• Bulletin of the Korean Chemical Society
• /
• v.35 no.7
• /
• pp.2049-2056
• /
• 2014

A simple method for exfoliating pristine graphite to yield mono-, bi-, and multi-layers of graphene sheets as a highly concentrated (5.25 mg/mL) and yielded solution in an organic solvent was developed. Pre-thermal treatment of pristine graphite at $900^{\circ}C$ in a sealed stainless steel bath under high pressures, followed by sonication in 1-methyl-2-pyrrolidinone solvent at elevated temperatures, produced a homogeneous, well-dispersed, and non-oxidized graphene solution with a low defect density. The electrical conductivities of the graphene sheets were very high, up to 848 S/cm. These graphene sheets were used to fabricate graphene-polyimide nanocomposites, which displayed a higher electrical conductivity (1.37 S/m) with an improved tensile strength (95 MPa). The synthesized graphene sheets and nanocomposites were characterized by transmission electron microscopy, scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.06a
• /
• pp.91-91
• /
• 2008

$SnO_2-B_2O_3-P_2O_5$ system were prepared by melt-quenching technique in the compositional series containing 50, 55 aod 60mol.% of $SnO_2$. A large glass-forming region was found at the phosphate side of the ternary system with homogeneous glasses containing up to 5-25mol.% of $B_2O_3$. For these glasses, thermal expansion coeffient($\alpha$), glass transition temperature(Tg), and glass softening temperature(Ts), were determined. The values a decrease with increasing $B_2O_3$ content, while Tg and Ts increased. The reason for the observed changes is local structure of the glasses. Local structure of the glasses was investigated by Raman and FT-IR measurements, suggesting that the number of bridging oxygens decreased whereas the non-bridging oxygen concentration increased with increasing $SnO_2$ content in the glasses.

• Structural Engineering and Mechanics
• /
• v.62 no.4
• /
• pp.401-415
• /
• 2017

A new higher shear deformation theory (HSDT) is presented for the thermal buckling behavior of functionally graded (FG) sandwich plates. It uses only four unknowns, which is even less than the first shear deformation theory (FSDT) and the conventional HSDTs. The theory considers a hyperbolic variation of transverse shear stress, respects the traction free boundary conditions and contrary to the conventional HSDTs, the present one presents a new displacement field which includes undetermined integral terms. Material characteristics and thermal expansion coefficient of the sandwich plate faces are considered to be graded in the thickness direction according to a simple power-law distribution in terms of the volume fractions of the constituents. The core layer is still homogeneous and made of an isotropic material. The thermal loads are supposed as uniform, linear and non-linear temperature rises within the thickness direction. An energy based variational principle is used to derive the governing equations as an eigenvalue problem. The validation of the present work is carried out with the available results in the literature. Numerical results are presented to demonstrate the influences of variations of volume fraction index, length-thickness ratio, loading type and functionally graded layers thickness on nondimensional thermal buckling loads.

• Structural Engineering and Mechanics
• /
• v.47 no.4
• /
• pp.559-573
• /
• 2013

Geometrically non-linear axisymmetric bending of a shallow spherical shell with a clamped or a simply supported edge under axisymmetric load was investigated numerically. The partial load was introduced by the Heaviside step function, and the solution was obtained by the finite difference and the Newton-Raphson methods. The thickness of the shell was considered to be uniform and the material was assumed to be homogeneous and isotropic. Sensitivity analysis was made for three geometrical parameters. The accuracy of the algorithm was checked by comparing the central deflection, the radial membrane stress at the edge, or the transverse shear force with the solutions of plates and shells in the literature and good agreement was obtained. The main findings of the study can be outlined as follows: (i) If the shell is fully loaded the central deflection of a clamped shell is larger than that of a simply supported shell provided that the shell is not very shallow, (ii) if the shell is partially loaded the central deflection of the shell is sensitive to the parameters of thickness, depth, and partial loading but the influence of the boundary conditions is negligible.

• Steel and Composite Structures
• /
• v.28 no.3
• /
• pp.349-362
• /
• 2018

This paper presents a semi-analytical solution for the creep analysis and life assessment of 304L austenitic stainless steel thick truncated conical shells using multilayered method based on the first order shear deformation theory (FSDT). The cone is subjected to the non-uniform internal pressure and temperature gradient. Damages are obtained in thick truncated conical shell using Robinson's linear life fraction damage rule, and time to rupture and remaining life assessment is determined by Larson-Miller Parameter (LMP). The creep response of the material is described by Norton's law. In the multilayer method, the truncated cone is divided into n homogeneous disks, and n sets of differential equations with constant coefficients. This set of equations is solved analytically by applying boundary and continuity conditions between the layers. The results obtained analytically have been compared with the numerical results of the finite element method. The results show that the multilayered method based on FSDT has an acceptable amount of accuracy when one wants to obtain radial displacement, radial, circumferential and shear stresses. It is shown that non-uniform pressure has significant influences on the creep damages and remaining life of the truncated cone.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.32 no.6A
• /
• pp.399-409
• /
• 2012

