• 제목/요약/키워드: Nitrogen dynamic

검색결과 135건 처리시간 0.022초

비이온성 미셀용액과 수중유형 마이크로에멀젼계의 특성 및 수단 IV의 가용화 (Characteristics of Non-ionic Micellar and O/W Microemulsion Systems and Solubilization of Sudan IV)

  • 지웅길;황성주;장은옥;현종목
    • 약학회지
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    • 제39권5호
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    • pp.495-505
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    • 1995
  • The O/W microemulsion systems were made from 2 or 4% (w/w) oil (soybean oil, olive oil or isopropyl myristate) and 10, 15 or 20% (w/w) Brij 96. They were compared with micellar solution of equivalent surfactant concentration m therms of physicochemical properties, and the solubilization of sudan IV. They were characterized by dynamic light scattering, stability, surface tension, viscosity and rheogram. The mean diameters of O/W microemulsion systems were 10-15nm, and those of Brij 96 micellar solutions were 18-19 nm. Both of them were monodisperse systems. The O/W microemulsion systems showed Newtonian flow and their apparent viscosities were lower than those of micellar solutions. The surface tensions of O/W microemulsion systems were increased or decreased depending on the types of oil used, when compared with those of micellar solutions. The O/W microemulsion systems were very stable, and did not show any flocculation or aggregation. Their mean diameters were not changed after three months. But oxidation was observed in microemulsions without nitrogen gas at high temperature. There was a significant improvement in the sudan IV solubffimtion in micromulsion compared with that m the micellar solution containing equivalent concentration of surfactant. The size distribution and mean diameters of O/W micromulsions were not changed when sudan IV was solubilized.

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하이드라진(N2H4) 아크젯 추력기의 수치적 모델링 (Numerical Modeling of Hydrazine-Fueled Arcjet Thruster)

  • 신재렬;이대성;오세종;최정열
    • 한국항공우주학회지
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    • 제36권9호
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    • pp.907-915
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    • 2008
  • 하이드라진(N2H4) 아크젯 추력기의 열화학 유동장 해석을 위한 전산유체해석을 수행하였다. 열복사와 전기장이 고려된 압축성 유동해석을 위해서 RANS 방정식을 수정하여 사용하였다. 로렌츠 힘과 Ohm 가열효과를 고려한 Maxwell 방정식이 유동방정식과 결합되어 전기 방전으로 인한 전기장해석을 위해 이용되었다. 아크젯 추력기 내부에서 유동장은 충분히 고온상태이기에 화학평형 해석이 이용되었으며, 광학 두께를 이용한 열복사 모델이 유동방정식에 적용되었다. 계산 결과들은 아크젯 추력기유동이 동결유동에 비해 추력은 180%증가되며, 비추력은 200%가까이 상승됨을 보여준다. 또한 유동장 해석 결과들은 아크젯 추력기 내부의 열적 물리적 특성에 대한 이해를 돕는다.

OPF with Environmental Constraints with Multi Shunt Dynamic Controllers using Decomposed Parallel GA: Application to the Algerian Network

  • Mahdad, B.;Bouktir, T.;Srairi, K.
    • Journal of Electrical Engineering and Technology
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    • 제4권1호
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    • pp.55-65
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    • 2009
  • Due to the rapid increase of electricity demand, consideration of environmental constraints in optimal power flow (OPF) problems is increasingly important. In Algeria, up to 90% of electricity is produced by thermal generators (vapor, gas). In order to keep the emission of gaseous pollutants like sulfur dioxide (SO2) and Nitrogen (NO2) under the admissible ecological limits, many conventional and global optimization methods have been proposed to study the trade-off relation between fuel cost and emissions. This paper presents an efficient decomposed Parallel GA to solve the multi-objective environmental/economic dispatch problem. At the decomposed stage the length of the original chromosome is reduced successively and adapted to the topology of the new partition. Two subproblems are proposed: the first subproblem is related to the active power planning to minimize the total fuel cost, and the second subproblem is a reactive power planning design based in practical rules to make fine corrections to the voltage deviation and reactive power violation using a specified number of shunt dynamic compensators named Static Var Compensators (SVC). To validate the robustness of the proposed approach, the algorithm proposed was tested on the Algerian 59-bus network test and compared with conventional methods and with global optimization methods (GA, FGA, and ACO). The results show that the approach proposed can converge to the near solution and obtain a competitive solution at a critical situation and within a reasonable time.

