• Title/Summary/Keyword: Nitrogen behavior

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Effect of Nitrogen Ion Implantation on Wear Behavior of Biocompatible Ti Implant (질소이온 주입이 생체적합성 티타늄 임플란트의 마모특성에 미치는 영향)

  • Byeon, Eung-Seon;Kim, Dong-Su;Lee, Gu-Hyeon;Jeong, Yong-Su
    • 연구논문집
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    • s.30
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    • pp.137-145
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    • 2000
  • Since the concept of osseointegration was introduced, titanium and titanium-based alloy materials have been increasingly used for bone-anchored metal in oralmaxillofacial and orthopedic reconstruction. Successful osseointegration has been attributed to biocompatibility and surface condition of metal implant among other factors. Although titanium and titanium alloys have an excellent over the metal ion release and biocompatibility, considerable controversy has developed over the metal ion and wear debris in vivo and vitro. In this study, nitrogen ion implantation technique was used to improve the corrosion resistance and wear property of titanium materials, ultimately to enhance the tissue reaction to titanium implants As ion implantation energy was increased, projected range of nitrogen ion the Ti substrate was gradually increased. Under condition of constant ion energy. atomic concentration of nitrogen was also increased with ion doses. The friction in Hank's solution was increased with ion doses. The friction coefficient of ion implanted specimens in HanK's solution was increased from 0.39, 0.47 to 0.52, 0.65 respectively under high energy and ion dose conditions. As increasing ion energies and ion dose, amount of wear was reduced.

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CFD Analysis of Natural Convection Flow Characteristics of Various Gases in the Spent Fuel Dry Storage System

  • Shin, Doyoung;Jeong, Uiju;Jeun, Gyoodong;Kim, Sung Joong
    • The KSFM Journal of Fluid Machinery
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    • v.19 no.4
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    • pp.19-28
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    • 2016
  • Objective of this study is to compare the inherent characteristics of natural convection flow inside the canister of spent fuel dry storage system with different backfill gases by utilizing computational fluid dynamics (CFD) code. Four working fluids were selected for comparison study. Helium currently used backfill gas for canister, air, nitrogen, and argon are frequently used as coolant in many heat transfer applications. The results indicate that helium has very distinct conductive behavior and show very weak natural convective flow compared to the others. Argon showed the strongest natural convective flow but also the worst coolability. Air and nitrogen showed similar characteristics to each other. However, due to difference in Prandtl number, nitrogen showed more effective natural convective flow. These results suggest that experimental validation for the nitrogen is needed to investigate the potential coolability other than currently commercially used helium.

Nitrogen Transport In Groundwater-Surface Water Hyporheic Zone at Brackish Lake (기수호의 지하수-지표수 혼합대 내 질소 거동 분석)

  • Seul Gi Lee;Jin Chul Joo;Hee Sun Moon;Su Ryeon Kim;Dong Jun Kim
    • Ecology and Resilient Infrastructure
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    • v.11 no.2
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    • pp.23-34
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    • 2024
  • Sediment, aquifer materials, surface water, and groundwater from brackish Songji lake affected by salinity of seawater, were collected and a pilot scale column experiment was conducted to simulate the nitrogen transport through the hyporheic zone. Upstream experiments of groundwater displayed that groundwater containing a small amount of salt percolated into aquifers and sediments, maintaining low dissolved oxygen concentrations. In addition, partial denitrification occurred in the aquifer due to salinity and low dissolved oxygen, resulting in the accumulation of NO2-. In sediments,nitrogenous compounds were reduced due to adsorption by long residence times or microbial-mediated oxidation/reduction reactions. Downstream experiments of surface water displayed that surface water from the brackish lake, containing high concentrations of dissolved oxygen and salts, infiltrated into the sediments and aquifer, supplying high dissolved oxygen concentrations. This resulted in biological nitrification in the sediments and aquifer, which reduced nitrogen-based pollutants despite the high salt concentration in the surface water. Whereas partial denitrification at low dissolved oxygen concentrations in the upwelling mixing zone was observed by salinity and accumulated NO2-, nitrification at high dissolved oxygen concentrations in the downwelling mixing zone was not significantly affected by salinity. These results confirm that salinity in the brackish water lake has some influence on the nitrogen behavior of the hyporheic mixing zone, although nitrogen behavior is a complex combination of factors such as DO, pH, substrate concentration, and organic matter concentration.

