• Title/Summary/Keyword: Non-cement

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Evaluation of high plasticity clay stabilization methods for resisting the environmental changes

  • Taleb, Talal;Unsever, Yesim S.
    • Geomechanics and Engineering
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    • v.30 no.5
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    • pp.461-469
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    • 2022
  • One of the most important factors that should be considered for using any ground improvement technique is the stability of stabilized soil and the durability of the provided solution for getting the required engineering properties. Generally, most of the earth structures that are constructed on clayey soils are exposing movements due to the long periods of drying or wetting cycles. Over time, environmental changes may result in swells or settlements for these structures. In order to mitigate this problem, this research has been performed on mixtures of high plasticity clay with traditional additives such as lime, cement and non-traditional additives such as polypropylene fiber. The purpose of the research is to assess the most appropriate ground improvement technique by using commercially available additives for resisting the developed desiccation cracks during the drying process and resisting the volume changes that may result during wet/dry cycles as an attempt to simulate the changes of environmental conditions. The results show that the fiber-reinforced samples have the lowest volumetric deformation in comparision with cement and lime stabilized samples, and the optimum fiber content is identified as 0.38%. In addition, the desiccation cracks were not visible on the samples' surface for both unreinforced and chemically stabilized samples. Regarding cracks resistance resulting from the desiccation process, it is observed, that the resistance is connected with the fiber content and increases with the increase of the fiber inclusion, and the optimum content is between 1% and 1.5%.

Prediction of Autogenous Shrinkage on Concrete by Unsaturated Pore Compensation Hydration Model (불포화 공극 보정 수화도 모델을 이용한 콘크리트의 자기수축 예측)

  • Lee, Chang Soo;Park, Jong Hyok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.5A
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    • pp.909-915
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    • 2006
  • To predict autogenous shrinkage of concrete, unsaturated pore compensation factor could be calculated by experiments of autogenous shrinkage of cement paste on the assumption that the differences between degree of hydration and strain rate of autogenous shrinkage are unsaturated pore formation rate. Applying unsaturated pore compensation factor on modified Pickket model considering contribution factor and non-contribution factor to autogenous shrinkage of concrete, experimental data and existing model were compared. From the results modified Pickket model was verified to present similar tendency between Tazawa model and experimental data, but CEB-FIP model might be corrected because this model uses ultimate autogenous shrinkage underestimated and the same autogenous time function of concrete material properties considering only compressive strength.

EIS Properties of Lightweght Aggregate According to Surface Coating (표면 코팅 유무에 따른 경량골재의 EIS 특징)

  • Pyeon, Myeong-Jang;Jeong, Su-Mi;Kim, Ju-Sung;Kim, Ho-Jin;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.107-108
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    • 2022
  • In recent years, the construction industry has a tendency to increase of high-rise builidngs. High rise buildings can use limited space efficiently. But High rise buildings have problem that have extremely heavy weight. Various studies are being conducted to reduce the weight of buildings. Although lightweight aggregate is a meterial that can effectively reduce the weight of buildings, the strength of the aggregate itself is weak and the absorption rate is high, so the strength of the ITZ(Interfacial Transition Zone) area is weak. Therefore, it is essential to improve the interfacial area when using lightweight aggregates. In this study, an experiment was conducted to improve the adhesion between the aggregate and cement paste and to strengthen the interfacial area by coating the surface of the lighteight aggregate with Blast Furnace Slag. To confirm the improvement, compressive strength and EIS(Electrochemical Impedance Spectroscopy) measurements were perfromed. Using EIS, the change in electrical resistance of the cement hardened body was confirmed. As a result, it was confirmed that the lightweight aggregate coated on the surface showed highter compressive strength and electrical resistance than the non-coated lightweight aggregate, and that the coating material was filled in the interfacial area and inside the aggregate that helped to strengthen the compresssive strength and higher electrical resistance.

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Transformation of Asbestos-Containing Slate Using Exothermic Reaction Catalysts and Heat Treatment (발열반응 촉매제와 열처리를 이용한 석면함유 슬레이트의 무해화 연구)

