• Title/Summary/Keyword: Nitrogen dynamic

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Trial Manufacture and Disinfection Evaluation of Anoxic Chamber System for Museum Insects (저산소 농도 살충 챔버 시스템 시제작 및 박물관 해충 살충 성능 평가)

  • Oh, Joonsuk;Choi, Jungeun;Lee, Jangmook
    • Journal of Conservation Science
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    • v.28 no.4
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    • pp.377-385
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    • 2012
  • Anoxic treatments using argon and nitrogen gas in controlled atmospheres have been used as a alternative to methyl bromide for insect disinfection in museums. Anoxic chamber system was manufactured and installed at The National Folk Museum of Korea for the first time in Korea. The internal capacity of anoxic chamber is 0.5m3 in which is able to use argon, nitrogen and carbon dioxide gas. This system is equipped with oxygen concentration, temperature and ralative humidity control devices and automatically controlled oxygen concentration from 0.01 to 20%, temperature from 10 to $50^{\circ}C$ and relative humidity 30 to 80%. To control the oxygen concentration, anoxic chamber system is adopted semi-dynamic method which supplies mixture of humidified gas and dry gas whenever oxygen concentration in chamber becomes higher than setting value. It has kept regularly oxygen concentration, temperature and relative humidity for 20 days using argon gas. To evaluate the disinfection of cigarette beetle larvae and adults and varied carpet beetle larvae, the anoxic chamber system maintained 0.01% of oxygen concentration, $25^{\circ}C$ in temperature and 50% in relative humidity for 30 days. Cigarette beetle larvae were killed in 7 days and adults in 3~5 days. And varied carpet beetle larvae were killed in 3 days. It reaches the conclusion form the evaluation this anoxic chamber system can be used to develop anoxic treatment as an alternative of methyl bromide for insect disinfection of infested cultural properties in museums.

Removal of Nutrients from Domestic Wastewater Using Intermittently Aerated Activated Sludge Systems Supplemented with Fermented Settled Sludge (발효된 1차 침전슬러지를 공급하여 간헐폭기조를 이용한 도시하수의 영양염류 처리)

  • Weon, Seung-Yeon;Lee, Sang-Ill
    • Journal of Korean Society on Water Environment
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    • v.20 no.1
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    • pp.18-23
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    • 2004
  • In this research, a 2-stage intermittently aerated activated sludge system(IA) and intermittently aerated dynamic flow activated sludge system(DF) were investigated for the removal of nutrients in domestic wastewater. Wastewater was characterized by low C/N( organics/nitrogen) ratio. $COD_{cr}$, $BOD_s$, TKN and TP concentrations of domestic wastewater were 235, 47, 32 and 5.4 mg/L, respectively. Three sets of IA and one set of DF were operated. Three of four systems were added with fermented settled sludge taken from primary settling tank as an external electron donor and the other(IA) for control reactor was operated without addition of electron donor. All systems were operated at same sludge retention time of 20 days and hydraulic retention time of 12hrs. The supplemental electron donor was supplied into the anoxic mode. A higher denitrification rate was observed from the reactors with fermented settled sludge as an electron donor for denitrification compared to that of without addition of organic source. The result of this study indicates that the settled primary sludge, if the fermented at the acid stage, was an excellent electron donor for denitrification. 81 % of TN and 80% of TP were removed from the systems with the supplemental organic source added. However, the control reactor without addition of electron donor showed only 39% of TN and 43% of TP.

Cure Shrinkage Behavior of Polymer Matrix Composite according to Degree of Cure (경화도에 따른 고분자 기지 복합재의 경화 수축률 거동)

  • Kwon, Hyuk;Hwang, Seong-Soon;Choi, Won-Jong;Lee, Jae-Hwan;Kim, Jae-Hak
    • Composites Research
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    • v.27 no.3
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    • pp.90-95
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    • 2014
  • Cure shrinkage during cure process of polymer matrix composites develope residual stress that cause some structural deformation, such as spring-in, spring-out and warpage. The carbon/epoxy prepreg used in this study is Hexply M21EV/34%/UD268NFS/IMA-12K supplied by Hexcel corp. Cure shrinkage and degree of cure measured by TMA(thermomechanical analyzer) and DSC(differential scanning calorimetry). Cure shrinkages are measured by TMA within a temperature range of $140{\sim}240^{\circ}C$ in a nitrogen atmosphere, and degree of cure determined by the heat of reaction using dynamic and isothermal DSC runs in argon atmosphere. As a result, the cure shrinkage is increased dramatically in a degree of cure range between 27~80%. the higher the cure temperature, the lower the degree of cure occurring to begin cure shrinkage.

