• Title/Summary/Keyword: Non-ionic surfactant

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Enzymatic Processing and Property of Denim by Acid Cellulase (산성 셀룰라제 이용한 데님의 효소가공 및 물성)

  • Seo, Hye-Young;Song, Wha-Soon;Kim, Hye-Rim
    • Fashion & Textile Research Journal
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    • v.11 no.3
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    • pp.465-468
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    • 2009
  • In this study, acid cellulase was used to treat denim fabrics by varying pH, temperature, enzyme concentration, treatment time and non-ionic surfactant (Triton X-100) concentration. Treatment condition was controlled based on the weight loss. The characteristics of enzyme-treated fabrics were measured in terms of tearing strength, stiffness, and color difference. The optimum conditions for cellulase treatment of denim fabric were pH 5.0, $50^{\circ}C$, 3% (o.w.f.), 90minutes. The weight loss did not change significantly with the addition of a non-ionic surfactant, but it improved when more non-ionic surfactant were used. The tearing strength of enzyme-treated denim fabrics did not deteriorate. The stiffness of the treated fabrics improved with the enzymatic treatment with and without the non-ionic surfactant. The difference in color of fabrics treated with enzyme increased.

Effects of Cloud Point of Non-ionic Surfactant on Deinking Efficiency of ONP at High Blending Ratio of OMG (비이온성 계면활성제의 운점이 OMG 배합비가 증가된 폐 신문지 탈묵효율에 미치는 영향)

  • Lee, Tai Ju;Seo, Jin Ho;Ryu, Jeong Yong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.164-169
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    • 2015
  • Nowadays blending ratio of OMG (old magazine) in recovered paper used for manufacturing newspaper have been increased. When large amount of OMG is consumed in newsprint mill, brightness can be improved by inorganic pigments of coating layer. On the other hand decrease in yield of deinking process will be encountered because the pigments can be removed as reject of froth flotation process. Therefore selection of the optimal deinking agent is an important. Non-ionic surfactant have been used widely in newsprint mill. Non-ionic surfactant has amphoteric characteristics. Hydrophilic group is ethylene and propylene oxide that can induce hydrogen bonding with water molecules. In this regard, cloud point is an important parameter in order to control efficiency of deinking process because hydration of the hydrophobic group can be varied according to temperature of a system. In this study, deinking properties of ONP at high blending ratio of OMG was analyzed according to cloud points of non-ionic surfactants. $L^*$, $a^*$, $b^*$, brightness and effective residual ink concentration did not affected by the change of cloud points. Especially, flotation reject decreased significantly according to increase in cloud point of the non-ionic surfactant. Consequently, when a nonionic surfactant having a cloud point higher than the temperature of the system is used, properties of the deinked pulp can be maintained and yield of deinking process can be improved.

Comparison of different surfactant system for simultaneous removal of nitrate and phosphate using micellar-enhanced ultrafiltration

  • 김보경;백기태;김호정;이율리아;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.417-421
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    • 2003
  • Three kinds of surfactant systems - cationic surfactant (system 1), combinition of two cationic surfactants (system 2), and combination of two cationic surfactant and non-ionic surfactant (system 3) - for the simultaneous removal of nitrate and phosphate by micellar-enhanced ultrafiltration (MEUF) were investigated. The highest removal efficiencies of nitrate and phosphate were observed in system 2, which were 90 % of nitrate and 72 % of phosphate. The COD of permeate in system 3 was the lowest, because the added non-ionic surfactant made critical micelle concentration (CMC) lower than that of other surfactant systems. In all systems, the flux decline was similar.

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Characteristics by Surfactant Condition at Copper CMP (구리 CMP시 비이온 계면활성제의 알루리마 슬러리 안정성에 대한 효과)

