• Title/Summary/Keyword: Nitrogen analysis

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Experimental study on natural circulation using liquid nitrogen for superconducting applications

  • Choi, Yeon Suk
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.3
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    • pp.49-52
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    • 2013
  • An experiment to investigate the natural circulation of a cryogen has been performed. The study is motivated mainly by our recent development of cryogenic cooling system for prototype superconducting cyclotron without any circulating pump. In the natural circulation loop system, a cooling channel is attached on the outer surface of the aluminium block and the liquid nitrogen passes through inside of the channel to cool the block indirectly. A cryocooler as a heat sink is located at the top to re-condense cryogenic vapor coming from the aluminium block in which electrical heater is installed as a heat source. The main dimensions are determined using the relevant analysis and the natural circulation loop is successfully fabricated. The temperature distributions in the loop are measured during initial cool-down process and in steady state, from which the modified Grashof numbers are calculated and compared with the existing correlation estimated with one-dimensional analysis for steady state flow.

Preparation and Chemical Characteristics of Food Protein Hydrolysates (식품단백질 효소분해물의 제조 및 이화학적 특성)

  • Kim, Jong-Hee;Hong, Soon-Kwang
    • Journal of the East Asian Society of Dietary Life
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    • v.19 no.1
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    • pp.45-51
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    • 2009
  • In this study, food protein hydrolysates were prepared from six types of food protein: purified meat protein, whole egg protein, casein, isolated soy protein, concentrated rice protein, and gluten. Food proteins were hydrolyzed with pepsin and ethanol (80%)-soluble fractions of pepsin hydrolysates were employed for analysis. The products were colorless and odorless powders with low fat content and good solubility. The MW (molecular weight) of the protein hydrolysates was confirmed to be $200{\sim}1,800$ via gel filtration. Free amino acid contents accounted for less than 5% of the samples. The results of our amino acid analysis revealed that all food protein hydrolysates preserved their original amino acid compositions and nutritional values of their source proteins with highly pure oligopeptide mixtures. These results show that the food protein hydrolysates prepared in these investigations should prove excellent dietary nitrogen sources for a variety of applications.

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Stable Isotope Ratio Analysis for Tracing thee Major Pollution Source in Agricultural Watersheds (농촌하천 유역의 주 오염원 추적을 위한 안정성 동위원소 질량비 분석)

  • 홍영진;김철성;권순국
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1999.10c
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    • pp.777-782
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    • 1999
  • It has been acknowledged that fertilizer and animal waste have different ratio of \ulcornerN/\ulcornerN which is presented as a symbol of $\delta$\ulcornerN, and that the values of $\delta$\ulcornerN for fertilizer and animal waste are placed less than +8 $\textperthousand$ and higher than +10$\textperthousand$, respectively. By this reason, the demarcation range for the source nitrogen mass ratio is between +8$\textperthousand$ and +10$\textperthousand$. In this study, we would suggest a possible method to trace the major pollution basis using the nitrogen isotope analysis method for management of water quality.

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Analysis of Wastewater Reuse Effect on Field-Scale Water Quality (하수처리수의 농업용수 재이용에 따른 포장단위 수질영향 분석)

  • Seong, Choung-Hyun;Kim, Sung-Jae;Kim, Sung-Min;Kim, Sang-Min
    • Journal of The Korean Society of Agricultural Engineers
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    • v.53 no.4
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    • pp.59-65
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    • 2011
  • The purpose of this study was to analyze the water quality change when wastewater applied to study paddy fields. CREAMS-PADDY (Chemical, Runoff and Erosion from Agricultural Management System) model was used to estimate the field-scale water quality. Simulated results were compared with observed data monitored from Byeongjeom study paddy fields which is located near the Suwon sewage treatment plant in Gyeonggi-do. Significance analysis was performed for the three different irrigation water quality level and five fertilizer reduction scenarios using LSD (Least Significant Difference) and DMRT (Duncan's Multiple Range Test). Total nitrogen was found to be significant for both irrigation water quality level and fertilizer reduction while total phosphorus was not. Annual drainage load for total nitrogen was reduced by 66~92 % compared to irrigation load when treated wastewater irrigated to study paddy fields from 2002 to 2007. Total phosphorus was reduced by 70~86 %.

