• Title/Summary/Keyword: Non-Cement Matrix

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Strength properties according to mixing type and ratio Alkali activator of Non-cement matrix using Paper Ash and Polysilicon sludge (폴리실리콘 슬러지와 제지애시를 활용한 무시멘트 경화체의 알칼리자극제 종류 및 혼입율에 따른 강도특성)

  • Sin, Jin-Hyun;Kim, Tae-Hyun;Kim, Heon-Tae;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.173-174
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    • 2017
  • Recently, many experiments using industrial by-products have been going on in Korea and abroad. Most of the studies on blast furnace slag and fly ash have been conducted, and the blast furnace slag based two and three component experiments have been conducted in many places. Therefore, this study is an additional study of research using polysilicon sludge and paper ash, which is a study using existing industrial by-products based on blast furnace slag, as strength properties of alkali activator according to kind and mixing ratio and to obtain basic data do.

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Solidification/Stabilization of Dyeing Sludge Treated by Fenton Reagent Using Blast Furnace Slag and Fly Ash

  • Lee, Sookoo;Kim, Sebum
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.453-458
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    • 2001
  • This study was performed to reuse the dyeing wastewater sludge treated by Fenton process through the solidification/stabilization technique. To solidify the dyeing sludge the industrial by-products such as blast furnace slag, fly ash and waste sand with cement were used. The laboratory scale and pilot scale test were conducted at room temperature to make construction brick which has high compressive strength and low leaching of heavy metals. The experimental results showed that blast furnace slag and fly ash could be used instead of cement and the products satisfied the regulation of Korean Standards. The blast furnace slag increased the compressive strength and the optimum ratio of slag/dyeing sludge on dry basis was found 0.4. The solidifying agent of SB series could increase rapidly the compressive strength and the optimum ratio of solidifying agent/sludge on dry basis was 0.26 at which the strength was two times compared with non-added condition. The portion of waste and industrial by-products in matrix was over 80%. From the pilot test the optimum pressure in molding was 100kg/$\textrm{cm}^2$ at which the compressive strength was over 100kg/$\textrm{cm}^2$. And the strength increased continuously to 160kg/$\textrm{cm}^2$ until 120 days curing time due to pozzolanic reaction. When SB-20 as a solidifying agent was used, the unconfined compressive strength of dyeing sludge could be obtained 110kg/$\textrm{cm}^2$ which satisfied the regulation of cement brick in Korea Standard(KS).

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Multiple Cracking Model of Fiber Reinforced High Performance Cementitious Composites under Uniaxial Tension

  • Wu, Xiangguo;Han, Sang-Mook
    • International Journal of Concrete Structures and Materials
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    • v.3 no.1
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    • pp.71-77
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    • 2009
  • A theoretical model of multiple cracking failure mechanism is proposed herein for fiber reinforced high performance Cementitious composites. By introducing partial debonding energy dissipation on non-first cracking plane and fiber reinforcing parameter, the failure mechanism model of multiple cracking is established based on the equilibrium assumption of total energy dissipation on the first crack plane and non-first cracking plane. Based on the assumption of the first crack to be the final failure crack, energy dissipation terms including complete debonding energy, partial debonding energy, strain energy of steel fiber, frictional energy, and matrix fracture energy have been modified and simplified. By comparing multiple cracking number and energy dissipations with experiment results of the reference's data, it indicates that this model can describe the multiple cracking behavior of fiber reinforced high performance cementitious composites and the influence of the partial debonding term on energy dissipation is significant. The model proposed may lay a foundation for the predictions of the first cracking capacity and post cracking capacity of fiber reinforced high performance cementitious composites and also can be a reference for optimal mixture for construction cost.

Influence of Mineral Admixtures on the Resistance to Sulfuric Acid and Sulfate Attack in Concrete (콘크리트의 황산 및 황산염 침투 저항성에 미치는 광물질 혼화재의 영향)

  • Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.219-228
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    • 2010
  • It has been well known that concrete structures exposed to acid and sulfate environments such as sewer, sewage and wastewater, soil, groundwater, and seawater etc. show significant decrease in their durability due to chemical attack. Such deleterious acid and sulfate attacks lead to expansion and cracking in concrete, and thus, eventually result in damage to concrete matrix by forming expansive hydration products due to the reaction between portland cement hydration products and acid and sulfate ions. Objectives of this experimental research are to investigate the effect of mineral admixtures on the resistance to acid and sulfate attack in concrete and to suggest high-resistance concrete mix against acid and sulfate attack. For this purpose, concretes specimens with three types of cement (ordinary portland cement (OPC), binary blended cement (BBC), and ternary blended cement (TBC) composed of different types and proportions of admixtures) were prepared at water-biner ratios of 32% and 43%. The concrete specimens were immersed in fresh water, 5% sulfuric acid, 10% sodium sulfate, and 10% magnesium sulfate solutions for 28, 56, 91, 182, and 365 days, respectively. To evaluate the resistance to acid and sulfate for concrete specimens, visual appearance changes were observed and compressive strength ratios and mass change ratios were measured. It was observed from the test results that the resistance against sulfuric acid and sodium sulfate solutions of the concretes containing mineral admixtures were much better than that of OPC concrete, but in the case of magnesium sulfate solution the concretes containing mineral admixtures was less resistant than OPC concrete due to formation of magnesium silicate hydrate (M-S-H) which is non-cementitious.

