• 제목/요약/키워드: Non-thermal Equilibrium

검색결과 93건 처리시간 0.023초

Design and Preparation of High-Performance Bulk Thermoelectric Materials with Defect Structures

  • Lee, Kyu Hyoung;Kim, Sung Wng
    • 한국세라믹학회지
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    • 제54권2호
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    • pp.75-85
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    • 2017
  • Thermoelectric is a key technology for energy harvesting and solid-state cooling by direct thermal-to-electric energy conversion (or vice versa); however, the relatively low efficiency has limited thermoelectric systems to niche applications such as space power generation and small-scale or high-density cooling. To expand into larger scale power generation and cooling applications such as ATEG (automotive thermoelectric generators) and HVAC (heating, ventilation, and air conditioning), high-performance bulk thermoelectric materials and their low-cost processing are essential prerequisites. Recently, the performance of commercial thermoelectric materials including $Bi_2Te_3$-, PbTe-, skutterudite-, and half-Heusler-based compounds has been significantly improved through non-equilibrium processing technologies for defect engineering. This review summarizes material design approaches for the formation of multi-dimensional and multi-scale defect structures that can be used to manipulate both the electronic and thermal transport properties, and our recent progress in the synthesis of conventional thermoelectric materials with defect structures is described.

DENSITY STRUCTURE AND STABILITY OF THE SUBCOMPONENTS IN GIANT MOLECULAR CLOUD COMPLEXES

  • Yoo, Chin-Woo;Hong, Seung-Soo
    • 천문학회지
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    • 제19권1호
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    • pp.33-49
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    • 1986
  • Radial distribution of internal density has been determined for thirteen subclouds in the three giant molecular cloud complexes accompanying Mon OB1, Mon OB2 and CMa OB1 associations, We modeled their radial density structures with the density distribution of isothermal gas spheres. Most of the subclouds, nine out of the thirteen, are well described by isothermal spheres of single component; while the rest four require an additional component. Total mass and potential energy of each subcloud are also derived from the radial density structure; thermal energy and internal velocity dispersion required for sustaining the density structure are deduced from the isothermal gas model. Our derived masses of the clouds are comparable to the values determined by Blitz (1978) under LTE assumption. This agreement suggests that the correction factor for non-LTE effect on mass-estimate is not far from unity. The ratio of the gravitational potential energy to the kinetic energy of thermal motion is as large as 250; hence the thermal motion alone cannot support these clouds against the gravity. Being supported by turbulence motion with velocities of six to seven times the thermal velocity, the clouds of one-component type seem to be in equilibrium with the gravity; while the clouds of two-component type are likely to be in the stage of gravitational collapse.

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지표 특성 변화에 대한 평형온도의 반응 연구 : EBM 연구 (On response of Surface Equilibrium Temperature for Change of Surface Characteristics : An EBM Study)

  • 서예원;추정은;하경자
    • 한국제4기학회지
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    • 제24권2호
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    • pp.1-11
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    • 2010
  • 지표 특성 차이에 따라 외부강제력에 대한 차별적인 반응을 보이는 지표 평형온도 분포를 실험하기 위해 에너지 균형 모형(Energy Balance Model, EBM)이 사용되었다. EBM은 입사되는 복사에너지가 각 위도별로 수송되는 에너지와 방출되는 복사에너지의 합과 균형을 이루었을 때의 온도를 산출한다. 지구의 에너지 원천인 태양복사에너지를 전지구 에너지 균형에 있어 중요하게 취급하기 위하여 위도별 알베도 변화뿐만 아니라 해륙의 분포 차이에 따른 에너지 균형을 고려한 지구 평형온도 분포에 관한 실험이 수행되었으며, 입사되는 태양복사에너지량을 강제력으로 하여 위도별 알베도의 선형적인 증감, 극지역 알베도의 5%, 10%, 15% 증감에 대한 반응, 극과 중위도 지역에서의 상반된 증감에 대한 반응을 실험하였다. 그리고 얼음-알베도 피드백의 유무에 대한 실험도 수행되었다. 극지역의 알베도를 증가시키면 입사되는 태양에너지를 차단시켜 위도별 열수송을 감소시키는데 이는 극지역을 저에너지 상태로 유지시킴으로써 저위도에서부터의 에너지 수송을 강화시킨다. 이러한 수송량의 차이로 인해 중위도 지역의 온도 변화는 극지역에 비해 크게 나타난다. 육지는 해양에 비해 열용량이 작기 때문에 평형온도에 도달하는 시간이 짧으며 알베도에 따른 온도변화에 민감하여 해양과의 온도차이를 유발시킨다. 따라서 평형온도는 지표가 가지는 특성인 알베도와 열용량의 차이에 따라 다르게 나타나며 알베도가 증가함에 따라 감소하고 열용량이 작을수록 변화율이 큰 특징이 있다. 얼음-알베도 피드백은 알베도의 선형적인 증가에 따른 지구 평형온도의 감소를 가속화시키지만 국지적으로는 비선형적인 감소를 보인다.

