• Journal of the Korean Society of Marine Environment & Safety
• /
• v.20 no.1
• /
• pp.96-103
• /
• 2014

A liquefied natural gas(LNG) in cryogenic liquid is converted back into gaseous form for distribution to residential and industrial consumers. In this re-gasification process, LNG supplies a plenty of cold thermal energy about $83.7{\times}10^4kJ/kg$. The LNG cold thermal energy is utilized for the re-liquefaction process of cryogenic fluids such as Nitrogen, Hydrogen and Helium, and ice manufacturing process and air-conditioning system in some advanced countries. Therefore, it is also necessary to establish the recovery systems of the LNG cold thermal energy around Incheon, Pyungtaek and Tongyung LNG import terminals in our country. Methane is used as working fluid in this paper, which is the major component of LNG over 85 % by volume, in order to investigate the flow behavior characteristics of LNG with phase change at low heat flux. This paper presents the effects of pipe diameters, pipe inclinations and saturation pressures on the flow boundaries of methane flowing in a cryogenic heat exchanger tube, together with those of nitrogen, propane, R11 and R134a. The outcomes obtained from this theoretical researches are also compared with previous experimental data. It was also found that the effect of pipe inclination on the methane flow boundaries was significant.

• Journal of the Korean Society for Heat Treatment
• /
• v.7 no.4
• /
• pp.307-317
• /
• 1994

The surf ace microstructure modification by $N^+$ ion implantation into 7050Al alloy and its low cycle fatigue behavior were investigated. Ion implantation method is to physically implant accelerated ions to the surface of a substrate. High dose of nitrogen($5{\times}10^{17}ions/cm^2$) were implanted into 7050Al alloy using current density of accellerating voltage of 100KeV. The implanted layers were characterized by Electron Probe-Micro Analysis(EPMA), Auger Elecron Spectroscopy(AES), X-Ray Diffraction(XRD), X-Ray Photoelectron Spectroscopy(XPS), and Transmission Electron Microscopy(TEM). The experimental results were compared with computer simulation data. It was shown that AlN was formed to 4500 ${\AA}$ deep. The low cycle fatigue life of the $N^4$ion modified material was prolonged by about three times the unimplanted one. The improved low cycle fatigue life was attributed to the formation of AlN and the damaged region on the surface by $N^+$ ion implantation.

• Macromolecular Research
• /
• v.10 no.2
• /
• pp.80-84
• /
• 2002

Silver species other than the silver ion were formed by UV irradiation on polymer electrolyte membranes containing silver salts and their effect on complexation behavior between the silver and olefin was investigated through the separation performance of olefin/paraffin mixtures. The ideal propylene/propane separation factor reached 350 and the separation coefficient was ca.15 due to the high loading amount of silver ions into poly(2-ethyl-2-oxazoline) (POZ) without UV irradiation. On UV irradiation either in air or under nitrogen, the silver-POZ membranes became yellow-brown initially due to the formation of colloidal silver particles, and finally black and metal-like luster. Even when Ag$^{+}$ was converted, to some extent, to Ag$^{\circ}$ by UV irradiation in air at the early stage, the separation coefficient of olefin/paraffin mixtures was maintained. This suggests that silver species other than the silver ion is active for olefin carrier for facilitated transport. Meanwhile the steady decrease of the separation coefficient was observed in the silver/POZ membranes irradiated under $N_2$. It is suggested that the reduction of silver ions in POZ goes through a different photoreduction mechanism with UV irradiation depending on the environment.t.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.26 no.4
• /
• pp.614-621
• /
• 2002

This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston bowl shapes(F, B and R-type) in a optically accessible engine. The images of liquid and vapor phases were captured in the motoring engine using exciplex fluorescence method. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure was 5.1MPa. Two dimensional spray fluorescence image of vapor phase was acquired to analyze spray behaviors and fuel distribution inside of cylinder. Four injection timings were set at BTDC 90$^{\circ}$, 80$^{\circ}$, 70$^{\circ}$, and 60$^{\circ}$. With a fuel injection timing of BTDC 90$^{\circ}$, fuel-rich mixture level in the center region was highest in a B-type piston. With a fuel injection timing of BTDC 60$^{\circ}$, R-type piston was best. R-type piston shape was suitable under enhanced swirl ratio and late injection condition and B-type piston shape was right in a weak swirl ratio. It was found that the piston bowl shape affected the mixture stratification inside of cylinder.

• Proceedings of the KSME Conference
• /
• 2001.11b
• /
• pp.915-920
• /
• 2001

This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston bowl shapes(F, B, and R-type) in a optically accessible engine. The images of liquid and vapor phases were captured in the motoring engine using exciplex fluorescence method. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure is 5.1MPa. Two dimensional spray fluorescence image of vapor phases was acquired to analyze spray behaviors and fuel distribution inside of cylinder. Four injection timings were set at BTDC $90^{\circ},\;80^{\circ},\;70^{\circ},\;and\;60^{\circ}$. With a fuel injection timing of BTDC $90^{\circ}$, fuel-rich mixture level in the center region was highest in a B-type piston. With a fuel injection timing of BTDC $60^{\circ}$, R-type piston was best. R-type piston shape was suitable under enhanced swirl ratio and late injection condition and B-type piston shape was right in a weak swirl ratio. It was found that the piston bowl shape affected the mixture stratification inside of cylinder.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.9 no.4
• /
• pp.153-163
• /
• 2004

