• Title/Summary/Keyword: Nitrogen monoxide

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The Origin of Diamonds (I). Experimental Data

  • R. LEverett angford
    • Journal of the Korean Chemical Society
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    • v.22 no.2
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    • pp.95-98
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    • 1978
  • Using gases trapped within natural diamonds as defected by crushing in the sample system of a research mass spectrometer, a proposed gaseous environment for the formation of diamonds is presented. Diamonds crushed under a vacuum of $10^{-9}$torr at a temperature of $200^{\circ}C$ yielded in order of abundance, water, hydrogen, nitrogen, carbon dioxide, methane, carbon monoxide, argon, and ethanol.

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Slagging treatment of MSW incineration ash by plasma system (플라즈마를 이용한 도시 쓰레기 소각재 용융처리 기술)

  • 박현서;지규일;장준섭;전석구;배희주;김형진;이시창;주성준;신범수
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1999.10a
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    • pp.65-68
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    • 1999
  • A plasma melting system to vitrify ny ash from MSW(Municipal Solid Waste) incinerator has been operated in SHI(Samsung Heavy Industries) since 1996. Waste feeding rate was 200kg/hr. with maximum working power of 500㎾. Because of high melting temperature of fly ash, bottom ash was used as an additive to decrease melting temperature. Data analysis for discharged slag shows volume reduction up to 30% and no leaching of heavy metals such as Pb, Cd, Cr which were an obstacle for landfill and recycle. Atmospheric pollution gas like nitrogen oxides, carbon monoxide, and PCDD/PCDF were restrained below the regulatory limit.

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Stabilization of Zeolites Y For Separation by Gas Chromatography (GC분리에 의한 Zeolite Y 안정화)

  • Yim, Going;Heenan, Willian A.
    • The Journal of Natural Sciences
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    • v.8 no.1
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    • pp.41-45
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    • 1995
  • A. partially decationized Y zeolite was pretreated under specific conditions. It was found this calcinated zeolite retains its separation properties for mixtures of the gases hydrogen, nitrogen, oxygen, carbon monoxide, and methane but has much lower affinity for water molecules than untreated, e.g., zeolites A type or X type. The observed effect is discussed on the basis of the results of adsorption measurements on the adsorption capacities, isotherms, and heats of adsorption.

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The Evaluation on Smoke Reduction by Natural Gas Dual Fuel Engine for City Bus (매연저감을 위한 천연가스 Dual-Fuel 엔진의 시내버스 적용평가)

  • 엄명도;조강래;오용석;한영출
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.3
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    • pp.215-220
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    • 1997
  • CNG dual fuel engine for heavy duty diesel engine developed by AFS International in Canada has been equipped to a Korean city bus engine and tested to compare the engine performance and the emission characteristics with the existing diesel fueled engine. Also the dual-fuel engine was applied to the city bus for road test. The results are summarized as follows. Performance optimization has been carried out to have engine power equivalent to or better than the diesel fueled engine. Smoke is decreased by 85% by Korean smoke 3 mode test. By 13 mode test CO is increased by 453% and THC is increased by 2, 086%. NOx is decreased by 7% in laboratory. D-13 test mode was changed in 1996 Korean regulation. Even though THC is increased very much, it's not too serious problem since CO and HC emission of diesel engine is very little compared to gasoline engine and more than 75% of THC is CH$_4$. But the reduction technologies of CO and HC has to be considered.

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Microwave-enhanced gasification of sewage sludge waste

  • Chun, Young Nam;Song, Hee Gaen
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.591-599
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    • 2019
  • To convert sewage sludge to energy, drying-gasification characteristics during microwave heating were studied. During the gasification of carbon dioxide, the main products were gas, followed by char, and tar in terms of the amount. The main components of the producer gas were carbon monoxide and hydrogen including a small amount of methane and light hydrocarbons. They showed a sufficient heating value as a fuel. The generated tar is gravimetric tar, which is total tar. As light tars, benzene (light aromatic tar) was a major light tar. Naphthalene, anthracene, and pyrene (light polycyclic aromatic hydrocarbon tars) were also generated, but in relatively small amounts. Ammonia and hydrogen cyanide (precursor for NOx) were generated from thermal decomposition of tar containing protein and nitrogen in sewage sludge. In the case of sludge char, its average pore diameter was small, but specific area, pore volume, and adsorption amounts were relatively large, resulting in superior adsorption characteristics.