  • Lee, Do-Won;Kim, Nam-Hoon;Kim, Sang-Yong;Seo, Yong-Jin;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1288-1291
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    • 2004
  • In this study, physical characteristics of alumina slurry on variation of pH value and the effect of non-ionic surfactants on alumina slurry for copper chemical mechanical planarization (CMP) slurry have been investigated. After pH value of the slurry with alumina abrasive was changed by adding various amount of $HNO^3$ or KOH, the differences of settling rate, particle size, and zeta-potential were estimated. Better settling rates were shown in slurries with alumina abrasive at near pH 1. Higher zeta-potential was shown at around pH 2 in alumina slurry and the point of zero charge (PZC) was measured at about pH $9\sim10$. Non-ionic surfactant was added in the slurry with 5wt% alumina abrasive to get its effect on slurry practically. Abrasive size was smaller increased when amount of surfactant increased in slurry with P-4 as abrasive; on the other side, it was smaller when amount of surfactant decreased with AES-12. Variation of zeta-potential has no tendency with adding surfactant; however, values of zeta-potential were between $35\sim50mV$. The proper amount of surfactant was $0.1\sim1.0wt%$ in slurry with P-4 and $0.5\sim1.0wt%$ in slurry with AES-12 respectively. Excellent dispersion stabilization was obtained by addition of non-ionic surfactant

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A Comparison Study on Drag Reduction Characteristics of Polymer and Surfactant as Drag Reduction Additive (고분자불질 및 계면활성제의 유동마찰 저감 특성 비교 연구)

  • Cho, Sung-Hwan;Ryu, Jae-Sung;Kim, Seong-Su;Jung, Sang-Hoon;Yoon, Seok-Mann
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.6
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    • pp.398-403
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    • 2010
  • The drag reduction(DR) of non-ionic surfactant and polymer according to the variation of fluid velocity, temperature and surfactant concentration was investigated experimentally. For this experiment, the kind of surfactant was non ionic amine-oxide and the kinds of polymer were polyacrylamide and xantan gum. An experimental apparatus equipped with one water storage tanks was built and two flow meters, two pressure gauges for data logging system was installed. Results showed that the kinds of polymer, polyacrylamide and xantan gum, had DR of below 20% for below 500 ppm in fluid temperature of $50{\sim}80^{\circ}C$. But the kind of surfactant, amine oxide, had DR of above 40% for 500~1000 ppm in fluid temperature of $50{\sim}80^{\circ}C$. As a result, amin oxide showed better materials to use to the district heating system.

AEROBIC DEGRADATION OF A NON-IONIC SURFACTANT IN A MEMBRANE BIOREACTOR(MBR)

  • Choi, In-Su;Wiesmann, Udo
    • Environmental Engineering Research
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    • v.12 no.2
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    • pp.81-91
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    • 2007
  • A membrane bioreactor (MBR) was used to investigate the aerobic degradation of foam active substance - non-ionic surfactant, APG 2000 UP. The surface aeration using the propeller loop reactor (PLR) guaranteed sufficient $O_2$ for substrate removal and bacteria growth and avoided foam development. Moreover, the cross-flow membrane filtration enabled the separation of the bacteria still loaded with surfactant in the collecting container. The biological degradation of the surfactant with varying hydraulic retention time (HRT) and influent concentration $c_{S0}$ showed high substrate removal of nearly 95% at high volumetric loading rates up to $7.4\;kgCOD\;m^{-3}d^{-1}$ and at sludge loading rates up to 1.8 kgCOD $(kgVSS\;d)^{-1}$ for biomass concentration $c_B\;{\approx}\;constant $. The increasing $c_B$ from 3.4 to $14.5\;gL^{-1}$ TSS respectively sludge retention time (SRT) from 5.1 to 442 d under complete biomass retention by the membrane filtration resulted in high removal of substrate ${\alpha}\;>\;90%$ with reducing excess sludge production.

Experimental Study on Drag Reduction Effects of New Non-Ionic Surfactants

  • Tae, Choon-Sub;Cho, Sung-Hwan
    • International Journal of Air-Conditioning and Refrigeration
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    • v.14 no.4
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    • pp.147-155
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    • 2006
  • The drag reduction (DR) and heat transfer efficiency reduction (ER) of non-ionic surfactant were investigated as a function of fluid velocity, temperature, and surfactant concentration. An experimental apparatus consisting of two temperature controlled water storage tanks, pumps, test specimen pipe and the piping network, two flow meters, two pressure gauges, a heat exchanger, and data logging system was built. From the experimental results, it was concluded that existing alkyl ammonium surfactant (CTAC Cethyl Trimethyl Ammonium Chloride) had DR of $0.6{\sim}0.8$ at $1,000{\sim}2,000ppm$ concentration with fluid temperature ranging between $50{\sim}60^{\circ}C$. However, the DR was very low when the fluid temperature was $70{\sim}80^{\circ}C$. The new amine oxide and betaine surfactant(SAOB Stearyl Amine Oxide + Betaine) had lower DR at fluid temperatures ranging between $50{\sim}60^{\circ}C$ compared with CTAC. However, with fluid temperature ranging between $70{\sim}80^{\circ}C$ the DR was $0.6{\sim}0.8$ when the concentration level was $1,000{\sim}2,000ppm$.

