• Title/Summary/Keyword: Nitrogen behavior

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Structure Behavior of Sputtered W-B-C-N Thin Film for various nitrogen gas ratios (PVD법으로 증착한 W-B-C-N 박막의 질소량에 따른 구조변화 연구)

  • Song, Moon-Kyoo;Lee, Chang-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.109-110
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    • 2005
  • We have suggested sputtered W-C-N thin film for preventing thermal budget between semiconductor and metal. These results show that the W-C-N thin film has good thermal stability and low resistivity. In this study we newly suggested sputtered W-B-C-N thin diffusion barrier. In order to improve the characteristics, we examined the impurity behaviors as a function of nitrogen gas flow ratio. This thin film is able to prevent the interdiffusion during high temperature (700 to $1000^{\circ}C$) annealing process and has low resistivity ($\sim$200$\mu{\Omega}-cm$). Through the analysis of X-Ray diffraction, resistivity and XPS, we studied structure behavior of W-B-C-N diffusion barrier.

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Neural network for Prediction of the Cutting Characteristies in Cryogenic Cutting (극저온 절삭에서 절삭특성예측을 위한 신경회로망의 적용)

  • 김칠수;오석영;임영호
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1994.10a
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    • pp.32-37
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    • 1994
  • We experimented on cutting characteristics - cutting force, behavior of cutting temperature, surface roughness, behavior of chips-under low temperature,which generated by liquid nitrogen(77K). The workpieces were freezed to -195 .deg. C and liquid nitrogen was also sprinkled on cutting area in order to increase the efficiency of machining in low temperature. The workpiece was became to -195 .deg. C in 5 minutes. In cooled condition(CC) surface roughness of workpiece was better than normal condition(NC). In addition, we investigated the possibility that surface roughness of workpiece and shear angle can be predicted analyzing cutting condititions by the trained neural network.

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Wear-characteristics variation of Fe-C-N alloy with changing content of carbon and nitrogen (탄소와 질소 함량에 따른 탄질소 복합첨가강의 내마멸 특성 변화)

  • Park, J.K.;Yi, S.K.;Kim, S.J.;Kim, Y.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.385-388
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    • 2009
  • Dry-sliding-wear behavior of Fe-18Cr-l0Mn steel with various carbon and nitrogen contents was characterized, and the effect of carbon and nitrogen contents on the wear was investigated. Dry sliding wear tests of the steel were carried out at room temperature against an AISI 52100 bearing steel ball using a pin-on-disk wear tester. Applied wear loads were varied from 10 N to 100 N, and the sliding distance was fixed as 720 m. Worn surfaces and the wear debris of the steel were examined using an SEM to find out the wear mechanism. It was found that the Fe-18Cr-10Mn with both carbon and nitrogen exhibited superior wear resistance to the steel with only nitrogen. The wear resistance of the Fe-18Cr-10Mn-xC-yN alloy increased with the increase of the carbon content. The excellent wear resistance of the Fe-18Cr-10Mn-xC-yN alloy was explained by the increased strain-hardening capability with the interstitial atoms.

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Improvement of wear resistance of Zircaloy-4 by nitrogen implantation

  • Han, Jeon G.;Lee, jae S.;Kim, Hyung J.;Kim, W.;Choi, B.Y.;Tang, Guoy
    • Proceedings of the Korean Vacuum Society Conference
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    • 1995.06a
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    • pp.151-151
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    • 1995
  • Nitrogen implantation process has been applied for improvement of wear resistance of Z Zircaloy-4 fuel cladding materials. Nitrogen was implanted at 120 ke V to a total do range of 1xHP ions/cm2 to 8xlO17 ions/cm2 at various temperatures of 298"C to 676"C. The m microstructure changes by nitrogen implantation were analyzed by using TEM, XRD 뻐d A AES, cmd then wear behavior was evaluated by ball-on-disc wear testings at various loads a and sliding velocity under unlubricated condition. Nitrogen implantation produced ZrNx nitride above 4.37x1017 ions!cm2 as well as heavy d dislocations, which enhanced microhardness of the implanted surface of up to 900 Hk from 2 200 Hk of unimplanted substrate. Hardness was also found to be increased with increasing i implantation temperature and enhanced up to OOOHk at 620 "C. the wear resistance was g greatly improved with increasing total ion do않 as well as implantation temperature. The effective enhancement of wear resistance at high dose and tem야ratures is believed d due to significant hardening associated with high degree of precipitation of Zr nitrides and g generation of prismatic dislocation I$\infty$ps.infty$ps.