Evaluation of Hardening Properties and Dry Shrinkage of Non-Sintered Binder Based Floor Mortar Utilizing Alpha-Hemihydrate Gypsum (알파반수석고를 활용한 비소성결합재 기반 바닥 모르타르의 경화특성 및 건조수축 평가)

  • Lee, Kye-Hyouk;Kim, Gyu-Yong;Lee, Bo-Kyeong;Kim, Rae-Hwan;Shin, Kyoung-Su
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.359-365
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    • 2015
  • Floor mortar experiences dry shrinkage by temperature and humidity difference of internal matrix with material type. Also, since floor mortar is influenced by environmental conditions during placing and curing period, cracks are likely to be occurred. In this study, it was evaluated the hardening and dry shrinkage properties of non-sintered binder based floor mortar utilizing alpha-hemihydrate gypsum which has expansibility in order to prevent crack of the floor mortar. It was applied to the construction site, and examined the effects of external environmental conditions on shrinkage deformation and cracking. Different types of slag accelerated initial and final setting in comparison with cement mortar and its compressive strength was satisfied standard compressive strength for floor mortar. Also shrinkage deformation behavior after the initial expansion exhibited a similar tendency with the cement mortar. From the field application result, no crack was found from slag mortar, and it is determined that the slag mortar has better dimensional stability than cement mortar caused by external environment conditions.

Nano-engineered concrete using recycled aggregates and nano-silica: Taguchi approach

  • Prusty, Rajeswari;Mukharjee, Bibhuti B.;Barai, Sudhirkumar V.
    • Advances in concrete construction
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    • v.3 no.4
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    • pp.253-268
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    • 2015
  • This paper investigates the influence of various mix design parameters on the characteristics of concrete containing recycled coarse aggregates and Nano-Silica using Taguchi method. The present study adopts Water-cement ratio, Recycled Coarse Aggregate (%), Maximum cement content and Nano-Silica (%) as factors with each one having three different levels. Using the above mentioned control parameters with levels an Orthogonal Array (OA) matrix experiments of L9 (34) has selected and nine number of concrete mixes has been prepared. Compressive Strength, Split Tensile Strength, Flexural Tensile Strength, Modulus of Elasticity and Non-Destructive parameters are selected as responses. Experimental results are analyzed and the optimum level for each response is predicted. Analysis of 28 days CS depicts that NS (%) is the most significant factor among all factors. Analysis of the tensile strength results indicates that the effect of control factor W/C ratio is ranked one and then NS (%) is ranked two which suggests that W/C ratio and NS (%) have more influence as compared to other two factors. However, the factor that affects the modulus of elasticity most is found to be RCA (%). Finally, validation experiments have been carried out with the optimal mixture of concrete with Nano-Silica for the desired engineering properties of recycled aggregate concrete. Moreover, the comparative study of the predicted and experimental results concludes that errors between both experimental and predicted values are within the permissible limits. This present study highlights the application of Taguchi method as an efficient tool in determining the effects of constituent materials in mix proportioning of concrete.

Stable isotope and rare earth element geochemistry of the Baluti carbonates (Upper Triassic), Northern Iraq

  • Tobia, Faraj Habeeb
    • Geosciences Journal
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    • v.22 no.6
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    • pp.975-987
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    • 2018
  • Stable isotope ratios of $^{18}O/^{16}O$ and $^{13}C/^{12}C$ and rare earth elements geochemistry of the Upper Triassic carbonates from the Baluti Formation in Kurdistan Region of Northern Iraq were studied in two areas, Sararu and Sarki. The aim of the study is to quantify the possible diagenetic processes that postdated deposition and the paleoenvironment of the Baluti Formation. The replacement products of the skeletal grains by selective dissolution and neomorphism probably by meteoric water preserved the original marine isotopic signatures possibly due to the closed system. The petrographic study revealed the existence of foraminifers, echinoderms, gastropods, crinoids, nodosaria and ostracods as major framework constituents. The carbonates have micritic matrix with microsparite and sparry calcite filling the pores and voids. The range and average values for twelve carbonate rocks of ${\delta}^{18}O$ and ${\delta}^{13}C$ in Sararu section were -5.3‰ to -3.16‰ (-4.12‰) and -2.94‰ to -0.96‰ (-1.75‰), respectively; while the corresponding values for the Sarki section were -3.69‰ to -0.39‰ (-2.08‰) and -5.34‰ to -2.70‰ (-4.02‰), respectively. The bivariate plot of ${\delta}^{18}O$ and ${\delta}^{13}C$ suggests that most of these carbonates are warm-water skeletons and have meteoric cement. The average ${\Sigma}REE$ content and Eu-anomaly of the carbonates of Sararu sections were 44.26 ppm and 1.03, respectively, corresponding to 22.30 ppm and 0.93 for the Sarki section. The normalized patterns for the carbonate rocks exhibit: (1) non-seawater-like REE patterns, (2) positive Gd anomalies (average = 1.112 for Sararu and 1.114 for Sarki), (3) super chondritic Y/Ho ratio is 31.48 for Sararu and 31.73 for Sarki which are less than the value of seawater. The presence of sparry calcite cement, negative $^{13}C$ and $^{18}O$ isotope values, the positive Eu anomaly in the REE patterns (particularly for Sararu), eliminated Ce anomaly ($Ce/Ce^{\ast}$: 0.916-1.167, average = 0.994 and 0.950-1.010, average = 0.964, respectively), and Er/Nd values propose that these carbonates have undergone meteoric diagenesis. The REE patterns suggest that the terrigenous materials of the Baluti were derived from felsic to intermediate rocks.