The flexural behavior of HSB plate girder with a non-slender web, due to inelastic lateral-torsional buckling, under uniform bending was investigated by the nonlinear finite element analysis. Both homogeneous sections fabricated from SM570-TMC, HSB600 or HSB800 steel and hybrid sections with HSB800 flanges and SM570-TMC web were considered. The flanges and web of selected noncomposite I-girders were modeled as thin shell elements and the geometrical and material nonlinear finite element analysis was performed by the ABAQUS program. The steel was assumed as an elasto-plastic strain hardening material. Initial imperfections and residual stresses were taken into account and their effects on the inelastic lateral-torsional buckling behavior were analyzed. The flexural strengths of selected sections obtained by the finite element analysis were compared with the nominal flexural strengths from KHBDC LSD, AASHTO LRFD, and Eurocode and the applicability of these codes in predicting the inelastic lateral torsional buckling strength of HSB plate girders with a non-slender web was assessed.

• Tunnel and Underground Space
• /
• v.11 no.4
• /
• pp.362-367
• /
• 2001

The stiff top layer in a soil profile, which can happen in winter, may change the isolation effect of the wave barrier. The research scope of this paper is the investigation of the propagation of surface waves in layered soil with a stiff layer on its top, and the isolation effect of the solid stiff wave barrier. The investigations have been performed numerically by the Boundary-Element Method as a two-dimensional problem. A strip foundation vibrated harmonically in vertical direction was considered as the vibration source. Three soil profiles, a homogeneous half-space, two profiles with different thickness of stiff top layer, with two different types of wave barriers were investigated. The profiles with a stiff top layer show considerable reductions of the amplitude of the vibration in comparison to the homogeneous soil profile. The layered soil profiles with a stiff top layer do not show wave propagation velocities as high as they are expected from the material properties. Furthermore the vibration amplitudes in a frozen soil are much smaller with distance than in a non-frozen soil.

• Steel and Composite Structures
• /
• v.25 no.2
• /
• pp.157-175
• /
• 2017

The novelty of this work is the use of a new displacement field that includes undetermined integral terms for analyzing thermal buckling response of functionally graded (FG) sandwich plates. The proposed kinematic uses only four variables, which is even less than the first shear deformation theory (FSDT) and the conventional higher shear deformation theories (HSDTs). The theory considers a trigonometric variation of transverse shear stress and verifies the traction free boundary conditions without employing the shear correction factors. Material properties of the sandwich plate faces are considered to be graded in the thickness direction according to a simple power-law variation in terms of the volume fractions of the constituents. The core layer is still homogeneous and made of an isotropic material. The thermal loads are assumed as uniform, linear and non-linear temperature rises within the thickness direction. An energy based variational principle is employed to derive the governing equations as an eigenvalue problem. The validation of the present work is checked by comparing the obtained results the available ones in the literature. The influences of aspect and thickness ratios, material index, loading type, and sandwich plate type on the critical buckling are all discussed.

• Journal of the Korea Institute of Building Construction
• /
• v.2 no.3
• /
• pp.163-170
• /
• 2002

Recently, polishing tile(porcelain homogeneous polished tile) was used in the construction field as a finishing material. But, there happened some problems such as tile exfoliation by construction condition in early ages. Also, for use of polishing tile in the dry wall system which used to lightweight wall, the examination of adhesive stability of polishing tile is needed. In this study, adhesive strength of Polishing tile was investigated by tile bond types on gypsum board and non asbestos board coated by tar-urethane and Polymer modified cementitious waterproofing membrane(Series I). Then, the effect of heat stress and vibration was estimated on gypsum and non asbestos board(Series II). As the result of study are the follows; (1) Polishing tile(600$\times$400mm) construction on waterproofing layer : Both laboratory estimation and spot examination sieve were happened that fall of tile because their hardening speed is late. (2) To using powder style adhesives in the dry wail with waterproofing layer : Adhesive strength of tile is Influenced by interface bond area and base side condition. (3) Shock and heat stresses : obvious decline of adhesive strength is not happened

• Imaging Science in Dentistry
• /
• v.46 no.4
• /
• pp.279-284
• /
• 2016

To our knowledge, the imaging features of costochondral grafts (CCGs) on cone-beam computed tomography (CBCT) have not been documented in the literature. We present the case of a CCG in the facial soft tissue to the anterior mandible, with changes mimicking a cartilaginous neoplasm. This is the first report to describe the CBCT imaging features of a long-standing graft in the anterior mandible. Implants or grafts may be incidental findings on radiographic images made for unrelated purposes. Although most are well-defined and radiographically homogeneous, being of relatively inert non-biological material, immune reactions to some grafts may stimulate alterations in the appearance of surrounding tissues. Biological implants may undergo growth and differentiation, causing their appearance to mimic neoplastic lesions. We present the case of a cosmetic autogenous CCG that posed a diagnostic challenge both radiographically and histopathologically.