• Title/Summary/Keyword: Non-Determination

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Verification of Viscosity Measurement for Identifying Irradiated Brown Rice (현미의 방사선 처리여부 판별을 위한 점도측정법의 검증)

  • Lee, Jeong-Eun;Jo, Deok-Jo;Choi, Mal-Gum;Kim, Hyun-Ku;Kim, Jeong-Sook;Kwon, Joong-Ho
    • Korean Journal of Food Science and Technology
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    • v.42 no.2
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    • pp.240-245
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    • 2010
  • Brown rice of Korea and China was irradiated at doses ranging from 0 to 15 kGy to verify the identification properties of viscosity measurement by determining the relationship between starch content and specific parameters. The starch contents of brown rice were 71.52 and 64.58% for rice of Korea and China, respectively. Additionally, a higher starch content was associated with a higher viscosity. The viscosity and the corresponding specific parameters decreased significantly as the irradiation dose increased, and these changes were influenced by the spindle speed (50, 150, 300 rpm), with a higher effect being observed at lower speeds. The determination coefficients ($R^2$) describing the relationship between irradiation dose and viscosity values ranged from 0.9423 to 0.9567 in Korean samples and from 0.9119 to 0.9387 in Chinese samples. The viscosity and the corresponding specific parameters enabled identification of the non-irradiated and irradiated brown rice from 30 unknown samples with an accuracy of 90%. Based on these findings, the viscosity and specific parameters can be applied as an additional tool for screening of irradiated brown rice.

Development of Disposable Immunosensors for Rapid Determination of Sildenafil and Vardenafil in Functional Foods

  • Vijayaraj, Kathiresan;Lee, Jun Hyuck;Kim, Hyung Sik;Chang, Seung-Cheol
    • Journal of Food Hygiene and Safety
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    • v.32 no.2
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    • pp.83-88
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    • 2017
  • We introduced disposable amperometric immunosensors for the detection of Sildenafil and Vardenafil (SDF/VDF) based on screen printed carbon electrodes. The developed immunosensors were used as a non-competitive sandwich-type enzyme immunoassay with a horseradish peroxidase label. The sensors were constructed on screen printed carbon electrodes by the simple electrochemical deposition of a reduced graphene oxide and chitosan (ErGO-CS) composite. To evaluate the sensing chemistry and optimize the sensor characteristics, a series of electrochemical experiments were carried out including electrochemical impedance spectroscopy, cyclic voltammetry and amperometry. The sensors showed a linear response to SDF/VDF concentrations in a range from 100 pg/mL to 300 ng/mL. The lower detection limit was calculated to be 55 pg/mL, the sensitivity was calculated to be $1.02{\mu}Ang/mL/cm^2$, and the sensor performance exhibited good reproducibility with a relative standard deviation (RSD) of 7.1%. The proposed sensing chemistry strategy and the sensor format can be used as a simple, cost-effective, and feasible method for the in-field analysis of SDF/VDF in functional or health supplement food samples.

Determination of Vitamin B6 Content using HPLC in Agricultural Products cultivated in Local Areas in Korea (HPLC를 이용한 지역 농산물의 비타민 B6 함량 분석)