In order to estimate the nutrient flux of the Seomjin River into the coastal waters of South Sea, and to understand the estuarine reactions during mixing between river water and seawater, we collected surface water along the salinity gradient in the Seomjin River estuary from Mar. 1999 to Apr. 2001. We found that nitrate and silicate were delivered by fluvial input, while phosphate was, supplied from disposed wastes in the Gwangyang Bay. Mean annual flux of dissolved inorganic nitrogen (DIN), phosphate and silicate into the Gwangyang Bay was estimated 10.9 molesㆍsec$^{-1}$(4,820 tonnesㆍyr$^{-1}$), 0.07 molesㆍsec$^{-1}$(68 tonnesㆍyr$^{-1}$), 13.3 molesㆍsec$^{-1}$(11,747 tonnesㆍy$^{-1}$), respectively. An evident removal of phosphate, silicate and ammonium at the mid-salinity zone during the dry season was attributed to the active uptake of phytoplankton, and consequently nutrient flux into the Gwangyang Bay was low. Whereas, during the flood season in summer, conservative or additional distribution of the nutrients was observed in the estuary. As a rsult nutrient flux into the Gwangyang Bay was maintained high. High concentrations of chlorophyll a and the active removal of nutrient during the dry season at the mid-salinity zone suggest that nutrient distribution in the Seomjin River estuary was mainly controlled by biological processes and nutrient fluxes into the Gwangyang Bay might be significantly modified of by the primary production.

• Transactions of Materials Processing
• /
• v.20 no.7
• /
• pp.504-511
• /
• 2011

The alkaline earth metal Ba has a relatively low melting point. Because of its significantly high affinity to oxygen, nitrogen and sulfur, it is highly functional as a steel refining agent. But Ba can adversely affect the properties of steel especially the workability, because it can form a variety of inclusions. So, understanding of these inclusions is needed for improvement of the properties of steel. Thus a fundamental study in the formation behavior of non-metallic inclusions in Ba added Hyper Duplex STS melts was investigated. The amount of Ba, holding time and temperature were considered as experimental variables. The number of non-metallic inclusions decreased and the large particle size of non-metallic inclusions increased as the amount of Ba increased. The number of non-metallic inclusions also decreased and the large particle size increased with increased holding times and temperatures of molten steel.

• Proceedings of the KSME Conference
• /
• 2003.11a
• /
• pp.472-477
• /
• 2003

This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston cavity diameters in a optically accessible engine. The images of vapor phases were measured in the motoring engine using exciplex fluorescence method. The conventional engine was modified as GDI engine with swirl flow. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure is 5.1MPa. Two dimensional spray fluorescence image of vapor phases was acquired to analyze spray behavior and fuel distribution inside of cylinder. Three injection timings were set at BTDC $180^{\circ}$, $60^{\circ}$and $60^{\circ}$. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture was concentrated in near the cavity center. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture level in the center region was highest in the S-type during the late compression stroke. With a fuel injection timing of BTDC $180^{\circ}$, fuel was not affected in a piston cavity and generally distributed as homogeneous mixture.

• Journal of the Korean institute of surface engineering
• /
• v.29 no.6
• /
• pp.735-738
• /
• 1996

Amorphous nickelphthalocyanine(NiPc) thin films were prepared by vacuum evaporation and their electrochromic behavior and voltammograms were examined in the five kinds of aqueous electrolytes. Amorphous NiPc films were prepared on indium-tin-oxide(ITO) glass substrates cooled to-$120^{\circ}C$ by using liquid nitrogen under a vacuum of $2.4 \times 10^{-4}$. The voltammetric and electrochromic measurements were made using a potential galvanostat. In order to confirm the color change, optical vis-transmission spectra of the NiPc films were measured by a spectrophotometer with various electrode potential applied. The NiPc amorphous thin films exhibited most clearly electrochromism in $KNO_3$ aqueous electrolyte. The specimen films underwent 3 color transitions (from blue to yellow-green, then to red violet, then to dark blue), corresponding to the three peaks on the voltammograms in $KNO_3$ aqueous electrolyte. Blue is color of the as-prepared film. When the potential was swept, charge compensation was attained upon oxidation by injection of anions from the electrolyte and upon reduction by expulsion of anions.

• Journal of the Korean Ceramic Society
• /
• v.33 no.1
• /
• pp.83-91
• /
• 1996

Monolithic AlN and AlN-W composites were fabricated by pressure-less sintering at 190$0^{\circ}C$ under nitrogen atmosphere and the influences of tungsten phase on the microstructure and mechanical properties were investi-gated. In the fabrication of sintered specimen no additive was used. And monolithic AlN showed substantial grain growth and low relative density. AlN-W composites were fully densified and grain growths of matrix were inhibited. The densification behavior of composites were inferred to be achieved through the liquid phase sintering process such as particle-rearrangement and solutino-reprecipitation. Also the oxid phases which is expected to form liquid phases duringsintering process were detected by XRD analysis. As the tungsten volume content increases fracture strength was decreased and fracture toughness was increased. It was suppo-sed that the strength decrease of composites with tungsten content was due to existence of interface phases. The subcritical crack growth behavior was observed from the stress-strain curve of composites. The effect of the secondary phase and interface phases on toughness in crease were studied through observation of crack propagation path and the influence of residual stress on crack propagation was investigated by X-ray residual stress measurement. In the result of residual stress measurement the compressive stress of matrix in composi-test was increased with tungsten volume content and the compressive stress distribution of matrix must have contributed to the inhibition of crack propagation.