Effect of Crystallization Treatment on the Magnetic Properties of Amorphous Strips Based on Co-Fe-Ni-B-Si-Cr Containing Nitrogen

  • Cho H.J.;Kwon H.T.;Ryu H.H.;Sohn K.Y.;You B.S.;Park W.W.
    • Journal of Powder Materials
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    • v.13 no.4 s.57
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    • pp.285-289
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    • 2006
  • Co-Fe-Ni-B-Si-Cr based amorphous strips containing nitrogen were manufactured via melt spinning, and then devitrified by crystallization treatment at the various annealing temperatures of $300^{\circ}C{\sim}540^{\circ}C$ for up to 30 minutes in an inert gas $(N_2)$ atmosphere. The microstructures were examined by using XRD and TEM and the magnetic properties were measured by using VSM and B-H meter. Among the alloys, the amorphous ribbons of $Co_{72.6}Fe_{9.8}Ni_{5.5}B_{2.4}Si_{7.1}Cr_{2.6}$ containing 121 ppm of nitrogen showed relatively high saturation magnetization. The alloy ribbons crystallized at $540^{\circ}C$ showed that the grain size of $Co_{72.6}Fe_{9.8}Ni_{5.5}B_{2.4}Si_{7.1}Cr_{2.6}$ alloy containing 121 ppm of nitrogen was about f nm, which exhibited paramagnetic behavior. The formation of nano-grain structure was attributed to the finely dispersed Fe4N particles and the solid-solutionized nitrogen atoms in the matrix. Accordingly, it can be concluded that the nano-grain structure of 5nm in size could reduce the core loss within the normally applied magnetic field of 300A/m at 10kHz.

Experimental Study on the Lift-off Behavior of Tone-excited Propane Jet Diffusion flames (음향 가진 된 프로판 확산 화염의 부상 거동에 관한 실험적 연구)

  • Kim, Seung-Gon;Park, Joeng;Kim, Tea-Kwon;Lee, Kee-Man
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.65-73
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    • 2003
  • An experimental study on flame lift-off characteristics of propane jet flame highly diluted with nitrogen has been conducted introducing acoustic forcing with a tube resonant frequency. A flame stability curve is attained according to forcing strength and nozzle exit velocity for $N_2$ diluted flames. Flame lift-off behavior with forcing strength and nozzle exit velocity is globally categorized into three; a well premixed behavior caused by a collapsible mixing for large forcing strength, a coexistent behavior of well-premixed and edge flames interacting with well-organized inner fuel vortices for moderate forcing strengths, and edge flame behavior for small forcing strengths. Special focus is concentrated on the coexistent behavior of the flame base in lifted flame since this may give a hint to a possibility which the flame base behaves like a well-mixed premixed flame in highly turbulent lifted flames. It is also shown that the acoustic forcing to self-pulsating laminar lifted flame affects flame lift-off behavior considerably which is closely related to downstream flow velocity, mixture strength, effective fuel Lewis number, and flame stretch.

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An Experimental Study on the Lift-off Behavior of Tone-Excited Propane Non-premixed Jet Flames (음향 가진된 프로판 비예혼합 제트 화염의 부상 거동에 대한 실험적 연구)

  • Kim, Seung-Gon;Kim, Kang-Tae;Park, Jeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.5
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    • pp.569-579
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    • 2004
  • The lift-off characteristics of lifted laminar propane jet flames highly diluted with nitrogen are investigated introducing acoustic forcing with a fuel tube resonance frequency. A flame stability curve is obtained according to forcing strength and the nozzle exit velocity for N2 diluted flames. Flame lift-off behavior is globally classified into three regimes; 1) a weakly varying partially premixed behavior caused by a collapsible mixing for large forcing strength, 2) a coexistent behavior of the edge flame and a weakly varying partially premixed behavior for moderate forcing strength, and 3) edge flame or triple flame behavior for small forcing. It is shown that the laminar lifted flame with forcing affects flame lift-off behavior considerably, and is also clarified that the flame characteristic of flame base is well described with the penetration depth of the degree of mixing, ${\gamma}$$\_$$\delta$/. It is also confirmed that the weakly varying partially premixed flame caused by a collapsible mixing fur large forcing strength behaves as that just near flame blow-out in turbulent lift-off flame.

