• 제목/요약/키워드: Non-Cement Matrix

검색결과 44건 처리시간 0.025초

폴리실리콘 슬러지와 제지애시를 활용한 무시멘트 경화체의 알칼리자극제 종류 및 혼입율에 따른 강도특성 (Strength properties according to mixing type and ratio Alkali activator of Non-cement matrix using Paper Ash and Polysilicon sludge)

  • 신진현;김태현;김헌태;이동훈;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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    • pp.173-174
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    • 2017
  • Recently, many experiments using industrial by-products have been going on in Korea and abroad. Most of the studies on blast furnace slag and fly ash have been conducted, and the blast furnace slag based two and three component experiments have been conducted in many places. Therefore, this study is an additional study of research using polysilicon sludge and paper ash, which is a study using existing industrial by-products based on blast furnace slag, as strength properties of alkali activator according to kind and mixing ratio and to obtain basic data do.

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Solidification/Stabilization of Dyeing Sludge Treated by Fenton Reagent Using Blast Furnace Slag and Fly Ash

  • Lee, Sookoo;Kim, Sebum
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.453-458
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    • 2001
  • This study was performed to reuse the dyeing wastewater sludge treated by Fenton process through the solidification/stabilization technique. To solidify the dyeing sludge the industrial by-products such as blast furnace slag, fly ash and waste sand with cement were used. The laboratory scale and pilot scale test were conducted at room temperature to make construction brick which has high compressive strength and low leaching of heavy metals. The experimental results showed that blast furnace slag and fly ash could be used instead of cement and the products satisfied the regulation of Korean Standards. The blast furnace slag increased the compressive strength and the optimum ratio of slag/dyeing sludge on dry basis was found 0.4. The solidifying agent of SB series could increase rapidly the compressive strength and the optimum ratio of solidifying agent/sludge on dry basis was 0.26 at which the strength was two times compared with non-added condition. The portion of waste and industrial by-products in matrix was over 80%. From the pilot test the optimum pressure in molding was 100kg/$\textrm{cm}^2$ at which the compressive strength was over 100kg/$\textrm{cm}^2$. And the strength increased continuously to 160kg/$\textrm{cm}^2$ until 120 days curing time due to pozzolanic reaction. When SB-20 as a solidifying agent was used, the unconfined compressive strength of dyeing sludge could be obtained 110kg/$\textrm{cm}^2$ which satisfied the regulation of cement brick in Korea Standard(KS).

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Multiple Cracking Model of Fiber Reinforced High Performance Cementitious Composites under Uniaxial Tension

  • Wu, Xiangguo;Han, Sang-Mook
    • International Journal of Concrete Structures and Materials
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    • 제3권1호
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    • pp.71-77
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    • 2009
  • A theoretical model of multiple cracking failure mechanism is proposed herein for fiber reinforced high performance Cementitious composites. By introducing partial debonding energy dissipation on non-first cracking plane and fiber reinforcing parameter, the failure mechanism model of multiple cracking is established based on the equilibrium assumption of total energy dissipation on the first crack plane and non-first cracking plane. Based on the assumption of the first crack to be the final failure crack, energy dissipation terms including complete debonding energy, partial debonding energy, strain energy of steel fiber, frictional energy, and matrix fracture energy have been modified and simplified. By comparing multiple cracking number and energy dissipations with experiment results of the reference's data, it indicates that this model can describe the multiple cracking behavior of fiber reinforced high performance cementitious composites and the influence of the partial debonding term on energy dissipation is significant. The model proposed may lay a foundation for the predictions of the first cracking capacity and post cracking capacity of fiber reinforced high performance cementitious composites and also can be a reference for optimal mixture for construction cost.

