atomic-scaled surface precipitation mode (< 100 atoms/($min{\cdot}nm^2$)) can form the growth layer on the surface of initial nucleus with high saturation magnetization (~190 emu/$g_{Fe}$) as an equilibrium a phase of Fe. Therefore, higher stabilization of small initial nucleus generated just after the injection of $Fe(CO)_5$ should be one of the key issues to achieve much higher $M_s$ of Fe NPs.

• Journal of Powder Materials
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• v.6 no.4
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• pp.314-319
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• 1999

The solid state reaction by mechanical alloying(MA) generally proceeds by lowering the free energy as the result of a chemical reaction at the interface between the two adjacent layers. However, Lee et $al.^{1-5)}$ reported that a mixture of Cu and Ta, the combination of which is characterized by a positive heat of mixing of +2kJ/mol, could be amorphized by mechanical alloying. This implies that there exists an up-hill process to raise the free energy of a mixture of pure Cu and la to that of an amorphous phase. It is our aim to investigate to what extent the MA is capable of producing a non-equilibrium phase with increasing the heat of mixing. The system chosen was the ternary $Cu_{30}Ta_{ 70-x}Mo_ x$ (x=35, 10). The mechanical alloying was carried out using a Fritsch P-5 planetary mill under Ar gas atmosphere. The MA powders were characterized by the X-ray diffraction with Cu-K $\alpha$ radiation, thermal analysis, electron diffraction and TEM micrographs. In the case of x=35, where pure Cu powders were mixed with equal amount of pure Ta and Mo powders, we revealed the formation of bcc solid solution after 150 h milling but its gradual decomposition by releasing fcc-Cu when milling time exceeded 200 h. However, an amorphous phase was clearly formed when the Mo content was lowered to x=10. It is believed that the amorphization of ternary $Cu_{30}Ta_{60}Mo_{10}$ powders is essentially identical to the solid state amorphization process in binary $Cu_{30}Ta_{70}$ powders.

• Journal of Powder Materials
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• v.9 no.5
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• pp.359-364
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• 2002

We report the structure, thermal and magnetic properties of a non-equilibrium $Al_{0.6}(Fe_{50}Cu_{50})_{0.4}$ alloy powder produced by rod milling and chemical leaching. An X-ray diffractometry(XRD), a transmission electron microscope(TEM), a differential scanning calorimeter(DSC), a vibrating sample magnetometer(VSM), and superconducting quantum interference device(SQUID) were utilized to characterize the as-milled and leaching specimens. The crystallite size reached a value of about 8.82 nm. In the DSC experiment, the peak temperatures and crystallization temperatures decreased with increasing milling time. The activation energy of crystallization is 200.5 kJ/mole for as-milled alloy powder. The intensities of the XRD peaks of as-milled powders associated with the bcc type $Al_{0.5}Fe_{0.5}$ structure formative at $350^{\circ}C$ sharply increase with increasing annealing temperature. Above $400^{\circ}C$, peaks alloted to $Al_{0.5}Fe_{0.5}$ and $Al_{5}Fe_{2}$ are observed. After annealing at $600^{\circ}C$ for 1h, the leached Ll specimen transformed into bcc $\alpha$-Fe and fcc Cu phases, accompanied by a change in the structural and magnetic properties. The saturation magnetization decreased with increasing milling time, and a value of about 8.42 emu/g was reached at 500 h of milling. The coercivity reached a maximum value of about 142.7 Oe after 500 h of milling. The magnetization of leached specimens as function of fields were higher at 5 K, and increased more sharply at 5 K than at 100 K.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.30 no.4
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• pp.175-185
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• 2018

This research investigates the internal flow and heat transfer in a plate heat exchanger with chevron shape by utilizing the computational fluid dynamics (CFD) software. The basic unit of the plate heat exchanger is generally composed of a hot channel, an intermediate chevron plate, and a cold channel. Several studies have reported experimental and numerical simulation of heat transfer and pressure drop. This study focused on the detailed numerical simulation of flow and heat transfer in the complicated chevron shape channel. The long chevron plate was designed to include 16 chevron patterns. For proper mesh resolution, the number of cells was determined after the grid sensitivity test. The working fluid is water, and its properties are defined as a function of temperature. The Reynolds number ranges from 900 to 9,000 in the simulation. A realizable $k-{\varepsilon}$ model and non-equilibrium wall function are properly considered for the turbulent flow. The friction factors and heat transfer coefficient are validated by comparing them with existing empirical correlations, and other patterned flow phenomena are also investigated.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.425.1-425.1
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• 2014

Thermal transport in nanomaterials is not only scientifically interesting but also technological important for various future electronic, bio, and energy device applications. Among the various computation approaches to investigate lattice thermal transport phenomena in nanoscale, the atomistic nonequilibrium Green's function approach based on first-principles density functional theory calculations appeared as a promising method given the continued miniaturization of devices and the difficulty of developing classical force constants for novel nanoscale interfaces. Among the nanometerials, carbon atomic chains, namely the cumulene (all-doulble bonds, ${\cdots}C=C=C=C{\cdots}$) and polyyne (alternation of single and triple bonds, ${\cdots}C{\equiv}C-C{\equiv}C{\cdots}$) can be considered as the extream cases of interconnction materials for nanodevices. After the discovery and realization of carbon atomic chains, their electronic transport properties have been widely studied. For the thermal transport properties, however, there have been few literatures for this simple linear chain system. In this work, we first report on the development of a non-equilibrium Green's function theory-based computational tool for atomistic thermal transport calculations of nanojunctions. Using the developed tool, we investigated phonon dispersion and transmission properties of polyethylene (${\cdots}CH2-CH2-CH2-CH2{\cdots}$) and polyene (${\cdots}CH-CH-CH-CH{\cdots}$) structures as well as the cumulene and polyyne. The resulting phonon dispersion from polyethylene and polyene showed agreement with previous results. Compared to the cumulene, the gap was found near the ${\Gamma}$ point of the phonon dispersion of polyyne as the prediction of Peierls distortion, and this feature was reflected in the phonon transmission of polyyne. We also investigated the range of interatomic force interactions with increase in the size of the simulation system to check the convergence criteria. Compared to polyethylene and polyene, polyyne and cumulene showed spatially long-ranged force interactions. This is reflected on the differences in phonon transport caused by the delicate differences in electronic structure.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.10
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• pp.1368-1379
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• 2000

A numerical study on swirling pulverized coal combustion in an axisymmetric enclosure is carried out by applying the 2-phase weighted sum of gray gases model (WSGGM) approach with the discrete ordinate method (DOM) to model the radiative heat transfer equation. In the radiative transfer equation, the same polynomial equation and coefficients for weighting factors as those for gas are adopted for the coal/char particles as a function of partial pressure and particle temperature. The Eulerian balance equations for mass, momentum, energy, and species mass fractions are adopted with the standard and RNG k-${\varepsilon}$ turbulence model, whereas the Lagrangian approach is used for the particulate phase. The eddy-dissipation model is employed for the reaction rate for gaseous mixture, and the single-step and two-step first-order reaction model for the devolatilization process for coal. Special attention is given to establish the thermal boundary conditions on radiative transfer equation By comparing the numerical results with experimental ones, the radiation model used here is confirmed and found to provide an alternative for simulating the radiative transfer.

• Coupled systems mechanics
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• v.10 no.2
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• pp.161-184
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• 2021

Strengthening of reinforced concrete beams with externally bonded fiber reinforced polymer plates/sheets technique has become widespread in the last two decades. Although a great deal of research has been conducted on simply supported RC beams, a few studies have been carried out on continuous beams strengthened with FRP composites. This paper presents a simple uniaxial nonlinear analytical model that is able to accurately estimate the load carrying capacity and the behaviour of damaged RC continuous beams flexural strengthened with externally bonded prestressed composite plates on both of the upper and lower fibers, taking into account the thermal load. The model is based on equilibrium and deformations compatibility requirements in and all parts of the strengthened beam, i.e., the damaged concrete beam, the FRP plate and the adhesive layer. The flexural analysis results and analytical predictions for the prestressed composite strengthened damaged RC continuous beams were compared and showed very good agreement in terms of the debonding load, yield load, and ultimate load. The use of composite materials increased the ultimate load capacity compared with the non strengthened beams. The major objective of the current model is to help engineers' model FRP strengthened RC continuous beams in a simple manner. Finally, this research is helpful for the understanding on mechanical behaviour of the interface and design of the FRP-damaged RC hybrid structures.

• Structural Engineering and Mechanics
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• v.84 no.6
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• pp.783-798
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• 2022

This study attempts to investigate the impact of thickness stretching and nonlinear hygro-thermo-mechanical loading on the bending behavior of FG beams. Young's modulus, thermal expansion, and moisture concentration coefficients vary gradually and continuously according to a power-law distribution in terms of the volume fractions of the constituent materials. In addition, the interaction between the thermal, mechanical, and moisture loads is involved in the governing equilibrium equations. Using the present developed analytical model and Navier's solution technique, the numerical results of non-dimensional stresses and displacements are compared with those obtained by other 3D theories. Furthermore, the present analytical model is appropriate for investigating the static bending of FG beams exposed to intense hygro-thermo-mechanical loading used for special technical applications in aerospace, automobile, and civil engineering constructions.

• Smart Structures and Systems
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• v.8 no.3
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• pp.275-302
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• 2011

This is a review paper on mathematical modeling of actively controlled piezo smart structures. Paper has four sections to discuss the techniques to: (i) write the equations of motion (ii) implement sensor-actuator design (iii) model real life environmental effects and, (iv) control structural vibrations. In section (i), methods of writing equations of motion using equilibrium relations, Hamilton's principle, finite element technique and modal testing are discussed. In section (ii), self-sensing actuators, extension-bending actuators, shear actuators and modal sensors/actuators are discussed. In section (iii), modeling of thermal, hygro and other non-linear effects is discussed. Finally in section (iv), various vibration control techniques and useful software are mentioned. This review has two objectives: (i) practicing engineers can pick the most suitable philosophy for their end application and, (ii) researchers can come to know how the field has evolved, how it can be extended to real life structures and what the potential gaps in the literature are.

• 한국전산유체공학회:학술대회논문집
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• 2008.03a
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• pp.84-91
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• 2008

Generalized hydrodynamic (GH) theory for multi-species gas and the computational models are developed for the numerical simulation of hypersonic rarefied gas flow on the basis of Eu's GH theory. The rotational non-equilibrium effect of diatomic molecules is taken into account by introducing excess normal stress associated with the bulk viscosity. The numerical model for the diatomic GH theory is developed and tested. Moreover, with the experience of developing the dia-tomic GH computational model, the GH theory is extended to a multi-species gas including 5 species; O$_2$, N$_2$, NO, O, N. The multi-species GH model includes diffusion relation due to the molecular collision and thermal phenomena. Two kinds of GH models are developed for an axisymmetric flow solver. By compar-ing the computed results of diatomic and multi-species GH theories with those of the Navier-Stokes equations and the DSMC results, the accuracy and physical consistency of the GH computational models are examined.