  • Yoon, Sungjun;Jeong, Hyeonyi;Park, Byungno;Kim, Yongun;Kim, Hyesu;Park, Jaebong;Roh, Yul
    • Economic and Environmental Geology
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    • v.52 no.6
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    • pp.627-635
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    • 2019
  • Cement-asbestos slate is the main asbestos containing material. It is a product made by combining 10~20% of asbestos and cement components. Man- and weathering-induced degradation of the cement-asbestos slates makes them a source of dispersion of asbestos fibres and represents a priority cause of concern. When the asbestos enters the human body, it causes cellular damage or deformation, and is not discharged well in vitro, and has been proven to cause diseases such as lung cancer, asbestos, malignant mesothelioma and pleural thickening. The International Agency for Research on Cancer (IARC) has designated asbestos as a group 1 carcinogen. Currently, most of these slats are disposed in a designated landfill, but the landfill capacity is approaching its limit, and there is a potential risk of exposure to the external environment even if it is land-filled. Therefore, this study aimed to exam the possibility of detoxification of asbestos-containing slate by using exothermic reaction and heat treatment. Cement-asbestos slate from the asbestos removal site was used for this experiment. Exothermic catalysts such as calcium chloride(CaCl2), magnesium chloride(MgCl2), sodium hydroxide(NaOH), sodium silicate(Na2SiO3), kaolin[Al2Si2O5(OH)4)], and talc[Mg3Si4O10(OH)2] were used. Six catalysts were applied to the cement-asbestos slate, respectively and then analyzed using TG-DTA. Based on the TG-DTA results, the heat treatment temperature for cement-asbestos slate transformation was determined at 750℃. XRD, SEM-EDS and TEM-EDS analyses were performed on the samples after the six catalysts applied to the slate and heat-treated at 750℃ for 2 hours. It was confirmed that chrysotile[Mg3Si2O5(OH5)] in the cement-asbestos slate was transformed into forsterite (Mg2SiO4) by catalysts and heat treatment. In addition, the change in the shape of minerals was observed by applying a physical force to the slate and the heat treated slate after coating catalysts. As a result, the chrysotile in the cement-asbestos slate maintained fibrous form, but the cement-asbestos slate after heat treatment of applying catalyst was broken into non-fibrous form. Therefore, this study shows the possibility to safely verify the complete transformation of asbestos minerals in this catalyst- and temperature-induced process.

A Review on the Recycling of the Concrete Waste Generate from the Decommissioning of Nuclear Power Plants (원전 해체 콘크리트 폐기물의 재활용에 대한 고찰)

  • Jeon, Ji-Hun;Lee, Woo-Chun;Lee, Sang-Woo;Kim, Soon-Oh
    • Economic and Environmental Geology
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    • v.54 no.2
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    • pp.285-297
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    • 2021
  • Globally, nuclear-decommissioning facilities have been increased in number, and thereby hundreds of thousands of wastes, such as concrete, soil, and metal, have been generated. For this reason, there have been numerous efforts and researches on the development of technology for volume reduction and recycling of solid radioactive wastes, and this study reviewed and examined thoroughly such previous studies. The waste concrete powder is rehydrated by other processes such as grinding and sintering, and the processes rendered aluminate (C3A), C4AF, C3S, and ��-C2S, which are the significant compounds controlling the hydration reaction of concrete and the compressive strength of the solidified matrix. The review of the previous studies confirmed that waste concretes could be used as recycling cement, but there remain problems with the decreasing strength of solidified matrix due to mingling with aggregates. There have been further efforts to improve the performance of recycling concrete via mixing with reactive agents using industrial by-products, such as blast furnace slag and fly ash. As a result, the compressive strength of the solidified matrix was proved to be enhanced. On the contrary, there have been few kinds of researches on manufacturing recycled concretes using soil wastes. Illite and zeolite in soil waste show the high adsorption capacity on radioactive nuclides, and they can be recycled as solidification agents. If the soil wastes are recycled as much as possible, the volume of wastes generated from the decommissioning of nuclear power plants (NPPs) is not only significantly reduced, but collateral benefits also are received because radioactive wastes are safely disposed of by solidification agents made from such soil wastes. Thus, it is required to study the production of non-sintered cement using clay minerals in soil wastes. This paper reviewed related domestic and foreign researches to consider the sustainable recycling of concrete waste from NPPs as recycling cement and utilizing clay minerals in soil waste to produce unsintered cement.

Engineering Characteristics of Non-sintering Binder-stabilized Mixture using Industrial By-Products (산업부산물을 이용한 비소성 고화제 혼합토의 역학적 특성)

  • Yun, Dae-Ho;Mun, Kyoung-Ju;Kim, Yun-Tae
    • Journal of Ocean Engineering and Technology
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    • v.28 no.2
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    • pp.140-146
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    • 2014
  • This study investigated the engineering characteristics of non-sintering binder-stabilized mixtures consisting of different ratios of a hardening agent(3%, 6%, 9%, 12%) for recycling industrial by-products through several series of laboratory tests. The hardening agents consisted of two kinds of non-sintering binders(NSB-1, NSB-2), which were developed by using inter-chemical reactions among blast furnace slag, phospho-gypsum, and an alkali activator. In addition, ordinary Portland cement(OPC) was used to compare the engineering characteristics of the stabilized mixture. An unconfined compressive test showed that the unconfined compressive strength increased with the curing time and mixing ratio. Experimental test results indicated that the 7-day strength of the NSB-1 mixture was similar to that of the OPC mixture. However, its 28-day strength was higher than that of the OPC mixture. The secant module of elasticity showed a range of $E_{50}=(42-109)q_u$ regardless of the agents. Based on the results of triaxial tests, the cohesion and friction angle increased with the mixing ratio.

