• Title/Summary/Keyword: Non-aqueous

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ENHANCED SOLUBILIZATION BY SYNTHETIC AND BIOSURFACT ANT ADDITION IN THE REMEDIATION OF PHENANTHRENE

  • Shin, Kyung-Hee;Lee, Byung-Tae;Kim, Kyoung-Woong
    • Proceedings of the KSEEG Conference
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    • 2003.04a
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    • pp.66-68
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    • 2003
  • Polycyclic Aromatic Hydrocarbons (PAHs) are hydrophobic and most are practically insoluble in water contributing to their persistence in the environment. In addition, most exist in strongly adsorbed forms when they are introduced into the soils. Their removal efficiency can be limited in low mass transfer phases, such as PAHs-contaminated soils, because most chemical and biological remediation technologies require transfer from NAPs (Non-Aqueous Phase Liquids) into the mobile phase. (omitted)

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Preparation of magnetic gelatin microspheres for the targeting of drugs

  • Lee, Kang-Choon;Koh, Ik-Bae;Oh, In-Joon
    • Archives of Pharmacal Research
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    • v.9 no.3
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    • pp.145-152
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    • 1986
  • Magnetically reponsive gelatin microspheres for the targeting of drugs have been prepared using a water-in-oil emulsion technique with chemical cross-linking of the protein. The manufacturing variables affecting microsphere size, size distribution and surface characteristics have been examined as well as the magnetic responsiveness in vitro. Sesame oil was utilized for non-aqueous phase and magentic gelatin microspheres of different size from 1. 89 to 14.88 $\mu\textrm{m}$ in mean diameter could be obtained with variation of HLB values of non-ionic surfactants. The content of magnetite which uniformly distributed throughout the microspheres was 26.7% (w/w). It was possible to control the localization of magnetic gelatin microspheres at specific sites within capilary models by using external magnetic field of under 5K gauss.

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Viscosity Measurement of Non-Newtonian Fluids Using the Transient Flow Phenomena in the Capillary Tube (모세관내 과도유동현상을 이용한 비뉴턴유체의 점도측정)

  • Cho, Min-Tae;Suh, Sang-Ho;Yoo, Sang-Sin
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.738-741
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    • 2001
  • The purpose of the present study is to measure the viscosity of liquid in the capillary tube viscometer using the unsteady flow concept. The capillary tube viscometer is consisted of a small cylindrical reservoir, capillary tubes, and the mass flow rate measuring system interfaced with computer. Two capillary tubes with 1.152 and 3.002 mm I.D. are used to determine the diameter effects on the viscosity measurements. The instantaneous shear rate and gravitational driving force in the capillary tube are determined by measuring the mass flow rate through the capillary tube instantaneously. The measured viscosities of water and aqueous Separan solution are in good agreement with the reported experimental data.

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A Study on the Helical Flow of Newtonian and Non-Newtonian Fluid

  • Woo, Nam-Sub;Hwang, Young-Kyu;Kim, Young-Ju
    • International Journal of Air-Conditioning and Refrigeration
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    • v.15 no.1
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    • pp.1-9
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    • 2007
  • This study concerns the characteristics of helical flow in a concentric and eccentric annulus with a diameter ratio of 0.52 and 0.9, whose outer cylinders are stationary and inner ones are rotating. Pressure losses and skin friction coefficients have been measured for fully developed flows of water and 0.2% aqueous of sodium carboxymethyl cellulose (CMC), respectively, when the inner cylinder rotates at the speed of 0-500 rpm. The effect of rotation on the skin friction is significantly dependent on the flow regime. In all flow regimes, the skin friction coefficient is increased by the inner cylinder rotation. The change of skin friction coefficient corresponding to the variation of rotating speed is large for the laminar flow regime, whereas it becomes smaller as Re increases for the transitional flow regime and, then, it gradually approach to zero for the turbulent flow regime.

Blood Viscosity Measurements Using a Pressure-Scanning Capillary Viscometer

  • Sehyun Shin;Keum, Do-Young;Ku, Yun-Hee
    • Journal of Mechanical Science and Technology
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    • v.16 no.12
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    • pp.1719-1724
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    • 2002
  • A previously designed capillary viscometer with measuring differential pressure was modified to measure the viscosity of non-Newtonian fluids including unadulterated blood continuously over numerous shear rates in a single measurement. Because of unavoidable experimental noise and a limited number of data, the previous capillary viscometer experienced an inaccuracy and could not directly determine a viscosity without an iterative calculation. However, in the present measurement there are numerous data available near the point of interest so that the numeric value of the derivative, d(In Q)/d(In Q$\sub$w/), is no longer sensitive to the method of differentiation. In addition, relatively low and wide shear rate viscosity measurements were possible because of the present precision pressure-scanning method with respect to time. For aqueous polymer solutions, excellent agreement was found between the results from the pressure-scanning capillary viscometer and those from a commercially available rotating viscometer. In addition, the pressure-scanning capillary viscometer measured the viscosity of unadulterated whole blood without adding any anticoagulants.