COMBUSTION KINETICS OF POLYETHYLENE TEREPHTHALATE

  • Oh, Sea-Cheon;Lee, Dong-Gyu;Kwak, Hyun;Bae, Seong-Youl
    • Environmental Engineering Research
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    • 제11권5호
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    • pp.250-256
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    • 2006
  • The combustion kinetics of poly(ethylene terephthalate) (PET) was studied by the dynamic model which accounts for the thermal decomposition of polymer at any time. The kinetic analysis was performed by a conventional nonisothermal thermogravimetric (TG) technique at several heating rates between 10 and 40 K/min in air atmosphere. The thermal decomposition of PET in air atmosphere was found to be a complex process composed of at least two stages for which kinetic values can be calculated. The combustion kinetic analysis of PET gave apparent activation energy for the first stage of $257.3{\sim}269.9\;kJ/mol$, with a value of $140.5{\sim}213.8\;kJ/mol$ for the second stage. To verify the effectiveness of the kinetic analysis method used in this work, the kinetic analysis results were compared with those of various analytical methods. The kinetic parameters were also compared with values of the pyrolysis of PET in nitrogen atmosphere.

가솔린엔진용 E-EGR 밸브 특성에 관한 연구 (A Study on the Characteristics of the Electronic EGR Valve for Gasoline Engine)

  • 박철웅;김창기
    • 한국자동차공학회논문집
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    • 제16권1호
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    • pp.127-133
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    • 2008
  • Since the 1960's, exhaust gas recirculation(EGR) has been used effectively in spark ignition(SI) engines to control the exhaust emissions of the oxides of nitrogen(NOx). The most important requirements for the application of EGR systems to conventional SI engines are controllable flow rate and good dynamic response. In order to evaluate the characteristics of the electronic EGR valve, a test bench which is consisted of blower, heater, air flow meter and driving unit for electronic EGR valve was set up to simulate engine operating conditions. During the tests, the valve actuation parameters were controlled and the valve lifts and flow rates were measured to infer the characteristics of EGR valve. The results confirmed the capabilities of mathematical analysis and it seems that the correction for the valve lift and potentiometer output is necessary to achieve precise control of EGR rates.

저신장율 대향류확산화염에서 소화하는 화염디스크로부터 화염구멍으로 천이에 관한 연구 (A Study on Transition of Shrinking Flame Disk to Flame Hole at Low Strain Rate Counterflow Diffusion Flames)

  • 박대근;박정;윤진한;길상인
    • 한국연소학회지
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    • 제13권4호
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    • pp.16-25
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    • 2008
  • Experiments have been conducted to clarify impacts of curtain flow and velocity ratio on low strain rate flame extinction, and to further display transition of shrinking flame disk to flame-hole. Critical mole fractions at flame extinction are examined in terms of velocity ratio, global strain rate, and nitrogen curtain flow rate. It is shown that multi-dimensional effects at low strain rate flames through global strain rate, velocity ratio, and curtain flowrate dominantly contribute to flame extinction and transition of shrinking flame disk to flame hole. Our concerns are particularly focused on the dynamic behavior of an edge flame in shrinking flame disk.