콘크리트의 황산 및 황산염 침투 저항성에 미치는 광물질 혼화재의 영향 (Influence of Mineral Admixtures on the Resistance to Sulfuric Acid and Sulfate Attack in Concrete)

  • 배수호;박재임;이광명
    • 콘크리트학회논문집
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    • 제22권2호
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    • pp.219-228
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    • 2010
  • 하수도, 오 폐수, 토양 속, 지하수 및 해수 등의 환경에 건설되는 콘크리트 구조물은 산 및 황산염에 노출되어 있다. 이 같은 산 및 황산염 침투로 포틀랜드 시멘트 중의 수화생성물과 산 및 황산염 이온이 반응하여 팽창 수화물을 생성함으로써 콘크리트에 팽창 및 균열을 발생시켜, 결국 콘크리트 매트릭스에 손상을 일으킨다. 따라서 이 연구의 목적은 콘크리트의 황산 및 황산염 침투 저항성에 미치는 광물질 혼화재의 영향을 평가하여, 황산 및 황산염 침투에 대한 고저항성 콘크리트를 제시하는 것이다. 이를 위하여 광물질 혼화재의 형태 및 비율을 변화시킨 OPC, 2성분계 및 3성분계의 3가지 종류의 시멘트를 사용하여 물-결합재비 32% 및 43%인 콘크리트를 제조하였다. 제작된 콘크리트 시편은 민물, 5% 황산, 10% 황산나트륨 및 10% 황산마그네슘 용액에 재령 28, 56, 91, 182 및 365일 동안 각각 침지시켰다. 콘크리트의 황산 및 황산염 침투 저항성을 평가하기 위하여 외관변화 관찰과 압축강도 비 및 질량 변화율을 측정하였다. 그 결과, 광물질 혼화재를 혼입한 콘크리트의 황산 및 황산나트륨 침투에 대한 저항성은 OPC 콘크리트 경우 보다 훨씬 우수한 것으로 나타났으나, 황산마그네슘의 경우 비결합재질의 규산마그네슘수화물(M-S-H)의 형성으로 광물질 혼화재를 혼입한 콘크리트가 OPC 콘크리트보다 불리한 것으로 나타났다.

알파반수석고를 활용한 비소성결합재 기반 바닥 모르타르의 경화특성 및 건조수축 평가 (Evaluation of Hardening Properties and Dry Shrinkage of Non-Sintered Binder Based Floor Mortar Utilizing Alpha-Hemihydrate Gypsum)

  • 이계혁;김규용;이보경;김래환;신경수
    • 한국건축시공학회지
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    • 제15권4호
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    • pp.359-365
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    • 2015
  • 본 연구에서는 바닥 모르타르에 발생하는 균열을 방지하기 위해, 팽창성이 있는 재료인 알파반수석고를 활용한 비소성결합재 기반 바닥 모르타르의 경화특성 및 건조수축 특성을 평가하고, 건설현장에 적용하여 외기환경에 노출된 조건에서 바닥 모르타르의 수축변형 거동 및 균열 발생여부를 검토하였다. 그 결과, 슬래그계 바닥 모르타르의 경우 시멘트계 모르타르에 비해 초결 및 종결시간이 급격히 단축되었고 압축강도는 관련기준을 만족하는 것으로 확인되었으며, 초기에 팽창 변형 이후의 수축변형 거동은 시멘트계 모르타르와 유사한 경향을 나타내었다. 슬래그계 바닥 모르타르의 현장 적용 결과 균열이 발생하지 않았으며, 외기환경 조건에 의한 변형률의 차이가 크지 않아 시멘트계 바닥 모르타르에 비해 치수안정성이 큰 것으로 판단된다.

Nano-engineered concrete using recycled aggregates and nano-silica: Taguchi approach