Studies on the Viscoelasticities of Acetal Type Nonionic Surfactants (아세탈형(型) 비(非)이온성(性) 계면활성제(界面活性劑)의 점탄성(粘彈性)에 관한 연구(硏究))

  • Shon, Joo-Hwan;Lee, Seung-Youl;Nam, Ki-Dae;Kim, Yu-Bae
    • Journal of the Korean Applied Science and Technology
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    • v.5 no.1
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    • pp.53-62
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    • 1988
  • Properties of aqueous solution, that is, the viscosities and solubilities of benzene were observed in relation to critical micelle concentration of each alkyl aldehyde polyoxyethylene glycol acetal type surfactant. These showed that the mininum points in specific viscosity/concentration-concentration curves were corresponded with the critical micelle concentration obtained by surface tension and appeared the remarkable increase of non-Newtonics according to the increase of the number of carbon in hydrophobic groups. The fluidity of non-Newtonics is not observed by a little increase of the degree of polymerization in polyoxyethylene glycol groups.

Nucleation Process of Indium on a Copper Electrode

  • Chung, Yonghwa;Lee, Chi-Woo
    • Journal of Electrochemical Science and Technology
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    • v.4 no.3
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    • pp.93-101
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    • 2013
  • The electrodeposition of indium onto a copper electrode from an aqueous sulfate solution containing $In^{3+}$ was studied by means of cyclic voltammetry and chronoamperometry. Reduction and oxidation of indium on copper were investigated by using cyclic voltammograms at different negative limiting potentials and at different scan rates in cumulative cycles. Cyclic voltammograms indicated that reduction and oxidation processes of indium could involve various reactions. Chronoamperometry was carried out to analyze the nucleation mechanism of indium in the early stage of indium electrodeposition. The non-dimensional plot of the current transients at different potentials showed that the shape of the plot depended on the applied potential. The nucleation of indium at potential step of -0.6~-0.8 V was close to progressive nucleation limited by diffusion. However the non-dimensional plot of current transients for the indium nucleation showed different behaviors from theoretical curves at the potential step lower than -0.8 V.

A Study on the One Bath Two Step Dyeing of Nylon/ Cationized Cotton Blends with Acid Dye/Direct Dye (나일론/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕 2단 염색에 관한 연구)

  • 성우경
    • Textile Coloration and Finishing
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    • v.12 no.1
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    • pp.44-51
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    • 2000
  • The conventional one bath exhaust dyeing system of nylon]/cotton blends with acid dye/direct dye involves a lot of neutral salt which affect dyeability of acid dyes. Because of conventional one bath exhaust dyeing system of nylonl/cotton blends with acid dye/direct dye needs acid dyes adjusted at a neutral liquor, suitable acid dye is limited. To improve dyeing property of nylon/cotton blends, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate dyeing possibilities of nylon/cationized cotton blends with acid dye/direct dye in a non-neutral salt dyebath by one bath two step method. The concentration of direct dye was 1.0%, 0.7%, 0.3%o.w.f. respectively at a non, 1%, 3%owf of reserving agent for being almost equal color strength between nylon and 3% cationized cotton when nylon/3% cationized cotton blends was dyed with acid dye/direct dye at concentration of acid dye(1%o.w.f.) by one bath two step method.

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A Study on the One Bath Two Step Dyeing of Wool/Cationized Cotton Blends With Acid Dye/Direct Dye (양모/카티온화 면 혼방품의 산성염료/직접염료에 의한 1욕2단 염색에 관한 연구)

  • Sung, Woo-Kyung;Lee, Choon-Gil
    • Fashion & Textile Research Journal
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    • v.3 no.2
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    • pp.168-173
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    • 2001
  • In order to overcome the disadvantage of the conventional two bath dyeing method of wool/cotton blends, it had prompted significant effort to the development of the one bath dyeing method which can accomplish savings in energy, water usage and time. To improve the dyeability of cotton toward direct dyes in a non-electrolytic and acidic dyebath, cotton component was pretreated with cationizing agent containing chlorohydrine group in aqueous solution of sodium hydroxide. This study was carried out to investigate almost equal color strength between wool component and cationized cotton component when wool/cationized cotton blends was dyed with acid dye/direct dye by the one bath two step method in a non-electrolytic and acidic dyebath.

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Manufacturing Polymer/clay Nanocomposites Using a Supercritical Fluid Process

  • Jung, Hyun-Taek;Yoon, Ho-Gyu;Lim, Soon-Ho
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.4
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    • pp.63-65
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    • 2008
  • The increased interest in reducing the environmental effects caused by releasing organic compounds and aqueous waste has motivated the development of polymeric materials in supercritical fluids. Recently, supercritical fluids have been used in material synthesis and processing because of their special properties, such as high diffusivity, low viscosity, and low surface tension. Supercritical carbon dioxide is the most attractive because it is non-toxic, non-flammable, and has moderate critical temperature and critical pressure values. Supercritical carbon dioxide can also swell most polymers. In this study, we prepared polymer/clay nanocomposites using supercritical fluids. Cloisites 10A, 15A, 25A, and 30B used in this study are montmorillonites modified with a quaternary ammonium salt. The nanocomposites of polymer/clay were characterized by X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry.