• 한국환경과학회지
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• 제16권10호
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• pp.1157-1167
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• 2007

In an effort to interpret the characteristics of fine particle concentrations in Busan, time variations of hourly monitored concentrations $PM_{10}$ (Particulate Matter with aerodynamic Diameter ${\le}10\;{\mu}m$) in Busan are analyzed for the period from 2000 to 2005. The characteristics of aerosol second generation formation process is also interpreted qualitatively, by using the statistical analysis of the meteorological variables including temperature, wind speed, and relative humidity. The result shows some significant annual, seasonal, weekly and diurnal variations of $PM_{10}$ concentrations. In particular, seasonal(i.e., spring) variations are governed by frequency of yellow sand events even for the non-yellow sand cases where yellow-sand days are eliminated in our analysis. However, in seasonal variation, summer season predominate lower $PM_{10}$ concentrations due to the frequent precipitation, and weekly and diurnal variations are both found to be reflecting the emission rate from traffic amount. Correlation coefficients between $PM_{10}$ concentration and meterological variables for non-yellow sand days show overall negative correlation with visibility, wind speed, cloud amounts, and relative humidity. However for non-precipitation days, during non-yellow sand period positive correlation are found clearly with relative humidity, suggesting the importance of secondary aerosol formation in Busan that can be achieved by both homogeneous aerosol formation and heterogeneous transformations resulting from hygroscopic aerosol characteristics.

• 한국산학기술학회논문지
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• 제19권1호
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• pp.596-602
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• 2018

최근 나노임프린트 리소그래피 공정이 마이크로/나노 스케일의 소자 개발에 있어서 경제적으로 대량 생산할 수 있는 기술로 주목 받고 있다. 자외선경화 방식의 나노임프린트의 경우 상온 및 저압의 장점과 함께 비진공 환경에서 공정을 통하여 설비 비용의 저감과 생산공정의 고속화를 달성할 수 있다. 그러나 이 경우 비진공 환경에서 발생하는 기포결함의 문제를 해결해야만 한다. 본 연구에서는 비진공 환경에서의 자외선경화 방식의 나노임프린트 공정에서 몰드 중공부 단면의 형상과 기포결함 발생 관계를 연구하였다. 일반적으로 많이 사용되는 사각형 단면과 타원형 단면 그리고 삼각형 단면에 대하여 2차원 유동해석 및 VOF 방법을 통하여 기포결함을 시뮬레이션 하였고 단면의 형상과 다양한 접촉각에 따른 유동선단의 특성을 분석하였다. 해석결과 몰드 중공부 형상은 기포결함 발생에 매우 중요한 영향을 미치며, 고려된 형상 모두 몰드와의 접촉각이 작을수록, 기판과의 접촉각이 클수록 기포결함 발생 가능성이 작아짐을 알 수 있었다. 또한 타원형 형상이 기포결함 발생방지 측면에서 가장 효과적임을 확인하였다.

• Journal of Periodontal and Implant Science
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• 제38권3호
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• pp.535-542
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• 2008

Purpose: The aim of this retrospective study is to evaluate survival rate of implant and bone formation, to analyze failure contribution factor. Material and Methods: A total of 52 consecutive patients(35 male, 17 female, mean age 49 years) with 104 osseous defects were treated during the period from October 2004 to June 2007 with a simultaneous or staged GBR approach using non-resorbable or resorbable membranes combined with autogenous bone grafts or xenograft(Bio-Oss, Bio-cera, BBP). Result: A total of 32(30,8%) of 104 GBR-treated sites failed the bone formation and a total of 5(5.6%) of 89 implants were removed. Early exposure of the membrane has significantly affected bone formation(p<0.05). Non-resorbable membrane showed more exposure of the membrane and low success rate of bone formation than resorbable membrane(p<0.05). There were no difference between success rate of bone formation and using autogenous bone or graft materials. There were no statistically significant difference between success rate of bone formation and smoking or using PRP. Mandible showed more success rate of bone formation than maxilla(p<0.05). Conclusion: Early exposure of the membrane, membrane type and maxilla/mandible type have influence on success rate of bone formation during GBR.

• 한국산학기술학회논문지
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• 제14권9호
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• pp.4178-4184
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• 2013

최근 나노임프린트 리소그래피 공정이 마이크로/나노 스케일의 소자 개발에 있어서 경제적으로 대량 생산할 수 있는 기술로 주목 받고 있다. 최근 나노임프린트 기술은 공정의 고속화 및 대면적화를 통한 대량생산 기술로의 전환을 목표로 하고 있다. 자외선경화 방식의 나노임프린트의 경우 상온 및 저압의 장점과 함께 비진공 환경에서 공정이 가능하다면 진공챔버 및 고압 스테이지 등과 같은 고가의 장비가 필요 없게 됨으로써 설비비용을 낮추고 공정시간을 단축하는데 큰 기여를 할 수 있다. 그러나 비진공 환경에서는 기포결함이 종종 발생하게 된다. 본 연구에서는 비진공 환경에서의 자외선경화 방식의 나노임프린트 공정 중 레지스트의 액적도포 방법에 따른 기포형성을 연구하였다. 액적의 양과 액적의 수를 달리하여 도포한 레지스트에 대하여 충전 후 기포결함 발생을 분석하였다.

• 소성∙가공
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• 제20권7호
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• pp.504-511
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• 2011

The alkaline earth metal Ba has a relatively low melting point. Because of its significantly high affinity to oxygen, nitrogen and sulfur, it is highly functional as a steel refining agent. But Ba can adversely affect the properties of steel especially the workability, because it can form a variety of inclusions. So, understanding of these inclusions is needed for improvement of the properties of steel. Thus a fundamental study in the formation behavior of non-metallic inclusions in Ba added Hyper Duplex STS melts was investigated. The amount of Ba, holding time and temperature were considered as experimental variables. The number of non-metallic inclusions decreased and the large particle size of non-metallic inclusions increased as the amount of Ba increased. The number of non-metallic inclusions also decreased and the large particle size increased with increased holding times and temperatures of molten steel.

• Bulletin of the Korean Chemical Society
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• 제24권11호
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• pp.1609-1612
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• 2003

The electrooxidation of 8-(3-acetylimino-6-methyl 2,4-dioxopyran)-1-aminonaphthaline (AMDAN) in aqueous and non aqueous media led to the formation of polymeric films, poly (AMDAN). The monomer, undergo anodic oxidation through the formation of a monocation radical irrespective of the nature of the medium. In aqueous medium, the monocation radical undergoes, through its resonance structures, dimerisation involving tail-to-tail, head-to-tail and even head-to-head coupling. The products formed, being more easily oxidisable than the parent substance, undergo further oxidation at the same potential so that the overall oxidation involves a one-step (i.e., a single wave), two-electron process. In non-aqueous medium, the monocation radical does not undergo dimerisation through coupling reactions. Retaining its identity, monomer oxidise in two steps involving one electron in each step. The fact that the cathodic peaks corresponding to these anodic peaks are rarely observed indicates fast consumption of the electrogenerated monocation radicals and dications by follow-up chemical reactions to produce polymeric products (poly AMDAN). The electrochemical behavior of the formed polymer films was investigated in both non aqueous and aqueous media. The films prepared in non aqueous medium were found to be more electroactive than that the films prepared in aqueous medium. This is confirmed with the results in litreature which illustrate that the film prepared in aqueous solution hold water in its structure via hydrogen bonding, which causes decomposition reactions.

• 한국미생물·생명공학회지
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• 제22권2호
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• pp.115-119
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• 1994

White mutant of Ganoderma lucidum(G4142) induced the non-basediocarpous basidiospores(NBB) from the aerial mycelia on agar media by the light illumination. Light was found to be necessary for NBB formation, but it also inhibited the growth of mycelium. The best sporulation was obtained at the periodic exposure of 16 hour light and 8 hour dark. Blue and yellow light were the most effective on sporulation, however, near UV and red light did not induce any spores. Effective light intensity for NBB bearing was about 1,000 lux as white light. Even after 16 days of culture, this strain did not form the pinhead nor chlamydospore. Optimum temperature for the mycelial growth and NBB formation were 30$\circ $C. Ganoderma lucidum G4142 exhibited the formation of stroma after five days of incubation at 30$\circ $C.

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.909-914
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• 2011

An improved convergent and economical method has been developed for the synthesis of erlotinib, a 4-anilinoquinazoline and an EGFR-tyrosine kinase inhibitor for treatment of non-small-cell lung cancer. The final two steps for the formation of this 4-anilinoquinazoline from suitable 2-aminobenzonitrile intermediate and 3-ethynylaniline were modified and were performed in a simple one-pot reaction. The ring-closing mechanism for the formation of erlotinib from the suitable formamidine intermediate and 3-ethynylaniline was investigated and determined to proceed via the formation of phenyl benzamidine intermediate rather than involving Dimroth rearrangement reported earlier. The new benzamidine intermediate was isolated for the first time and characterized.

• 대한기계학회논문집B
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• 제26권6호
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• pp.833-841
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• 2002

The present study examined the possibility of NOx reduction in the high temperature industrial furnaces, duct burner of gas turbine cogeneration and two-stage gas turbine combustor. The experimental study was carried out for the non-premixed flame of second stage combustor with the variations of oxygen concentration in the hot exhaust gas of first stage combustor. It also examined the flammability range, temperature and NOx, $CO_2$, $O_2$formation in the combustor with respect to oxygen concentration in which the fuel(natural gas) is supplying into the hot exhaust gas. The results show that the inner temperature of flame reaches 1,20$0^{\circ}C$ at EGR $O_2$23% and that 15ppm of NOx at EGR $O_2$15.5% increases up to 60ppm at EGR $O_2$23%. It is believed that Fenimore＇s prompt NOx mechanism is more influential on the NOx formation than Zeldovich＇s thermal NOx mechanism does.

• Journal of Microbiology and Biotechnology
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• 제25권10호
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• pp.1648-1652
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• 2015

Azaphilone polyketides are synthesized by iterative non-reducing fungal polyketide synthases (NR-fPKSs) with a C-terminus reductive domain (-R). Several azaphilone biosynthetic gene clusters contain a putative serine hydrolase gene; the Monascus azaphilone pigment (MAzP) gene cluster harbors mppD. The MAzP productivity was significantly reduced by a knockout of mppD, and the MAzP NR-fPKS-R gene (MpPKS5) generated its product in yeast only when co-expressed with mppD. Site-directed mutations of mppD for conserved Ser/Asp/His residues abolished the product formation from the MpPKS5/mppD co-expression. MppD and its homologs are thus proposed as a new protein factor involved in the product formation of NR-fPKS-R.