Behavior of Nutrients in Runoff Water from a Small Rural Watershed (농촌 소유역 유출수에서의 영양염류의 거동)

  • Oh, Kwang-Young;Kim, Jin-Soo;Oh, Seung-Young
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.2
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    • pp.51-57
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    • 2009
  • The purpose of this study was to investigate characteristics of behavior of nutrients such as TN (Total nitrogen), TDN (Total dissolved nitrogen), TP (Total phosphorus) TDP (Total dissolved phosphorous) in runoff water from a nonpoint source dominated watershed ($6.67\;km^2$). Regular and intensive flow measurement and water sampling were taken during two years (February 2002 to January 2004) in the Ingyeong River, a tributary of the Han River. The mean concentrations of nutrients during rainy days were significantly (p < 0.05) higher than those during dry days. The mean TDN/TN ratio in rainy days (95%) is almost identical to that in dry days (96%), but mean TDP/TP ratio in rainy days (24%) significantly decreased compared with that in dry days (66%), suggesting that dominant form of TP is shifted from dissolved form to particulate form. Accordingly, the measures (.eg. filter strips, cover crops) to reduce soil erosion for fallow upland in the rainy season should be taken to control particulate phosphorous.

Bending Strain Dependence of the Critical Current in Externally-reinforced Bi-2223 Tapes with Different Hermeticity under pressurized Liquid Nitrogen (외부보강된 밀봉 상태가 다른 Bi-2223테이프의 가압 LN2하에서 임계전류의 굽힘변형률 의존성)

  • Shin, Hyung-Seop;Dizon, John Ryan C;Park, Jeong-Soo;Rolley, Bonifacio
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.541-545
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    • 2007
  • The critical current degradation behaviors of multifilamentary Bi-2223 superconducting tapes under pressurized liquid nitrogen were investigated using a r-shaped sample holder which gives a series of bending strains to tape. Three kinds of externally-reinforced Bi-2223 tapes with different hermeticity were used as samples. The tape with the thicker reinforcement layer had a better bending strain tolerance of $I_c$, but when the bending strain was calculated at the outermost filament, the $I_c$ degradation behavior became identical. For all samples, $I_{c0}$ decreased with the increase of applied pressure, but the $I_c$ degradation behavior with bending strain at each pressure level was similar. Furthermore, after depressurization from 1 MPa to atmospheric pressure, $I_c$ was completely recovered to its initial values. When the samples were warmed up to room temperature after pressurization tests, the ballooning damage occurred at lower bending strain regions. The region where ballooning was observed was identical to the one where the significant $I_c$ degradation occurred.

Toughness and Damping Properties of Nanostructured Ni-Al Alloys Produced by Mechanical Alloying Methods (기계적합금화법에 의해 제조된 NiAl 나노금속간화합물 소결체의 인성 및 제진특성)

  • 안인섭;김형범;김영도;김지순
    • Journal of Powder Materials
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    • v.7 no.3
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    • pp.143-148
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    • 2000
  • NiAl alloy powders were prepared by mechanical alloying method and bulk specimens were produced using hot isostatic pressing techniques. This study focused on the transformation behavior and properties of Ni-Al mechanically alloyed powders and bulk alloys. Transformation behavior was investigated by differential scanning calorimeter (DSC), XRD and TEM. Particle size distribution and microstructures of mechanically alloyed powders were studied by particle size analyzer and scanning electron microscope (SEM). After 10 hours milling, XRB peak broadening appeared at the alloyed powders with compositions of Ni-36at%Al to 40at%Al. The NiAl and $Ni_3Al$ intermetallic compounds were formed after water quenching of solution treated powders and bulk samples at $1200^{\circ}C$, but the martensite phase was observed after liquid nitrogen quenching of solution treated powders. However, the formation of $Ni_3Al$ intermetallic compounds were not restricted by fast quenching into liquid nitrogen. It is considered to be caused by fast diffusion of atoms for the formation of stable $\beta$(NiAl) phase and $Ni_3Al$ due to nano sized grains during quenching. Amounts of martensite phase increased as the composition of aluminium component decreased in the Ni-Al alloy, which resulted in the increasing damping properties.

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