Synthesis and Characterization of Transition Metal Complexes with Benzimidazolyl-2-hydrazones of o-anisaldehyde and Furfural

  • Mohapatra, R.K.;Mishra, U.K.;Mishra, S.K.;Mahapatra, A.;Dash, D.C.
    • Journal of the Korean Chemical Society
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    • v.55 no.6
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    • pp.926-931
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    • 2011
  • A series of complexes of the type [$ML_2Cl_2$], where L=2-(o-anisylidene-2'-imino) amino benzimidazole (AIAB) and 2-(furfurylidene imino) amino benzimidazole (FIAB), M=Cu(II), Co(II), Ni(II) and Zn(II), have been synthesized and characterized on the basis of elemental analysis, thermal analysis, molar conductivity, magnetic moment, electronic, infrared, $^1H$-NMR spectral studies. The results are in consistent with bidentate chelation of ligand with azomethine nitrogen and ring nitrogen donors. All these Schiff bases and their complexes have also been screened for their antibacterial (Bacillus subtilis, Bacillus stearothermophilus, Escherichia coli and Salmonella typhi) and antifungal activities (Aspergillus niger and Aspergillus flavus).

Optimal condition for efficient DNA transfer in filamentous cyanobacteria by electroporation

  • Poo, Ha-Ryoung
    • Journal of Microbiology
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    • v.35 no.3
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    • pp.181-187
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    • 1997
  • Filamentous cyanobacteria are an ecologically important group of bacteria because they are able to provide both organic carbon fixed nitrogen that can support the nutritional requirements for other microorganisms. Because of their prokaryotic nature, they can also be used as potentially powerful model systems for the analysis of oxygenic photosynthesis and nitrogen fixation. Gene transfer is an indispensable procedure for genetic analysis of filamentous cyanobacteria. Electroporation was used to introduce foreign DNA into cyanobacterial cells. In experiments designed to optimize the electroporation technique, the effects of the field strength (amplitude of pulse) and time constant (duration of pulse), DNA concentration and host restriction/modification of DNA on the efficiency of electro-transformation were investigated. The results of this research revelaed that a high voltage pulse of short duration was effective for the electro-transformation of Anabaene sp. M131. The maximal number of transformants was obtained at 6 kV/cm with a pulse duration of 5 msec. The efficiency of electro-transformation was also sensitive to concenetration of DNA; even small amounts of DNA (0.01 .mu.g/ml) were able to gie a large number of transformants (1.0 * 10$\^$3/ cfu/ml).

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Characteristics of the NO/$N_2O$ Nitrided Oxide and Reoxidized Nitrided Oxide for NVSM (비휘발성 기억소자를 위한 NO/$N_2O$ 질화산화막과 재산화 질화산화막의 특성에 관한 연구)

  • 이상은;서춘원;서광열
    • Journal of the Korean Vacuum Society
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    • v.10 no.3
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    • pp.328-334
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    • 2001
  • The characteristics of $NO/N_2O$ nitrided oxide and reoxidized nitrided oxide being studied as super thin gate oxide and gate dielectric layers of nonvolatile semiconductor memory(NVSM) was investigated by dynamic secondary ion mass spectrometry(D-SMS), time-of-flight secondary ion mass spectrometry(ToF-SIMS), and x-ray photoelectron spectroscopy (XPS). The specimen was annealed in $NO/N_2O$ ambient after initial oxide process. The result of D-SIMS exhibits that the center of nitrogen exists at the initial oxide interface and the distribution of nitrogen is wider in the annealing process with $N_2O$ than with NO annealing process. For investigating the condition of nitrogen that exists within the nitrided oxide, ToF-SIMS and XPS analysis were carried out. It was shown that the center of nitrogen investigated by D-SIMS was expected the SiON chemical bonds. The nitrogen near the newly formed reoxide/silicon substrate interface was appeared as $Si_2NO$ chemical bonds, and it is agreed with the distribution of SiN and $Si_2NO$ species by ToF-SIMS.

