• Title/Summary/Keyword: Nitrous Oxide

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A Comparative Study of Gate Oxides Grown in $10%-N_2O$ and in Dry Oxygen on N-type 4H SiC

  • Cheong, Kuan-Yew;Bahng, Wook;Kim, Nam-Kyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.17-19
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    • 2004
  • The electrical properties of gate oxides grown in two different processes, which are in 10% nitrous oxide($N_2O$) and in dry oxygen, have been experimentally investigated and compared. It has been observed that the $SiC-SiO_2$ interface-trap density(Dit) measured in nitrided gate oxide has been tremendously reduced, compared to the density obtained from gate oxide grown in dry oxygen. The beneficial effects of nitridation on gate oxides also have been demonstrated in the values of total near interface-trap density and of forward-bias breakdown field. The reasons of these improvements have been explained.

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The Relevance of Soil N2O Emissions Measured by a Closed Chamber Technique on the Physico-chemical Soil Parameters (Closed chamber를 이용한 토양 N2O 배출량과 주요 토양 인자들과의 상관성)

  • Kim Deug-Soo;Oh Jin Man
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.749-758
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    • 2004
  • Nitrous oxide ($N_2$O) has been known as an important trace gas due to the greenhouse gas and the major source of stratospheric oxide of nitrogen (NO). Soil is the major source of $N_2$O in nature. The physicochemical characteristics of soils affect the emission of $N_2$O from soil. These physicochemical parameters are soil moisture, soil temperature, and soil N content. Since these parameters are correlated to the flux of $N_2$O from soil individually and compositely, there still remain many unknowns in the mechanism to produce $N_2$O in soil and the roles of such physicochemical parameters which affect the soil $N_2$O emission. Soil $N_2$O fluxes were measured at different levels in water filled pore space (WFPS), soil temperature and soil N contents from the same amounts of soils which were sampled from agriculturally managed upland field in a depth of ~30 cm at Kunsan. The soil $N_2$O flux measurements were conducted in a laboratory with a closed flux chamber system. The optimum soil moisture and soil temperature were observed at 60% of WFPS and ~13$^{\circ}C$. The soil $N_2$O flux increased as soil N contents increases during the whole experimental hours (up to 48 hours). However, average $N_2$O flux decreased after ~30 hours when organic carbon was mixed with nitrogen in the sample soils. It is suggested that organic carbon could be important for the emission of $N_2$O, and that the ratio of N to C needs to be identified in the process of $N_2$O soil emission.

The Effect of Intracuff Pressure Adjustment on Postoperative Sore Throat and Hoarseness after Nitrous Oxide and Air Anesthesia (아산화질소(N2O)와 공기(Air)를 사용한 마취 수술의 기낭압 조정이 수술 후 인후통과 쉰목소리에 미치는 영향)

  • Gu, An Na;Yu, Mi
    • Journal of Korean Academy of Nursing
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    • v.49 no.2
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    • pp.215-224
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    • 2019
  • Purpose: To investigate the differences in postoperative sore throat and hoarseness by adjustment of endotracheal tube cuff pressure (CP) during nitrous oxide ($N_2O$) and air anesthesia. Methods: A one-equivalent control group pretest-posttest design was used. Data were collected from August 8 to October 19, 2017 and analyzed using the independent t-test and repeated measures ANOVA. Eighty-four participants were enrolled and divided into three groups: 28 in the Control Group (CP adjusted every 30 minutes using $N_2O$), 28 in Experimental Group 1 (CP adjusted every 10 minutes using $N_2O$), and 28 in Experimental Group 2 (non-adjusted CP using air), all of whom underwent urologic, gynecologic, and orthopedic surgeries at the G University hospital. Sore throat was assessed using a numeric rating scale; hoarseness was evaluate using the Stout classification at 1, 6, and 24 hours after surgery. Results: Scores for sore throat and hoarseness were significantly different between the groups at each measurement time, and scores were consistently higher in the control group. During subsequent measurements, sore throat and hoarseness scores were significantly lower at 6 hours. Cuff pressure changed significantly using air anesthesia (${\chi}^2=10.41$, p=.015) up to 2 hours after induction. Severe sore throat and hoarseness was observed for up to 6 hours after surgery. Conclusion: Cuff pressure adjustment at short time intervals would be helpful in reducing postoperative sore throat and hoarseness. Nursing intervention focused on prevention of sore throat and hoarseness should be required up to 6 hours postoperatively in patients undergoing endotracheal intubation.

Effects of Ceria and CO Reductant on $N_2O$ Decomposition over the Layered Mixed Oxide Catalysts (층상 혼합금속산화물 촉매에 의한 $N_2O$ 분해에서 Ceria 첨가 및 CO 환원제의 영향)

  • Yang, Ki-Seon;Chang, Kil-Sang
    • Clean Technology
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    • v.16 no.4
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    • pp.284-291
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    • 2010
  • Nitrous oxide ($N_2O$) is a greenhouse material which is hard to remove. Even with a catalytic process it requires a reaction temperature, at least, higher than 670 K. This study has been performed to see the effects of Ce addition to the mixed oxide catalyst which shows the highest activity in decomposing $N_2O$ completely at temperature as low as 473 K when CO is used as a reducing agent. Mixed metal oxide(MMO) catalyst was made through co-precipitation process with small amount of Ce added to the base components of Co, Al and Rh or Pd. Consequently, the surface area of the catalyst decreased with the contents of Ce, and the catalytic activity of direct decomposition of $N_2O$ also decreased. However, in the presence of CO, the activity was found high enough to compensate the portion of activity decrease by Ce addition, so that it can be ascertained that the catalytic activity and stability can be maintained in the CO involved $N_2O$ reduction system when Ce is added for the physical stability of the catalyst.

Trends and Projected Estimates of GHG Emissions from Indian Livestock in Comparisons with GHG Emissions from World and Developing Countries

  • Patra, Amlan Kumar
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.4
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    • pp.592-599
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    • 2014
  • This study presents trends and projected estimates of methane and nitrous oxide emissions from livestock of India vis-$\grave{a}$-vis world and developing countries over the period 1961 to 2010 estimated based on IPCC guidelines. World enteric methane emission (EME) increased by 54.3% (61.5 to $94.9{\times}10^9kg$ annually) from the year 1961 to 2010, and the highest annual growth rate (AGR) was noted for goat (2.0%), followed by buffalo (1.57%) and swine (1.53%). Global EME is projected to increase to $120{\times}10^9kg$ by 2050. The percentage increase in EME by Indian livestock was greater than world livestock (70.6% vs 54.3%) between the years 1961 to 2010, and AGR was highest for goat (1.91%), followed by buffalo (1.55%), swine (1.28%), sheep (1.25%) and cattle (0.70%). In India, total EME was projected to grow by $18.8{\times}10^9kg$ in 2050. Global methane emission from manure (MEM) increased from $6.81{\times}10^9kg$ in 1961 to $11.4{\times}10^9kg$ in 2010 (an increase of 67.6%), and is projected to grow to $15{\times}10^9kg$ by 2050. In India, the annual MEM increased from $0.52{\times}10^9kg$ to $1.1{\times}10^9kg$ (with an AGR of 1.57%) in this period, which could increase to $1.54{\times}10^9kg$ in 2050. Nitrous oxide emission from manure in India could be $21.4{\times}10^6kg$ in 2050 from $15.3{\times}10^6kg$ in 2010. The AGR of global GHG emissions changed a small extent (only 0.11%) from developed countries, but increased drastically (1.23%) for developing countries between the periods of 1961 to 2010. Major contributions to world GHG came from cattle (79.3%), swine (9.57%) and sheep (7.40%), and for developing countries from cattle (68.3%), buffalo (13.7%) and goat (5.4%). The increase of GHG emissions by Indian livestock was less (74% vs 82% over the period of 1961 to 2010) than the developing countries. With this trend, world GHG emissions could reach $3,520{\times}10^9kg$ $CO_2$-eq by 2050 due to animal population growth driven by increased demands for meat and dairy products in the world.