  • Choi, So-Ra;Song, Eun-Ju;Song, Young-Eun;Choi, Min-Kyung;Han, Hyun-Ah;Lee, In-Sok;Shin, So-Hee;Lee, Ki-Kwon;Choi, Young-Min;Kim, Haeng-Ran
    • The Korean Journal of Food And Nutrition
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    • v.30 no.4
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    • pp.710-718
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    • 2017
  • Contents of water soluble vitamin $B_6$ in a total of 62 agricultural products cultivated in local areas in Korea were analyzed by high performance liquid chromatography with fluorescence detector (HPLC/FLD). To verify the method of vitamin $B_6$ analysis, a quality control chart was formulated with in-house control using a mixture of broccoli and shiitake mushrooms. Among cereals, high content of vitamin $B_6$ measured $234.3{\sim}260.3{\mu}g/100g$ in dried mung bean and soybean. Vitamin $B_6$ content of non-glutinous and glutinous black rice measured $105.0{\mu}g/100g$ and $129.7{\mu}g/100g$, respectively. In vegetables, high content of vitamin $B_6$ were measured in passion fruit ($104.3{\mu}g/100g$), gat ($55.7{\sim}84.3{\mu}g/100g$), gomchwi ($31.3{\sim}88.0{\mu}g/100g$) and garlic ($72.7{\sim}98.3{\mu}g/100g$). Among fruits, gold kiwi 'Zespri' and green kiwi 'Hayward' revealed high vitamin $B_6$ content of $116.3{\mu}g/100g$ and $78.7{\mu}g/100g$, respectively. In persimmons, daebongsi had high vitamin $B_6$ content ($36.0{\sim}72.7{\mu}g/100g$) than bansi and sweet persimmon. Vitamin $B_6$ content in dried jujube and persimmon increased more than $86.7{\mu}g/100g$ compared to fresh materials. Among specialty crops, green tea powder ($64.7{\sim}251.0{\mu}g/100g$) and sansuyu ($172.3{\mu}g/100g$) revealed high content. Of mushrooms, vitamin $B_6$ content of Sparassis crispa ($139.3{\mu}g/100g$) was the highest. Vitamin $B_6$ content information of agricultural products in local areas in Korea collected from this experiment will be used as valuable preliminary data for grasp national nutritional status.

Determination of operating offline detention reservoir considering system resilience (시스템 탄력성을 고려한 빗물저류조 운영수위 결정)

  • Lee, Eui Hoon;Lee, Yong Sik;Jung, Donghwi;Joo, Jin Gul;Kim, Joong Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.10
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    • pp.403-411
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    • 2016
  • Recently, the number of occurrences of inundation and the severity of flood damage has increased rapidly as the frequency of localized heavy rainfall and the ratio of impervious area increased in urban areas. Most local governments focus on employing structural measures (e.g., the construction of detention reservoirs/pump stations, rehabilitation of drainage and sewer pipes) to prevent urban inundation. On the other hand, the effectiveness of implementing such structural measures is being dimished because there are already many inundation prevention facilities. The limitation of structural measures can be overcoming by employing non-structure measures, such as flood alerts and the operation of drainage facilities. This study suggests the pump operation rule (i.e., suggesting pump stop level) for a new detention reservoir operating method, which triggers the operation of a pump based on the water level at the monitoring node in urban drainage system. In the new reservoir operation, a total of 48 rainfall events are generated by the Huff distribution for determining the proper pump stop level. First, the generated rainfall events are distributed as frequencies, quartiles, and durations. The averaged system resilience value was determined to range from 1.2 m to 1.5 m is based on the rainfall-runoff simulation with rainfall generated by the Huff distribution. In this range, 1.2 m was identified considering the safety factor of 1.25 by the Standard on sewer facilities in 2011.

Mathematical Description of Soil Loss by Runoff at Inclined Upland of Maize Cultivation (옥수수 재배 경사지 밭에서 물 유출에 따른 토양유실 예측 공식)

  • Hur, Seung-Oh;Jung, Kang-Ho;Ha, Sang-Keon;Kwak, Han-Kang;Kim, Jeong-Gyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.2
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    • pp.66-71
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    • 2005
  • Soil loss into stream and river by runoff shall be considered for non-point source pollution management as national land conservation. The purpose of this study was to develop the mathematical equation to predict soil loss from inclined uplands of maize cultivation due to the runoff by rainfall which mainly converges on July and August. Soil loss was concentrated on May because of low canopy over an entire field in 2002 and on June and July because of heavy rainfall in 2003. By regression analysis the relation between runoff and soil loss can be represented by a linear equation of y =1.5291x - 3.4933, where y is runoff ($Mg\;ha^{-1}$) and x is soil loss ($kg\;ha^{-1}$). The determination coefficient of this equation was 0.839 (P<0.001). Therefore, the mathematical equation derived from the practical experiment at the inclined upland can be applicable to predict soil loss accompanied by runoff due to periodic rainfall converging on short periods within a couple of months.