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Non-Adiabatic Flamelet Modeling for Combustion Processes of Oxy-Natural Gas Flame

  • Kim, Gun-Hong;Kim, Yong-Mo
    • Journal of Mechanical Science and Technology
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    • 제19권9호
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    • pp.1781-1789
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    • 2005
  • In order to realistically predict the combustion characteristics of the oxy-fuel flame, the present study employs the non-adiabatic flame let approach. In this combustion model, the detailed equilibrium chemistry is utilized to accurately account for the thermal dissociation as well as to properly include the radiative cooling effects on the detailed chemistry. Numerical results indicate that the present approach has the capability to correctly capture the essential features and precise structure of the oxy-fuel flames. In this work, the detailed discussion has been made for the characteristics of oxy-fuel flames, the capability and defect of the present approach and also uncertainties of experimental data.

Thermal buckling analysis of FG plates resting on elastic foundation based on an efficient and simple trigonometric shear deformation theory

  • Tebboune, Wafa;Benrahou, Kouider Halim;Houari, Mohammed Sid Ahmed;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • 제18권2호
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    • pp.443-465
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    • 2015
  • In this paper, an efficient and simple trigonometric shear deformation theory is presented for thermal buckling analysis of functionally graded plates. It is assumed that the plate is in contact with elastic foundation during deformation. The theory accounts for sinusoidal distribution of transverse shear stress, and satisfies the free transverse shear stress conditions on the top and bottom surfaces of the plate without using shear correction factor. Unlike the conventional trigonometric shear deformation theory, the proposed sinusoidal shear deformation theory contains only four unknowns. It is assumed that the mechanical and thermal non-homogeneous properties of functionally graded plate vary smoothly by distribution of power law across the plate thickness. Using the non-linear strain-displacement relations, the equilibrium and stability equations of plates made of functionally graded materials are derived. The boundary conditions for the plate are assumed to be simply supported on all edges. The elastic foundation is modelled by two-parameters Pasternak model, which is obtained by adding a shear layer to the Winkler model. The effects of thermal loading types and variations of power of functionally graded material, aspect ratio, and thickness ratio on the critical buckling temperature of functionally graded plates are investigated and discussed.

Thermal post-buckling behavior of imperfect temperature-dependent sandwich FGM plates resting on Pasternak elastic foundation

  • Barka, Merbouha;Benrahou, Kouider Halim;Bakora, Ahmed;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • 제22권1호
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    • pp.91-112
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    • 2016
  • In this paper, post-buckling behavior of sandwich plates with functionally graded (FG) face sheets under uniform temperature rise loading is examined based on both sinusoidal shear deformation theory and stress function. It is supposed that the sandwich plate is in contact with an elastic foundation during deformation, which acts in both compression and tension. Thermo-elastic non-homogeneous properties of FG layers change smoothly by the variation of power law within the thickness, and temperature dependency of material constituents is considered in the formulation. In the present development, Von Karman nonlinearity and initial geometrical imperfection of sandwich plate are also taken into account. By employing Galerkin method, analytical solutions of thermal buckling and post-buckling equilibrium paths for simply supported plates are determined. Numerical examples presented in the present study discuss the effects of gradient index, sandwich plate geometry, geometrical imperfection, temperature dependency, and the elastic foundation parameters.

에너지 완화법을 이용한 실린더 주위의 극초음속 실제기체 유동에 관한 수치해석적 연구 (Computational Study of Hypersonic Real Gas Flows Over Cylinder Using Energy Relaxation Method)

  • ;김희동
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 춘계학술대회논문집
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    • pp.216-217
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    • 2008
  • In recent years, scientific community has found renewed interest in hypersonic flight research. These hypersonic vehicles undergo severe aero-thermal environment during their flight regimes. During reentry and hypersonic flight of these vehicles through atmosphere real gas effects come into play. The analysis of such hypersonic flows is critical for proper aero-thermal design of these vehicles. The numerical simulation of hypersonic real gas flows is a very challenging task. The present work emphasizes numerical simulation of hypersonic flows with thermal non-equilibrium. Hyperbolic system of equations with stiff relaxation method are identified in recent literature as a novel method of predicting long time behaviour of systems such as gas at high temperature. In present work, Energy Relaxation Method (ERM) has been considered to simulate the real gas flows. Navier-Stokes equations A numerical scheme Advection Upstream Splitting Method (AUSM) has been selected. Navier-Stokes solver along with relaxation method has been used for the simulation of real flow over a circular cylinder. Pressure distribution and heat flux over the surface of cylinder has been compared with experiment results of Hannemann. Present heat flux results over the cylinder compared well with experiment. Thus, real gas effects in hypersonic flows can be modeled through energy relaxation method.