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Thermal diffusion experiment of impulsive heat in subcooled liquid nitrogen (과냉 액체질소 내에서 순간적 열확산 실험)

  • Choi, J.H.;Ha, J.C.;Byun, J.J.;Chang, H.M.;Kim, H.M.;Ko, T.K.
    • Progress in Superconductivity and Cryogenics
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    • v.8 no.1
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    • pp.65-70
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    • 2006
  • Transient heat transfer caused by an impulsive heating in subcooled liquid nitrogen is investigated experimentally. This study is part of out ongoing efforts directed to a stable cryogenic cooling system lot superconducting fault current limiters (SFCL). A thin heater attached by epoxy on one surface of a GFRP plate is immersed in liquid-nitrogen bath at temperatures between 77 K and 55 K. A strong heat flux up to $150W/cm^2$ is generated lot 100 ms, and the temperature of the heater sulfate is measured as a function of time. The behavior of bubbles on the heating surface can be explained by comparing the measured temperature history for vertical and two horizontal (up and down) orientations. It is concluded that the subcooling of liquid nitrogen below 70 K is very effective in suppressing bubbles, resulting in better thermal protection and faster recovery from an impulsive heat.

Ecological Study of the Changes in the Components of Human Milk During the Breast Feeding and the Relationships between the Dietary Behavior of Lactating Women and the Growth of Breastfed Infants - I. A Study on the Nitrogen Content in Human Milk - (수유 기간에 따른 모유의 성분 함량 변화와 수유부의 섭식 태도 및 영아의 성장 발육에 관한 생태학적 연구 I. 모유의 질소 함량에 관한 연구)

  • 송세화
    • Journal of Nutrition and Health
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    • v.23 no.3
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    • pp.179-186
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    • 1990
  • Nitrogen(N) concentrations of human milk in various fractions, such as total, protein, nonprotein, whey protein and casein were determined at 2-3 days, 1, 2, 4, 6 and 12 weeks of postpartum. significant decreases in total N, nonprotein N, protein N, whey protein N and casein N were found with time postpartum. Total nitrogen decreased from 401mg/dl at 2-3 days to 211mg/dl at 12 week. Whey protein nitrogen was found to contribute to the total nitrogen decrease with time. The percentage of nonprotein nitrogen was 13% in colostrum and 17-18% in mature milk. The proportions of whey protein and casein nitrogen were 55:45 at 2-3 days and 34:66 at 12 week postpartum. These determinations will provide the basic information on the variability of nitrogen components as lactation proceed.

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Deformation Behavior & Rolling Effect on the Hot Rolling of High Nitrogen Stainless Steel (고질소강의 열간압연시 변형거동 및 압연효과)

  • Kim, Y.D.;Kim, D.K.;Lee, J.W.;Bae, W.B.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.329-332
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    • 2008
  • Nowadays, It is required human body-friendly, good mechanical properties, and economical efficiency material, simultaneously. The material to meet above requirement condition rear up high nitrogen stainless steel(HNS). However, HNS have a lot of problem such as poor workability, hot crack sensitivity. So, It is needed the condition of plastic working to overcome above many problem. In this study, VIM ingot with 100kg was made by pressurized vacuum induction melting. And then, The slab perform for hot rolling was prepared by open-die forging. Hot rolling process was performed by computer simulation according to change of height reduction, rolling temperature, heating numbers, rolling pass and so forth. The results of analysis were investigated between analysis and lab-scale rolling product.

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