Quantification of Chloride Diffusivity in Steady State Condition in Concrete with Fly Ash Considering Curing and Crack Effect (재령 및 균열효과를 고려한 플라이애시 콘크리트의 정상상태 염화물 확산 특성의 정량화)

  • Yoon, Yong-Sik;Cheon, Ju-Hyun;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.109-115
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    • 2019
  • In case of the cracks in concrete, the penetration of deterioration ions such as chloride ions in to cracks is accelerated. According to the penetration of chloride ions, structural and durability problems to RC(Reinforced Concrete) structures are caused. In this study, the accelerated chloride diffusion coefficient which is in steady state is evaluated for 2 year aged normal and high strength FA(Fly Ash) concrete, after a range of crack depths are induced up to 1.0 mm in 56 aged day. Considering crack effect by linear regression analysis, high strength concrete has slightly less increasing ratio of diffusion coefficient by crack than normal strength concrete, and diffusion coefficient increases non-linearly as crack width is increased. Also, In two types of concrete, crack effect decrease as the curing period increase. In the case of quantifying crack and curing effect by using exponential function form, the coefficients of determination are higher than those of linear regression analysis. Under steady state, it is thought that there is not a high correlation between the crack effect and the curing effect, and considering the two independent effects, it is believed that reasonable prediction equation for diffusion of concrete with crack can be proposed.

An Experimental Study for the Hydraulic Characteristics of Vertical lift Gates with Sediment Transport (퇴적토 배출을 수반한 연직수문의 수리특성에 관한 실험적 연구)

  • Choi, Seung Jea;Lee, Ji Haeng;Choi, Heung Sik
    • Ecology and Resilient Infrastructure
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    • v.5 no.4
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    • pp.246-256
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    • 2018
  • In order to analyze hydraulic characteristics of discharge coefficient, hydraulic jump height, and hydraulic jump length, accompanied sediment transport, in the under-flow type vertical lift gate, the hydraulic model experiment and dimensional analysis were performed. The correlations between Froude number and hydraulic characteristics were schematized according to the presence and absence of sediment transport; the correlation of hydraulic characteristics and non-dimensional parameters was analyzed and multiple regression formulae were developed. In the hydraulic characteristics accompanied the sediment transport, by identifying the aspect different from the case that the sediment transport is absent, we verified that it is necessary to introduce variables that can express the characteristics of sediment transport. The multiple regression equations were suggested and each determination coefficient appeared high as 0.749 for discharge coefficient, 0.896 for hydraulic jump height, and 0.955 for hydraulic jump length. In order to evaluate the applicability of the developed hydraulic characteristic equations, 95% prediction interval analysis was conducted on the measured and the calculated by regression equations, and it was determined that NSE (Nash-Sutcliffe Efficiency), RMSE (root mean square), and MAPE (mean absolute percentage error) are appropriate, for the accuracy analysis related to the prediction on hydraulic characteristics of discharge coefficient, hydraulic jump height and length.

Development of Individual Residue Analysis Method for Cyanazine in Agricultural Commodities as an Unregistered Herbicide in Korea (국내 미등록 제초제 cyanazine의 농산물 중 개별 잔류분석법 개발)

  • Choung, Myoung-Gun;Im, Moo-Hyeog
    • Journal of the Korean Society of International Agriculture
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    • v.30 no.4
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    • pp.339-346
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    • 2018
  • Cyanazine is a member of the triazine family of herbicides. Cyanazine is used as a pre- and post-emergence herbicide for the control of annual grasses and broadleaf weeds. This experiment was conducted to establish a determination method for cyanazine, as domestic unregistered pesticide, residue in major agricultural commodities using HPLC-DAD/MS. Cyanazine was extracted with acetone from representative samples of five raw products which comprised apple, green pepper, Kimchi cabbage, hulled rice and soybean. The extract was diluted with saline water and partitioned to dichloromethane for remove polar extractive in the aqueous phase. For the hulled rice and soybean samples, n-hexane/acetonitrile partition was additionally employed to remove non-polar lipids. The extract was finally purified by optimized florisil column chromatography. On a $C_{18}$ column in HPLC, cyanazine was successfully separated from co-extractives of sample, and sensitively quantitated by diode array detection at 220 nm. Accuracy and precision of the proposed method was validated by the recovery experiment on every major agricultural commodity samples fortified with cyanazine at 3 concentration levels per agricultural commodity in each triplication. Mean recoveries were ranged from 83.6 to 93.3% in five major representative agricultural commodities. The coefficients of variation were all less than 10%, irrespective of sample types and fortification levels. Limit of quantitation(LOQ) of cyanazine was 0.02 mg/kg as verified by the recovery experiment. A confirmatory method using LC/MS with selected-ion monitoring(SIM) technique was also provided to clearly identify the suspected residue.