Studies on the Denitrification in the Submerged Paddy Soil -1. The Denitrification Rates Upon the Different Levels of Nitrogen Fertilizer in Sandy Soil (논토양(土壤)의 탈질작용(脫窒作用)에 관(關)한 연구(硏究) -제(第) 1 보(報). 사질답토양(砂質畓土壤)에서 질소시비량(窒素施肥量) 차이(差異)가 탈질(脫窒)에 미치는 영향(影響))

  • Lee, Sang Kyu;Kim, Seung Hwan;Park, Jun Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.1
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    • pp.94-98
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    • 1985
  • A laboratory experiment was conducted to find out the denitrification rate upon the different levels of nitrogen fertilizer in submerged sandy soil. The results obtained were summarized as follows: 1. The highest denitrification rate was observed at 25 days after incubation. The amount was reached at 1830 ug/100g soil for 20mg nitrogen was applied in 100g soil. 2. Increases of fertilizer nitrogen was enhanced the rate of ammonification and nitrification during the incubation time. 3. Deep correlation was observed between the denitrification capacities which was determined as nitrous oxide and Mitchaelis-Menten kinetic with relation to nitrate concentration. More higher denitrification rates were observed in Mitchaelis-Menten kinetic than dentrification rate with determined as nitrous oxide. 4. A Zero order (with relation to nitrate concentration) kinetic model for denitrification was presented in this experiment condition to illustrate the variability of nitrous oxide concentrations in the submerged soil atmosphere.

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Methane and Nitrous Oxide Emissions from Livestock Agriculture in 16 Local Administrative Districts of Korea

  • Ji, Eun-Sook;Park, Kyu-Hyun
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.12
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    • pp.1768-1774
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    • 2012
  • This study was conducted to evaluate methane ($CH_4$) and nitrous oxide ($N_2O$) emissions from livestock agriculture in 16 local administrative districts of Korea from 1990 to 2030. National Inventory Report used 3 yr averaged livestock population but this study used 1 yr livestock population to find yearly emission fluctuations. Extrapolation of the livestock population from 1990 to 2009 was used to forecast future livestock population from 2010 to 2030. Past (yr 1990 to 2009) and forecasted (yr 2010 to 2030) averaged enteric $CH_4$ emissions and $CH_4$ and $N_2O$ emissions from manure treatment were estimated. In the section of enteric fermentation, forecasted average $CH_4$ emissions from 16 local administrative districts were estimated to increase by 4%-114% compared to that of the past except for Daejeon (-63%), Seoul (-36%) and Gyeonggi (-7%). As for manure treatment, forecasted average $CH_4$ emissions from the 16 local administrative districts were estimated to increase by 3%-124% compared to past average except for Daejeon (-77%), Busan (-60%), Gwangju (-48%) and Seoul (-8%). For manure treatment, forecasted average $N_2O$ emissions from the 16 local administrative districts were estimated to increase by 10%-153% compared to past average $CH_4$ emissions except for Daejeon (-60%), Seoul (-4.0%), and Gwangju (-0.2%). With the carbon dioxide equivalent emissions ($CO_2$-Eq), forecasted average $CO_2$-Eq from the 16 local administrative districts were estimated to increase by 31%-120% compared to past average $CH_4$ emissions except Daejeon (-65%), Seoul (-24%), Busan (-18%), Gwangju (-8%) and Gyeonggi (-1%). The decreased $CO_2$-Eq from 5 local administrative districts was only 34 kt, which was insignificantly small compared to increase of 2,809 kt from other 11 local administrative districts. Annual growth rates of enteric $CH_4$ emissions, $CH_4$ and $N_2O$ emissions from manure management in Korea from 1990 to 2009 were 1.7%, 2.6%, and 3.2%, respectively. The annual growth rate of total $CO_2$-Eq was 2.2%. Efforts by the local administrative offices to improve the accuracy of activity data are essential to improve GHG inventories. Direct measurements of GHG emissions from enteric fermentation and manure treatment systems will further enhance the accuracy of the GHG data.