  • Prusty, Rajeswari;Mukharjee, Bibhuti B.;Barai, Sudhirkumar V.
    • Advances in concrete construction
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    • 제3권4호
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    • pp.253-268
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    • 2015
  • This paper investigates the influence of various mix design parameters on the characteristics of concrete containing recycled coarse aggregates and Nano-Silica using Taguchi method. The present study adopts Water-cement ratio, Recycled Coarse Aggregate (%), Maximum cement content and Nano-Silica (%) as factors with each one having three different levels. Using the above mentioned control parameters with levels an Orthogonal Array (OA) matrix experiments of L9 (34) has selected and nine number of concrete mixes has been prepared. Compressive Strength, Split Tensile Strength, Flexural Tensile Strength, Modulus of Elasticity and Non-Destructive parameters are selected as responses. Experimental results are analyzed and the optimum level for each response is predicted. Analysis of 28 days CS depicts that NS (%) is the most significant factor among all factors. Analysis of the tensile strength results indicates that the effect of control factor W/C ratio is ranked one and then NS (%) is ranked two which suggests that W/C ratio and NS (%) have more influence as compared to other two factors. However, the factor that affects the modulus of elasticity most is found to be RCA (%). Finally, validation experiments have been carried out with the optimal mixture of concrete with Nano-Silica for the desired engineering properties of recycled aggregate concrete. Moreover, the comparative study of the predicted and experimental results concludes that errors between both experimental and predicted values are within the permissible limits. This present study highlights the application of Taguchi method as an efficient tool in determining the effects of constituent materials in mix proportioning of concrete.

Stable isotope and rare earth element geochemistry of the Baluti carbonates (Upper Triassic), Northern Iraq

  • Tobia, Faraj Habeeb
    • Geosciences Journal
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    • 제22권6호
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    • pp.975-987
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    • 2018
  • Stable isotope ratios of $^{18}O/^{16}O$ and $^{13}C/^{12}C$ and rare earth elements geochemistry of the Upper Triassic carbonates from the Baluti Formation in Kurdistan Region of Northern Iraq were studied in two areas, Sararu and Sarki. The aim of the study is to quantify the possible diagenetic processes that postdated deposition and the paleoenvironment of the Baluti Formation. The replacement products of the skeletal grains by selective dissolution and neomorphism probably by meteoric water preserved the original marine isotopic signatures possibly due to the closed system. The petrographic study revealed the existence of foraminifers, echinoderms, gastropods, crinoids, nodosaria and ostracods as major framework constituents. The carbonates have micritic matrix with microsparite and sparry calcite filling the pores and voids. The range and average values for twelve carbonate rocks of ${\delta}^{18}O$ and ${\delta}^{13}C$ in Sararu section were -5.3‰ to -3.16‰ (-4.12‰) and -2.94‰ to -0.96‰ (-1.75‰), respectively; while the corresponding values for the Sarki section were -3.69‰ to -0.39‰ (-2.08‰) and -5.34‰ to -2.70‰ (-4.02‰), respectively. The bivariate plot of ${\delta}^{18}O$ and ${\delta}^{13}C$ suggests that most of these carbonates are warm-water skeletons and have meteoric cement. The average ${\Sigma}REE$ content and Eu-anomaly of the carbonates of Sararu sections were 44.26 ppm and 1.03, respectively, corresponding to 22.30 ppm and 0.93 for the Sarki section. The normalized patterns for the carbonate rocks exhibit: (1) non-seawater-like REE patterns, (2) positive Gd anomalies (average = 1.112 for Sararu and 1.114 for Sarki), (3) super chondritic Y/Ho ratio is 31.48 for Sararu and 31.73 for Sarki which are less than the value of seawater. The presence of sparry calcite cement, negative $^{13}C$ and $^{18}O$ isotope values, the positive Eu anomaly in the REE patterns (particularly for Sararu), eliminated Ce anomaly ($Ce/Ce^{\ast}$: 0.916-1.167, average = 0.994 and 0.950-1.010, average = 0.964, respectively), and Er/Nd values propose that these carbonates have undergone meteoric diagenesis. The REE patterns suggest that the terrigenous materials of the Baluti were derived from felsic to intermediate rocks.

시멘트 기반 탄화슬러지 치환율에 따른 경화체의 특성 (Properties of Matrix According to the Replacement Ratio of Portland Cement-based Carbonation Sluge)

  • 강용모;이혜은;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 봄 학술논문 발표대회
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    • pp.189-190
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    • 2021
  • Recently, the spread of intense social distancing and untact culture due to COVID-19 has increased the time spent indoors. In addition, according to the International Cancer Institute, fine dust was classified as a first-class carcinogen, a substance found to be carcinogenic, such as asbestos and benzene. As a result, interest in indoor air quality is increasing, and many studies are underway to reduce air pollutants. This study is a basic experiment of a board made to improve indoor air quality. The basic characteristics of the board, flexural strength and compressive strength, are analyzed and the results of the test are as follows. Experiments have shown that flexural strength and compressive strength tend to decrease as the replacement rate of hydrocarbons increases. It is believed that the strength of the sludge has decreased due to the increase in internal voids due to the increase in non-surface area, volume and diameter of microfiber as it undergoes the carbonation process. In addition, it is believed that the amount of moisture needed for curing during the mixing process was reduced due to the absorption of hydrocarbons.