Aggregation of Partially Quarternized Poly(4-vinylpyridine) with Anionic Surfactant Sodium Dodecvl Sulfate (부분적으로 4차아민화된 폴리(4-비닐피리딘)과 음이온 계면활성제인 도데실 황산 소듐과의 응집체 형성)

  • 김용철;박일현;심후식;최이준
    • Polymer(Korea)
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    • v.28 no.2
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    • pp.154-161
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    • 2004
  • Modified poly(4-vinylpyridine) was obtained by partial quarternization of nitrogen atoms in pyridine rings of poly(4-vinylpyridine) with methyl group. By means of laser light scattering and fluorescence, it was found that this modified polymer chains were aggregated in the aqueous solution and its structure was core-shell type. The hydrophobic parts of the chains were densely condensed in core part and the hydrophilic part of quarternized amino with positive charge formed the shell part. In the mixed system of modified poly(4-vinylpyridine) and anionic surfactant, sodium dodecyl sulfate, it was observed that a critical aggregation concentration existed and that this critical concentration was suddenly decreased above 0.1 M NaCl. The size change of aggregates was also investigated by dynamic light scattering while sodium dodecyl sulfate was added into polymer solution upto the critical aggregation concentration.

Development and Field Application of the Advanced Wastewater Treatment process (KSMBR) by Hollow Fiber Submerged Membrane (침지식 중공사막을 결합한 Dynamic state 하수고도처리공정(KSMBR process)의 개발 및 현장적용평가)

  • Kim, Ji-yeon;Seo, In-seok;Kim, Hong-suck;Kim, Youn-kwon;Kim, Byung-goon;Choi, Chang-gyu;Ahn, Hyo-won;Seo, Wan-seok;Jang, Moon-seog
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.358-363
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    • 2006
  • KSMBR process is dynamic state advanced wastewater treatment applied with Trisectional Aeration (TSA) mode combined with membrane. TSA was remodeled conventional intermittent aeration which was operated nonaeration-aeration. TSA operates nonaeration ($N_1$) - aeration (A) - nonaeration ($N_2$) in Trisectional Aeration Reactor (TAR). Organics of influent could be nearly consumed to denitrification without influence by remained DO in TAR and it could be operated about sludge return ratio of 1Q (influent base). The purpose of this study was to apply KSMBR to the full-scale plant and to evaluate efficiency of nitrogen and phosphorus removal and TSA operation. The result of this study, average CODcr/T-N and CODcr/T-P ratio were 7.8 and 59.6, respectively. BOD, TCODcr, SS, T-N, T-P, E-coli removal efficiency were 98.4, 95.2, 73.0, 69.6, 99.95 %, respectively. KSMBR obtained high removal efficiencies of C, N and P when it applied full-scale plant.

Effect of Decomposition on Nitrogen Dynamics in Soil Applied with Compost and Rye

  • Ko, Byong-Gu;Kim, Myung-Sook;Park, Seong-Jin;Yun, Sun-Gang;Oh, Taek-Keun;Lee, Chang Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.6
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    • pp.648-657
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    • 2015
  • Soil organic matter (SOM) plays an important role in the continuous production and environmental conservation in arable soils. In particular, the decomposition of organic matter in soil might promote soil organic matter and fertility due to the mineralization of N. In this study, to evaluate the effect of organic matter amendment on the C mineralization and N dynamic, $CO_2-C$ flux, extractable N and $N_2O$ emission were determined using closed chamber for 4 weeks at 10, 15, $20^{\circ}C$ of incubation temperature after the mixture of $2Mgha^{-1}$ rice straw compost and rye in sandy loam and clay loam. Regardless of soil texture, decomposition rates of rice straw compost and rye at $10{\sim}20^{\circ}C$ of incubation temperature ranged from 0.9 to 3.8% and 8.8 to 20.3%, respectively. Rye application in soil increased $NH_4-N$ and $NO_3-N$ content as well as the $N_2O$ emission compared to the rice straw compost. After incubation for 4 weeks, total C content in two soils was higher in rice straw compost than in rye application. In conclusion, application of rice straw compost and rye to soil was able to improve the soil organic matter and fertility. However, organic matter including the recalcitrant compounds like rice straw compost would be effective on the management of soil organic matter and the reduction of greenhouse gases in soil.