Status and Trends of Emission Reduction Technologies and CDM Projects of Greenhouse Gas Nitrous Oxide (온실가스 아산화질소(N2O) 저감기술 및 CDM 사업의 현황과 전망)

  • Chang, Kil Sang
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.17-26
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    • 2008
  • With the effectuation of Kyoto Protocol on the United Nations Framework Convention on the Climate Change, the emission reduction of greenhouse gases became an urgent issue and has been competitively secured among countries as the form of certificates through clean development mechanism (CDM) or joint implementation (JI). Nitrous oxide ($N_2O$) is one of the major greenhouse gases along with carbon dioxide ($CO_2$) and methane ($CH_4$) having warming potential 310 times that of carbon dioxide and chemically very stable in the atmosphere to give a life time of more than 120 years so that it reaches to the stratosphere to act as an ozone depleting substance. $N_2O$ hardly decomposes and thus, besides to the adoption of thermal decomposition at high temperature, selective catalytic reduction methods are usually used at temperatures over $400^{\circ}C$ in which the presence of NOx acts as a major impeding material in the decomposition process. In this article, the sources of various $N_2O$ generation, catalytic reduction processes and the status and trends of emission trade with CDM projects for greenhouse gas reduction are summarized and discussed on a condensed basis.

Effect of Green Manure Crop and Biochar on Nitrous Oxide Emission from Red Pepper Field (녹비작물과 바이오숯의 고추 재배지 아산화질소 배출량 저감 효과)

  • Seo, Young-Ho;Kim, Se-Won;Choi, Seung-Chul;Kim, In-Jong;Kim, Kyung-Hi;Kim, Gun-Yeob
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.540-543
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    • 2012
  • Atmospheric nitrous oxide ($N_2O$) level has been increasing at a rate of 0.2~0.3% per year. The rise in $N_2O$ concentration in atmosphere was mainly due to an increased application of nitrogen fertilizers. The objective of the study was to assess the effect of green manure crop and biochar on $N_2O$ emissions from upland crop field. The green manure crop used in the study was hairy vetch and the cultivated crop was red pepper (Capsicum annuum L.). Nitrogen was applied at a rate of $190kg\;ha^{-1}$, standard N fertilization rate for red pepper. Emissions of $N_2O$ from the field were reduced from the plots applied with hairy vetch and biochar by 46.5% and 24.6%, respectively, compared with nitrogen fertilizer treated plots with $N_2O$ emission of $1.14kg\;N_2O-N\;ha^{-1}$. The results from the study imply that green manure crop and biochar can be utilized to reduce greenhouse gas emission from the upland crop field.

Assessment on Nitrous Oxide (N2O) Emissions different Nitrogen Application Rates during the Red Pepper Cultivation in Flat Upland

  • Lee, Jong-Eun;Yun, Yeo-Uk;Lee, Jin-Il;Nam, Yun-Gyu;Kim, Gun-Yeob;Kim, Sun-Ju
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.1
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    • pp.59-65
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    • 2014
  • Generally, nitrogen (N) fertilization higher than the recommended dose is applied during vegetable cultivation for increasing in productivity. However, excessive N application rate beyond plant requirement could cause adverse environmental impact such as nitrate leaching and nitrous oxide emission. In this experiment, the impacts of N fertilization was studied on nitrous oxide ($N_2O$) emission to standardize the optimum fertilization level for minimizing of $N_2O$ emission as well as most of the crop productivity. Herein, we assessed the $N_2O$ emission in the flat upland soil which was cultivated with different N application rates on red pepper for 3 years (2010~2012). $N_2O$ emission was measured in chemical N fertilizer amounts 0 (N 0), 95 (N 0.5), 190 (N 1.0), $380(N_2.0)kgha^{-1}$ by using the abnormal shape chamber closed repeating three times. In average for 3 years, the total $N_2O$ emissions of each treatment in field of soybean were 2.110 (N 0), 3.165 (N 0.5), 5.039 (N 1.0), and $7.228(N_2.0)kgN_2Oha^{-1}yr^{-1}$, respectively. And then the primary regression between nitrogen fertilizer amount and the total $N_2O$ emission was showed as y = 0.0138x + 2.0942 ($r^2=0.9885$), and an average of the emission factor was $EF_1$ 0.0148(0.0118~0.0191) $N_2O-NkgN^{-1}kg^{-1}$ from 2010 to 2012. The result was a little higher than the emission default of the IPCC 1996 Guideline ($EF_1$ 0.0125) when the results are converted into $N_2O$ emission factor.