Properties of Matrix According to the Replacement Ratio of Portland Cement-based Carbonation Sluge (시멘트 기반 탄화슬러지 치환율에 따른 경화체의 특성)

  • Kang, Yong-Mo;Lee, Hye-Eun;Lee, Sang Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.189-190
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    • 2021
  • Recently, the spread of intense social distancing and untact culture due to COVID-19 has increased the time spent indoors. In addition, according to the International Cancer Institute, fine dust was classified as a first-class carcinogen, a substance found to be carcinogenic, such as asbestos and benzene. As a result, interest in indoor air quality is increasing, and many studies are underway to reduce air pollutants. This study is a basic experiment of a board made to improve indoor air quality. The basic characteristics of the board, flexural strength and compressive strength, are analyzed and the results of the test are as follows. Experiments have shown that flexural strength and compressive strength tend to decrease as the replacement rate of hydrocarbons increases. It is believed that the strength of the sludge has decreased due to the increase in internal voids due to the increase in non-surface area, volume and diameter of microfiber as it undergoes the carbonation process. In addition, it is believed that the amount of moisture needed for curing during the mixing process was reduced due to the absorption of hydrocarbons.

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Properties of Non-cement Artificial Stone Utilizing the Waste Porcelain and Waste Glass (폐유리 및 폐자기를 활용한 무시멘트계 인조석재의 특성)

  • Kim, Tae-Hyun;Lee, Seung-Ho;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.2
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    • pp.136-142
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    • 2016
  • As the rapid industrialization and modernization progress of the world it is becoming a fast-paced environment pollution. And, dust or environment pollution to solve reckless diggings of natural aggregate cause a serious problem. This study was used a Blast Furnace Slag and Combined Heat and Power Plant of Fly Ash as a cement substitute to reduce $CO_2$ emissions during cement production, this study intend to suggest it's result as basic data 'Properties of Artificial Stone interior or exterior materials type utilizing industrial by-product and waste resource' utilizing Waste Porcelain and Waste Glass. As a result, it was high strength that matrix added the Combined Heat and Power Plant of Fly Ash of addition ratio 40%. Also, pre-experiment was conduct as mixing ratio of waste glass, waste porcelain on the basis of the preceding experiment, proper mixing ratio was judged that proper of waste glass, waste porcelain was mixing ratio 60, 70 (%) of appeared surface aggregate ratio more than 45%.

Effects of water on rock fracture properties: Studies of mode I fracture toughness, crack propagation velocity, and consumed energy in calcite-cemented sandstone

  • Maruvanchery, Varun;Kim, Eunhye
    • Geomechanics and Engineering
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    • v.17 no.1
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    • pp.57-67
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    • 2019
  • Water-induced strength reduction is one of the most critical causes for rock deformation and failure. Understanding the effects of water on the strength, toughness and deformability of rocks are of a great importance in rock fracture mechanics and design of structures in rock. However, only a few studies have been conducted to understand the effects of water on fracture properties such as fracture toughness, crack propagation velocity, consumed energy, and microstructural damage. Thus, in this study, we focused on the understanding of how microscale damages induced by water saturation affect mesoscale mechanical and fracture properties compared with oven dried specimens along three notch orientations-divider, arrester, and short transverse. The mechanical properties of calcite-cemented sandstone were examined using standard uniaxial compressive strength (UCS) and Brazilian tensile strength (BTS) tests. In addition, fracture properties such as fracture toughness, consumed energy and crack propagation velocity were examined with cracked chevron notched Brazilian disk (CCNBD) tests. Digital Image Correlation (DIC), a non-contact optical measurement technique, was used for both strain and crack propagation velocity measurements along the bedding plane orientations. Finally, environmental scanning electron microscope (ESEM) was employed to investigate the microstructural damages produced in calcite-cemented sandstone specimens before and after CCNBD tests. As results, both mechanical and fracture properties reduced significantly when specimens were saturated. The effects of water on fracture properties (fracture toughness and consumed energy) were predominant in divider specimens when compared with arrester and short transverse specimens. Whereas crack propagation velocity was faster in short transverse and slower in arrester, and intermediate in divider specimens. Based on ESEM data, water in the calcite-cemented sandstone induced microstructural damages (microcracks and voids) and increased the strength disparity between cement/matrix and rock forming mineral grains, which in turn reduced the crack propagation resistance of the rock, leading to lower both consumed energy and fracture toughness ($K_{IC}$).