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Nitrogen Dynamics and Growing of Shrimp (Fenneropenaeus chinensis) in the High Density Aquaculture Ponds (고밀도 축제식 양식장의 질소역학과 대하 (Fenneropenaeus chinensis) 성장)

  • KANG Yun Ho;YOON Yang Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.37 no.1
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    • pp.24-32
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    • 2004
  • A mathematical model is used to investigate nitrogen dynamics in the intensive aquaculture ponds in the western coast of Korea. Parameters associated with water quality, sediments and growing of shrimp (Fenneropenaeus chinensis) are measured to calibrate the model for feeding ponds A and B and storage ponds. The model describes the fate of nitrogen including loadings of ammonia from feeds, phytoplankton assimilation, nitrification, sedimentation, volatilization and discharge. The model obtains good agreements with the measured values of TAN $(NH_4,\;NH_3),\;NO(NO_2,\;NO_3)$ and Chl (chlorophyll a). Impacts of water exchange on TAN and Chl are investigated, showing that the range of 0.01-0.2 (/day) cannot effectively reduce TAN but reduces Chl. Nitrogen in the ponds A is removed by sedimentation $66\%,$ volatilization $8\%,$ discharge of particulate and dissolved $8\%.$ The pond B shows $56\%\;and\;26\%$ of sedimentation and volatilization, respectively, to yield $10\%.$ decrease and 8c/o increase compared to those in the pond A. While the pond A has larger area (1.02:0.66 ha) and same stocking density (0.025 md./L) at the beginning of culture, the pond B obtains higher stocking density (0.0065:0.0091 md./L), longer feeding period (103:121 day) and resultant higher shrimp production (1.15:2.13 t/ha/cycle) at harvest. This is possibly due to the hydraulic characteristics driven by paddlewheels. At low ratio of the low speed area and the pond area, the rate of sedimentation is high, while the rate of gas exchange is low. Thus, the measurement and model analysis suggest that water quality and shrimp production are positively correlated with the hydraulic characteristics in the shrimp ponds.

Structure of Bacterial Communities in Biological Nitrogen Removal System (Biological Nitrogen Removal System의 세균 군집 분석)

  • Kim, Kyung-Mi;Lee, Sang-Ill;Lee, Dong-Hun
    • Korean Journal of Microbiology
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    • v.42 no.1
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    • pp.26-33
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    • 2006
  • To understand the efficient process of biological nitrogen removal (BNR) system, the structure of bacterial communities in nitrification reactors was analyzed using PCR and terminal restriction fragment length poly morphism (I-RFLP) methods. In this study, we used an advanced treatment system with plotting media, Nutrient Removal Laboratory system, or the rumination type sequencing batch reactor (SBR) system. The terminal restriction fragments of ammonia-oxidizing bacteria (AOB) and other $\beta-proteobacteria$ were observed in all of three BNR systems. The nucleotide sequence analysis of terminal restriction fragments showed that Nitrosomonas and Nitrosolobus were major populations of AOB in SBR system, whereas uncultured $\beta-proteobacteria$ and Cardococcus australiensis were the predominant groups in other two BNR systems. Also the SBR system may be more efficient to enrich AOB. These results indicate that the different structure of bacterial community may be developed depending on the wastewater treatment systems, although the same influent is used.

Effect of the SBA-15 template and KOH activation method on CO2 adsorption by N-doped polypyrrole-based porous carbons

  • Yuan, Hui;Jin, Biao;Meng, Long-Yue
    • Carbon letters
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    • v.28
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    • pp.116-120
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    • 2018
  • Nitrogen-doped carbons have attracted much attention due to their novel application in relation to gas storage. In this study, nitrogen-doped porous carbons were synthesized using SBA-15 as a template, polypyrrole as the carbon and nitrogen precursor, and KOH as an activating agent. The effect of the activation temperature ($600-850^{\circ}C$) on the $CO_2$ adsorption capacity of the obtained porous carbons was studied. Characterization of the resulting carbons showed that they were micro-/meso-porous carbon materials with a well-developed pore structure that varied with the activation temperature. The highest surface area of $1488m^2g^{-1}$ was achieved at an activation temperature of $800^{\circ}C$ (AC-800). The nitrogen content of the activated carbon decreased from 4.74 to 1.39 wt% with an increase in the activation temperature from 600 to $850^{\circ}C$. This shows that nitrogen is oxidized and more easily removed than carbon during the activation process, which indicates that C-N bonds are more easily ruptured at higher temperatures. Furthermore, $CO_2$ adsorption isotherms showed that AC-800 exhibited the best $CO_2$ adsorption capacity of $110mg\;g^{-1}$ at 298 K and 1 bar.