Combustion and Exhaust Emission Characteristics of Bio-Ethanol Fuel(E100) in SI Engine (SI 엔진에서 바이오에탄올 연료(E100)의 연소 및 배기특성)

  • Ha, Sung-Yong;Lee, Chang-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.8
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    • pp.582-588
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    • 2008
  • An experimental investigation was conducted to investigate the effect of Bio-ethanol fuel on the engine performance and exhaust emission characteristics under various engine operating conditions. To investigate the effect of bio-ethanol fuel, the commercial 1.6L SI engine equipped with 4 cylinder was tested on EC dynamometer. The engine performance including brake torque, brake specific fuel consumption, and barke specific energy consumption of bio-ethanol fuel was compared to those obtained by pure gasoline. Furthermore, the exhaust emissions were analyzed in terms of regulated exhaust emissions such as unburned hydrocarbon, oxides of nitrogen, and carbon monoxide.Result of this work shows that the effect of blending of ethanol to gasoline caused drastic decrease of emissions under various operating conditions. Also, improved engine performance such as brake torque and brake power were indicated for bio-ethanol fuel.

A Numerical Study on Flow around Exhaust Ducts of Flue Gas from Apartment Heating Boiler (공동주택 보일러 연소배기가스의 실내유입에 관한 수치적 연구)

  • 박외철;정락기
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.7
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    • pp.557-562
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    • 2003
  • Flue gas from apartment heating gas boiler is exhausted outside through an exhaust duct mounted horizontally in a vertical row on the wall. The flue gas includes nitrogen-oxides (NOx) and carbon monoxide. To investigate the possible entrainment of the flue gas into the apartments through the windows, a large eddy simulation (LES) based numerical method is utilized. Distribution of the velocity intensity and temperature around the exhaust ducts is presented for three numerical parameters: exhaust velocity, temperature of the flue gas, and exhaust duct length. The flow field visualized with particles inserted at the ends of the ducts is also presented. The results clearly show that the exhausted flue gas may flow into the apartments when the windows are open.

Effect of Copper on the Properties of ZSM-5 Catalyst Fabricated by Mechanical Alloying Method (기계적합금화법에 의해 제조된 ZSM-5촉매특성에 미치는 Cu의 영향)

  • 안인섭
    • Journal of Powder Materials
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    • v.3 no.3
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    • pp.153-158
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    • 1996
  • The exhaust gas from vehicle engines and industrial boilers contains considerable amount of harmful nitrogen monoxide(NO) which causes air pollusion and acid rain. To remove NO catalytic reduction processes using Cu ion exchanged ZSM-5 zeolite have been widely studied. In this study, an attempt was made to fabricate Cu/zeolite catalyst by using high energy ball mill. The catalytic performance of ball milled Cu/ZSM-5 zeolites is analyzed and optimum copper contents was determined. The processing variables were reaction temperature and copper contents. Complete removal of NO gas was obtained at the temperature of 553 K on 10wt.% CU/ZSM-5 mechanically alloyed composite powders. Mechanically alloyed CU/ZSM-5 catalyst showed homogeneous distribution of Cu in ZSM-5.

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Toxicological Study for Blood Cyanide and Carboxyhemoglobin Levels in the Fire- related Fatalities

  • Baeck, Seung-Kyung;Kim, Dong-Woo;Kim, Sun-Chun;Park, Woo-Yong;Jin, Kwang-Ho;Chung, Young-Ho;Park, Yun-Shin;Seo, Joong-Seok
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.170.2-170.2
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    • 2003
  • The most common cause of death in fires is the inhalation of noxious gases rather than thermal injury. Carbon monoxide is well-known toxic component in fire atmospheres. However, the importance of hydrogen cyanide(HCN) as a toxic agent in the fire related fatalities(FRF) is under discussion. HCN is known to be produced in fires involving by the pyrolysis of polyacrylonitril (PAN) and other nitrogen-containing polymer. (omitted)

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Nitric Oxide Production Inhibitory and Anti-Oxidative Activities of Phenolic Compounds from the Barks of Ulmus davidiana

  • Lee, Jae-Hee;Yeom, Seung-Hwan;Kim, Min-Kee;Kim, Hyun-Jung;Sim, Jae-Geul;Lee, Min-Won
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.196.2-196.2
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    • 2003
  • The Barks of Ulmus davidiana (Ulmaceae) have been used for the treatment of insecticide, anti-boil and anti-fungi in Korean traditional medicine. Four phenolic compounds were isolated from 80% Acetone extracts. The structures of these compounds were elucidated as (+)-catechin, (+)-catechin 7-O-${\beta}$-D-glucopyranoside, (+)-catechin 7-O-${\beta}$-D-xylopyranoside and procyanidin B-1. These phenolic compounds showed significant nitrogen monoxide(NO) production inhibitory activity in IFN-${\gamma}$, LPS stimulated RAW 264.7 cell and also showed significant antioxidative activity on DPPH radical. (omitted)

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