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폐유리 및 폐자기를 활용한 무시멘트계 인조석재의 특성 (Properties of Non-cement Artificial Stone Utilizing the Waste Porcelain and Waste Glass)

  • 김태현;이승호;이상수;송하영
    • 한국건설순환자원학회논문집
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    • 제4권2호
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    • pp.136-142
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    • 2016
  • 전 세계적으로 급격한 산업화 및 현대화가 진행됨에 따라 환경오염 또한 급격히 진행되어가고 있다. 그리고 천연골재의 무분별한 채취로 환경오염 및 분진발생 등은 심각한 문제가 되고 있다. 이에 본 연구는 시멘트 생산 시 $CO_2$ 배출량을 줄이고자 시멘트 대체재로서 산업부산물인 고로슬래그와 유동층 연소 플라이애시를 사용하고자 하였으며, 천연골재의 무분별한 채취 문제를 해결하고자 골재로서 폐자기 및 폐유리를 활용하는 인조석재에 적용하는 산업부산물 및 폐자원을 활용한 내 외장재 인조석재의 특성에 대한 기초자료를 제시하고자 하였다. 그 결과, 고로슬래그를 주 결합재로 하여 유동층 연소 플라이애시를 40% 첨가하였을 때 가장 강도가 높았으며 또한, 선행실험을 토대로 폐자기 및 폐유리의 혼입율에 따른 실험을 진행 한 결과, 폐자기 및 폐유리의 적정 혼입율은 출석률이 45% 이상 보이는 혼입율 60, 70(%)의 혼입율이 가장 적정 혼입율이라고 판단된다.

Effects of water on rock fracture properties: Studies of mode I fracture toughness, crack propagation velocity, and consumed energy in calcite-cemented sandstone

  • Maruvanchery, Varun;Kim, Eunhye
    • Geomechanics and Engineering
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    • 제17권1호
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    • pp.57-67
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    • 2019
  • Water-induced strength reduction is one of the most critical causes for rock deformation and failure. Understanding the effects of water on the strength, toughness and deformability of rocks are of a great importance in rock fracture mechanics and design of structures in rock. However, only a few studies have been conducted to understand the effects of water on fracture properties such as fracture toughness, crack propagation velocity, consumed energy, and microstructural damage. Thus, in this study, we focused on the understanding of how microscale damages induced by water saturation affect mesoscale mechanical and fracture properties compared with oven dried specimens along three notch orientations-divider, arrester, and short transverse. The mechanical properties of calcite-cemented sandstone were examined using standard uniaxial compressive strength (UCS) and Brazilian tensile strength (BTS) tests. In addition, fracture properties such as fracture toughness, consumed energy and crack propagation velocity were examined with cracked chevron notched Brazilian disk (CCNBD) tests. Digital Image Correlation (DIC), a non-contact optical measurement technique, was used for both strain and crack propagation velocity measurements along the bedding plane orientations. Finally, environmental scanning electron microscope (ESEM) was employed to investigate the microstructural damages produced in calcite-cemented sandstone specimens before and after CCNBD tests. As results, both mechanical and fracture properties reduced significantly when specimens were saturated. The effects of water on fracture properties (fracture toughness and consumed energy) were predominant in divider specimens when compared with arrester and short transverse specimens. Whereas crack propagation velocity was faster in short transverse and slower in arrester, and intermediate in divider specimens. Based on ESEM data, water in the calcite-cemented sandstone induced microstructural damages (microcracks and voids) and increased the strength disparity between cement/matrix and rock forming mineral grains, which in turn reduced the crack propagation resistance of the rock, leading to lower both consumed energy and fracture toughness ($K_{IC}$).