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벨로스형 어큐뮬레이터의 압력 맥동 감쇠 특성 (Attenuation of Pressure Fluctuations in Oil Hydraulic Pipeline with Bellows Type Accumulator)

  • 이일영;정용길;이수종
    • 동력기계공학회지
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    • 제5권4호
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    • pp.31-37
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    • 2001
  • Pressure propagation and attenuation characteristics in a hydraulic pipeline with a bellows type accumulator was investigated by theoretical analyses and experiments. In the first stage of the study, equations to evaluate the amount of oil volume charged into the bellows together with nitrogen gas were proposed. In the next stage, the authors suggested a mathematical model based on transfer matrix method to describe the dynamic characteristics of the pipe element with a metal bellows type accumulator. Through comparisons and considerations of the experimental and the numerical data shown in frequency domain, the validity of the mathematical model was confirmed.

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Sorption of $Pb^{2+}$ Ions on to Activated Carbons Prepared from Olive Stones

  • Attia, Amina. A.;Shouman, Mona. A.;El-Nabarawy, Th.
    • Carbon letters
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    • 제6권3호
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    • pp.141-147
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    • 2005
  • The carbon sample "O", phosphoric acid-activated carbon "OP", zinc chloride-activated carbon "OZ", and two steam activated carbons "OS" and "OS2" with different burn-off of 25% and 58% respectively, were prepared from olive stones. The textural properties were determined from the results of nitrogen adsorption at 77 K and by analyzing these results through the application of different adsorption models. The chemistry of the carbon surfaces was determined from the base neutralization capacities, acid neutralization capacity and surface pH. The sorption of $Pb^{2+}$ ions on to the carbons prepared was followed under dynamic and equilibrium conditions. The differences between the values of the textural parameters were attributed to the inapplicability of some adsorption models and to the heterogeneity of the microporous carbons. The sorption of $Pb^{2+}$ ions is favored on carbon and activated carbons. However, chemically activated carbons are more effective compared with steam-activated ones. The sorption of $Pb^{2+}$ ions were related to the chemistry of the surface rather than to the textural properties.

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3D 프린팅 공정 관점의 저온분사 기술 (Cold spray technology as a potential additive manufacturing)

  • 김형준;윤상훈
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.90-90
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    • 2017
  • Cold spray (Cold gas dynamic spray, kinetic spray) is the latest spray coating process that is known as solid state deposition process. In cold spray, inert gases (typically nitrogen and helium) accelerate powder particles prior to impact onto the substrate. Accelerating particles start to deposit onto the substrate after reaching certain critical velocities depending on the coating materials and substrate. Since process gas temperatures are kept below to melting temperature of the coating materials, it is possible to spray temperature sensitive materials such as copper and titanium, nanocrystal materials, and amorphous metals without affecting the phase change and oxide formation. It is also possible to deposit thick coatings because cold spray coatings present compressive residual stresses. This ability to deposit thick coatings is suitable to repair or rebuild parts as an additive manufacturing process. In this presentation, cold spray is introduced and compared to other additive manufacturing processes such as laser and electron beam based processes. It is also presented some applications especially in the view point of additive manufacturing process.

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Poly(n-butyl methacrylate)의 열분해에 관한 연구 (Study on the Thermal Degradation of Poly(n-bulyl methacrylate))

  • 곽기철;설수덕;손진언
    • Elastomers and Composites
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    • 제23권3호
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    • pp.213-222
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    • 1988
  • The thermal decomposition of poly(n-butyl methacrylate)(Pn-BMA) was studied using a dynamic and isothermal thermogravimetry in nitrogen gas with 50ml/min at several heating rates from 1 to $20^{\circ}C/min$, and at several heating temperature from 320 to $370^{\circ}C$. The mathematical techniques used for calculation of activation energy were Kissinger, Anderson, Chatterjee-Conrad, Friedman, Fuoss, Ozawa and isolthermal method. The range of activation energies obtained using the several techniques was between 43 and 51Kcal/mol except Chatterjee-Conrad and this range agreed with each other very well. The thermal degradation of Pn-BMA was considered to be carried out by main chain scission.

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