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Effective Interdiffusion of Co/Pd multilayers

  • Kim, Jai-Young;Jan E. Evetts
    • Journal of Magnetics
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    • 제2권3호
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    • pp.86-92
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    • 1997
  • An artificially modulated magnetic Co/Pd multilayer is one of the promising candidates for high density magneto-optic (MO) recording media in the wavelength of a blue laser beam, due to large Kerr rotation angle. However, since the Co/Pd multilayer is a non-equilibrium state in terms of free energy and MO recording is a kind of thermal recording which is conducted around Curie temperature (Tc) of the recording media, the assessment of the thermal stability in the Co/Pd multilayer is crucially important both for basic research and applications. As the parameter of the thermal stability in this research, effective interdiffusion coefficients (Deff) perpendicular to the interface of the Co/Pd multilayers are measured in terms of Ar sputtering pressure and heat treatment temperature. From the results of the research, we find out that the magnetic exchange energy between Co and Pd sublayers strongly affects Deff of the Co/Pd multilayers. This discovery will provide the understanding of the magnetic exchange energy in the effective interdiffusion process of a magnetic multilayer structure and suggest the operating temperature range for MO recording in the Co/Pd multilayer for the basic research and applications, respectively.

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열 질식에 의한 덕티드 로켓 가스 발생기의 연소 압력 상승 (A Sudden Increase in Combustion Pressure of Gas Generator of Ducted Rocket by Thermal Choking)

  • 김도영;신경훈;이창진
    • 한국항공우주학회지
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    • 제43권8호
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    • pp.684-691
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    • 2015
  • 덕티드 로켓 가스발생기용 추진제 성능을 검증하기 위한 실험에서 직경이 10mm인 파이프와 최소 직경이 8.7mm인 수축 노즐을 배출 튜브로 사용하였을 때 급격한 압력 증가가 관찰되었다. 급격한 연소 압력 증가는 배출 튜브를 통과하는 유동의 열 질식(thermal choking) 때문인 것으로 판단하였다. 본 연구에서는 원형 파이프를 사용하는 경우, 배출 튜브 유동의 열 질식을 고려하여 가스발생기 연소 압력 변화를 예측하였다. 그 결과, 배출가스의 비-평형 화학반응으로 인한 배출 튜브 유동의 열 질식 발생이 급격한 연소 압력 증가의 원인임을 확인하였다. 특히 덕티드 로켓의 높은 압력 지수는 배출 튜브 내에서 발생하는 열에 매우 민감하게 반응하여 배출 튜브 내의 열 질식 가능성을 높이는 것으로 분석되었다. 또한 배출 튜브로 단면적의 변화가 있는 발산형 파이프를 사용하면 가스발생기의 급격한 연소 압력 증가를 예방할 수 있을 것으로 판단하였다.

Development of a Linear Stability Analysis Model for Vertical Boiling Channels Connecting with Unheated Risers

  • Hwang, Dae-Hyun;Yoo, Yeon-Jong;Zee, Seong-Quun
    • Nuclear Engineering and Technology
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    • 제31권6호
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    • pp.572-585
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    • 1999
  • The characteristics of two-phase flow instability in a vertical boiling channel connecting with an unheated riser are investigated through the linear stability analysis model. Various two-phase flow models, including thermal non-equilibrium effects, are taken into account for establishing a physical model in the time domain. A classical approach to the frequency response method is adopted for the stability analysis by employing the D-partition method. The adequacy of the linear model is verified by evaluating experimental data at high quality conditions. It reveals that the flow-pattern-dependent drift velocity model enhances the prediction accuracy while the homogeneous equilibrium model shows the most conservative predictions. The characteristics of density wave oscillations under low-power and low-quality conditions are investigated by devising a simple model which accounts for the gravitational and frictional pressure losses along the channel. The necessary conditions for the occurrences of type-I instability and flow excursion are deduced from the one-dimensional D-partition analysis. The parametric effects of some design variables on low quality oscillations are also investigated.

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