Synthesis of Magnesium Hydroxide and Surface Modification by Sorbitol Surfactants (수산화마그네슘의 합성과 솔비톨계 계면활성제를 이용한 표면개질)

  • Kang, Kuk-Hyoun;Hyun, Mi-Ho;Ryu, Kun-Sung;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.92-100
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    • 2014
  • Hydrophobic magnesium hydroxide [$Mg(OH)_2$] was modified by hydrothermal method using non-ionic sorbitol surfactant with Span series. Mganesium chloride [$MgCl_2$] and sodium hydroxide [NaOH] were used for synthesis of $Mg(OH)_2$. Also non-ionic surfactant were added as a stabilizer, dispersant and surface modifier. Addition of non-ionic surfactant was favourable to obtain small sized $Mg(OH)_2$ particles with better dispersibility and hydrophobic property of $Mg(OH)_2$ particles. The obtained product were characterized by particle size analysis(PSA), scanning electron microscope(SEM), energy dispersive spectroscopy(EDS), x-ray diffraction(XRD) and fourier transform infrared spectroscopy(FT-IR). The results show that the product are prepared with this method has a well hydrophobic properties and dispersity compared with unmodified $Mg(OH)_2$ particles. The improve properties of surface modified $Mg(OH)_2$ particles were also verified by similarity synthesizing under slightly different conditions.

Effect of Fatty Acid and Non-ionic Surfactant on the Deinkability of Mixed Recovered Paper (혼합폐지의 탈묵효율에 미치는 지방산과 비이온성 계면활성제의 영향)

  • Seo, Jin Ho;Choi, Do Chim;Ryu, Jeong Yong;Chung, Sung Hyun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.2
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    • pp.34-41
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    • 2015
  • Recovered paper has been widely used as a main raw material of papermaking in Korea. Recycling of recovered paper helps to reduce production cost and preserve an environment. To recycle recovered paper efficiently, de-inking is a key process in recycling mills. De-inking process would be affected by various influencing factors such as the type of de-inking agent, mixed ratio of recovered paper, season, and process conditions. In this study, fatty acid and nonionic surfactant were used as the de-inking agent in froth-flotation process of mixed recovered paper. De-inking properties of mixed recovered paper were investigated according to the addition level of each chemical. Nonionic surfactant had a small effect on de-inking efficiency of mixed recovered paper due to decreased reject. As the additional level of fatty acid increases, fragmented ink particles increased and then optical properties of recycled paper decreased because fragmented ink particles adsorbed onto the fiber surface.

Preparation of Coconut Oil in Water Emulsions Using Tween-Span Type Mixed Surfactant : Optimization of CCD-RSM (Tween-Span계 혼합계면활성제를 이용한 Coconut Oil 원료 O/W 유화액의 제조 : CCD-RSM을 이용한 최적화)

  • Yoo, Bong-Ho;Zhu, Kaiyang;Zuo, Chengliang;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.31 no.1
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    • pp.19-24
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    • 2020
  • In this study, the O/W emulsions prepared from coconut oil and the non-ionic mixed surfactant as Tween-Span system were evaluated and optimized in order to upgrade the stability of manufactured emulsions. For the optimization, a central composite design model-response surface methodology, so called as CCD-RSM was implemented. Quantitative factors were the hydrophile-lipophilie balance (HLB), amount of non-ionic mixed surfactant and emulsification speed while experimental results included the mean droplet size (MDS), emulsion stability index (ESI), and thermal instability index (TII). Optimized values of the HLB, amount of non-ionic mixed surfactant and emulsification speed obtained from CCD-RSM were 9.1, 8.7 wt.%, and 6,200.8 rpm, respectively. Expected experimental results for MDS, ESI, and TII under the optimized experimental condition were 151.0 nm, 99.86, and 3.17%, respectively. The average error from actual experiments which established for validation of the conclusions was lower than 3.5%. Therefore, a highly favorable level could be obtained when the optimized CCD-RSM was applied to manufacturing the O/W emulsion in this study.