A STUDY ON THE BOND STRENGTH OF REPAIRED GLASS IONOMER CEMENTS (Repaired glass ionomer cement의 결합강도에 관한 연구)

  • Seo, Su-Jeong;Kim, Shin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.23 no.2
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    • pp.347-355
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    • 1996
  • The purpose of this study was to compare the bond strengths of different kinds of glass ionomer cements (GIC), which is recently increasing the clinical application in the field of pediatric dentistry and measure the repaired bond strengths in order to examine the clinical applicabilty of partial repaired cases. By using one kind of the light cured type GIC and three kinds of the chemical cured type GIC, the bond strengths of the followings were compared : unrepaired group as control, repaired conditioning group, which was treated the repaired surface using 25% polyacrylic acid and repaired non-conditioning group without surface treatment. Three point bending test was performed under Universal Testing Machine in order to measure the compressive bond strengths. The results were as follows : 1. Light cured GIC had higher bond strength than chemical cured type GIC in both of repaired and unrepaired groups. 2. In repaired cases, all of the materials decreased the bond strength when compared to the control group. In the light cured type, the bond strength of repaired conditioning group decreased 31.6%, repaired non-conditioning group decreased 40.8%. In chemical cured types, the bond strength of repaired conditining group decreased 11.8%, repaired non-conditioning group decreased 20.9%. 3. All the materials, in the case of the chemical treatment on the repaired surface using 25% polyacrylic acid had higher bond strength than untreated but, lower than control group.

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Prediction of Hybrid fibre-added concrete strength using artificial neural networks

  • Demir, Ali
    • Computers and Concrete
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    • v.15 no.4
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    • pp.503-514
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    • 2015
  • Fibre-added concretes are frequently used in large site applications such as slab and airports as well as in bearing system elements or prefabricated elements. It is very difficult to determine the mechanical properties of the fibre-added concretes by experimental methods in situ. The purpose of this study is to develop an artificial neural network (ANN) model in order to predict the compressive and bending strengths of hybrid fibre-added and non-added concretes. The strengths have been predicted by means of the data that has been obtained from destructive (DT) and non-destructive tests (NDT) on the samples. NDTs are ultrasonic pulse velocity (UPV) and Rebound Hammer Tests (RH). 105 pieces of cylinder samples with a dimension of $150{\times}300mm$, 105 pieces of bending samples with a dimension of $100{\times}100{\times}400mm$ have been manufactured. The first set has been manufactured without fibre addition, the second set with the addition of %0.5 polypropylene and %0.5 steel fibre in terms of volume, and the third set with the addition of %0.5 polypropylene, %1 steel fibre. The water/cement (w/c) ratio of samples parametrically varies between 0.3-0.9. The experimentally measured compressive and bending strengths have been compared with predicted results by use of ANN method.

Remote Sensing Data Processing of the Ulsan Area for Classification of Non-metallic Minerals and Rocks (울산 지역 비금속광물 및 암석 분류를 위한 원격탐사 자료처리)

  • 박종남;박인석
    • Korean Journal of Remote Sensing
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    • v.7 no.2
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    • pp.131-147
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    • 1991
  • Feature enhancement combined with some pattern recognition techiques were applied to the Remote Sensing Data for geological mapping with particular emphasis on non-me-tallic ore deposits and their related geologies. The area chosen is north of Ulsan, the size of which is about 400km$^2$. The geology of the area consists mainly of volcanics, volcanic sediments and clastic sediments of Miocene age, underlain by the Kyungsang sediments of Cretaceous age. The mineralization occurs in tuffs or along the bedding plane of tuffaceous sediments, the main products of which are Kaolinite and Bentonite. The outcrops or mine dumps in the study area were most effectively extracted on the histrogram normalized image of TM Band 1 and 2, due to their high reflectivity. These may be confused with some artificial features, like slate roof complex of the poultry farm or cement ground, which should be classified by field checking. Detailed examination of enhancment image combined with pattern recognition techniques made enable to classify different rocks and thereby extract volcanic products which are mainly related to non-metallic ore deposits in the study area.

Time-resolved polarization and depolarization tracking on reaction pathway of calcium carbonates in a view of non-classical nucleation theory (비전통핵생성 이론 관점에서 탄산칼슘의 반응경로에 대한 시간분해 분극 및 탈분극 추적)

  • Kim, Gwangmok
    • Journal of Urban Science
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    • v.9 no.2
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    • pp.45-50
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    • 2020
  • The formation characteristics of calcium carbonates are closely related to the durability and mechanical properties of cement-based materials. In this regard, a deep understanding of the reaction pathway of calcium carbonates is critical. Recently, non-classical nucleation theory was summarized and it was presumed that prenucleation clusters are present. The formation of the prenucleation cluster at undersaturated condition (≈ 0.1 ml) in the present study was investigated via electrical characteristics of an electrolytic solution. Calcium chloride dihydrate (CaCl2·2H2O) and sodium carbonate (Na2CO3) were used as starting materials to supply calcium and carbonate sources, respectively. Furthermore, the reaction pathway of calcium carbonates was investigated by time-resolved polarization and depolarization characteristics of the electrolytic solution. The time-resolved polarization and depolarization tests were conducted by switching polarity with an interval of 20 seconds for 1 hr and by measuring the variation of electrical resistance. It can be inferred from the results obtained in the present study that the reactive constituent for the formation of calcium carbonates was mostly consumed in the period possibly associated with the prenucleation and the reaction pathways may be governed by the monomer-addition mechanism.