An Empirical Study on the Profit Margin Adequacy of Korean General Insurance (국내 일반보험 예정이익률 적정성에 관한 실증연구)

  • Park, Geunyong;Kim, So-Yeun
    • The Journal of the Korea Contents Association
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    • v.21 no.6
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    • pp.588-597
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    • 2021
  • In Korea, the standard for calculating the profit of a general insurance, which constitutes the loading in the premium, is not specified, and most of the non-life insurance companies reflect 2~5% of the premium as profit margin. Although the transparency of pricing is required due to the nature of insurance products, there are insufficient standards and empirical studies on the determination of insurance price factors in the domestic insurance industry. In this study, we propose a method of calculating the expected profit margin of general insurance. A way for calculating the expected profit margin of the general insurance is to reflect the shareholder demand on the capital that the insurance company should secure against the risk of loss due to the profit/loss volatility, as a ratio to the insurance premium. Shareholders should be compensated for the risks associated with their insurance operations, and the opportunity cost of these shareholders is to be reflected in premiums. In this study, we calculate the amount of capital that the company should accumulate to prepare insurance risk for each product, and insurance risk is defined as the volatility of insurance operating profit/loss. And insurance risk is calculated using stochastic simulation based on Dynamic Financial Analysis (DFA) methodology. Finally, we calculate the expected profit margins for 25 products and analyzed the difference between those and the profit ratio of domestic general insurance.

Determination of Thermoluminescence Properties of MgB4O7 Doped with Dy3+, La3+ and Ho3+ for a Light Tracer Application (비화공식 예광탄 응용을 위한 Dy3+, La3+ 그리고 Ho3+이 도핑된 MgB4O7의 열 발광 특성 분석)

  • Park, Jinu;Kim, Nakyung;Choi, Jiwoon;Koh, Jaehyuk;Chin, Hee Sik;Jung, Duck Hyeong;Shin, Byungha
    • Korean Journal of Materials Research
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    • v.32 no.1
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    • pp.9-13
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    • 2022
  • Bullets flying with a light from the back are called "tracers". Tracers are ignited by the combustion gas of the propellant and emit bright light that allows the shooter to visually trace the flight path. Therefore, tracers mark the firing point for allies to assist shooters to hit target quickly and accurately. Conventional tracers are constructed with a mixture of an oxidizing agent, raw metal, and organic fuel. Upon ignition, the inside of the gun can be easily contaminated by the by-products, which can lead to firearm failure during long-term shooting. Moreover, there is a fire risk such as forest fires due to residual flames at impact site. Therefore, it is necessary to develop non-combustion type luminous material; however, this material must still use the heat generated from the propellant, so-called "thermoluminescence (TL)". This study aims to compare the TL emission of Dy3+, La3+ and Ho3+ doped MgB4O7 phosphors prepared by solid state reaction. The crystal structures of samples were determined by X-ray diffraction and matched with the standard pattern of MgB4O7. Luminescence of various doses (200 ~ 15,000 Gy) of gamma irradiated Dy3+, La3+ and Ho3+ (at different concentrations of 5, 10, 15 and 20 %) doped MgB4O7 were recorded using a luminance/color meter. The intensity of TL yellowish (CIE x = 0.401 ~ 0.486, y = 0.410 ~ 0.488) emission became stronger as the temperature increased and the total gamma-ray dose increased.