Ultraviolet Resonance Raman Spectroscopy of Bacteriorhodopsin and Its Photointermediates

  • Hashimoto, Shinji
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.114-117
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    • 2002
  • Ultraviolet resonance Raman (UVRR) spectroscopy was used to elucidate the dynamic change of the protein structure of bacteriorhodopsin (BR) during the photocycle. The photointermediates minus light- adapted (LA) BR difference spectra show Trp difference signals, which are assigned to Trp189 or Trp182 on helix F by using the mutants, W182F and W189F. The Difference signals of Trp 182 indicates an increase in hydrogen bonding strength at the indole nitrogen and a large change in the side chain conformation (X$\^$2,1/ torsion angle) in the M$_1$ \longrightarrow M$_2$ transition. On the other hand, Trp189 shows an increased hydrophobic interaction. These results suggest that the tilt of helix F occurs in the M$_1$\longrightarrow M$_2$ transition. In the M$_2$ \longrightarrow N transition, the hydrophobic interaction of Trp182 decreases drastically, The decrease in hydrophobic interaction of Trp182 in the N state suggests an invasion of water molecules that promote the proton transfer from Asp96 to the Schiff base. Structural reorganization of the protein after the tilt of helix F may be important for efficient reprotonation of the Schiff base.

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Impact of Physiological Stresses on Nitric Oxide Formation by Green Alga, Scenedesmus obliquus

  • Mallick, Nirupama;Mohn, Friedrich-Helmuth;Rai, Lalchand;Soeder, Carl-J.
    • Journal of Microbiology and Biotechnology
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    • v.10 no.3
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    • pp.300-306
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    • 2000
  • The rate of apparent nitric oxide (NO) release, as measured in the exhaust gas of green alga, Scenedesmus obliquus, depended on the light intensity and pH. It doubled after lowering the temperature from $25^{\circ}C{\;}to{\;}15^{\circ}C$ and strongly decreased from $35^{\circ}C{\;}to{\;}42^{\circ}C$. The Scenedesmus cells, deficient in nitrogen or phosphorus, demonstrated a significant increase in NO production following their transfer to nitrate- and phosphate-rich media. The addition of herbicides (DCMU and glyphosate) or toxic concentrations of $Cu^{2+}{\;}or{\;}Fe^{3+}$ produced strong NO peaks, resembling those that occurred after sudden darkening. An increase in the $Ni^{2+}$ concentration to 20 ppm resulted in a gradual increase of NO release from the initial ~1.5 ppbv to>20 ppbv, whereas $Cd^{2+}$ instantaneously suppressed the NO by the cultures of Scenedesmus was not altered by L-NNA, an inhibitor of nitric oxide synthase (NOS), or by its substrate, L-arginine. This seems to exclude the role of NOS in the NO formation under study. Accordingly, it can be assumed that the rate of NO formation is mainly a function of dynamic nitrite pool sizes and environmental factors significantly affect the NO production in algae.

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Long-term Variations of Chemical Properties in Controlled Horticultural Soils of Gyeongnam Province

  • Lee, Young-Han;Lee, Seong-Tae;Hong, Kang-Pyo;Lee, Sang-Dae;Kim, Je-Hong;Ok, Yong-Sik;Kim, Min-Keun;Kim, HyeRan
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.5
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    • pp.308-312
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    • 2013
  • The monitoring of chemical dynamic changes in controlled horticultural lands is very important for agricultural sustainability. Field monitoring was performed to evaluate the soil chemical properties of 200 controlled horticultural soil samples in Gyeongnam province every 4 years from 2000 to 2012. Soil chemical properties such as pH, amount of organic matter, available phosphate, nitrate nitrogen, and exchangeable potassium, calcium, magnesium, and sodium were analyzed. The amount of exchangeable calcium and soil pH were significantly higher in 2012 than in 2000. In 2012, the frequency distribution for values of pH, organic matter, available phosphate, and exchangeable potassium, calcium, and magnesium that were within the optimum range was 16.0%, 22.5%, 11.5%, 3.5%, 2.5%, and 5.0%, respectively. Especially, available phosphate and exchangeable calcium were excess level with portions of 76.0% and 96.5%, respectively. These results indicated that a balanced management of soil chemical properties can reduce the amount of fertilizer applied for sustainable agriculture in controlled horticultural lands.

A Study on Thermal Stability of Chlorinated Polyethylene (함염소 폴리에틸렌의 열안정성에 관한 연구)

  • Seul S. D.;Lee N. W.
    • Journal of the Korean Institute of Gas
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    • v.1 no.1
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    • pp.120-126
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    • 1997
  • The thermal decomposition of low density polyethylene(LDPE) and $25\%{\~}48\%$ chlorinated polyethylene(CPE) were studied using a dynamic thermogravimetry in the stream of nitrogen gas with 20ml/min. The mathematic method, differential (Friedman) and Integral (Ozawa) method were used to obtain value of activation energy of decomposition energy on the reaction. The activation energies evaluated by the above methods agree with each other very well. The maximum average activation energy calculated was 71.71kcal/mol. The thermal decomposition of LDPE and CPE were considered to be carried out by main chain scission and the thermogravimetric trace curve agree with the theoretical equation.

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