• Title/Summary/Keyword: Nitrogen analysis

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Nitrite Accumulation Characteristics and Quantitative Analyses of Nitrifying and Denitrifying Bacteria in a Sequencing Batch Reactor (연속회분반응기의 아질산 축적 특성과 질산화 및 탈질 미생물의 정량적 분포 연구)

  • Kim, Dong-Jin;Kwon, Hyun-Jin;Yoon, Jung-Yee;Cha, Gi-Cheol
    • Journal of Korean Society on Water Environment
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    • v.24 no.3
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    • pp.383-390
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    • 2008
  • Recently, the interests on economical nitrogen removal from wastewater are growing. As a method of the novel nitrogen removal technology, nitrogen removal via nitrite pathway by selective inhibition of free ammonia and free nitrous acid on nitrite oxidizing bacteria have been intensively studied. The inhibition effects of free ammonia and free nitrous acid are low when domestic wastewater is used, however, because of its relatively lower nitrogen concentration than the wastewater from industry and landfill, etc. In this study, a sequencing batch reactor (SBR) is proposed for nitrogen removal to investigate the effect of the low nitrogen concentration on nitrite accumulation. Nitrification efficiency reached almost 100% during the aerobic cycle and the maximum specific nitrification rate ($V_{max,nit}$) reached $17.8mg\;NH_4{^+}-N/g\;MLVSS{\bullet}h$. During the anoxic cycle, average denitrification efficiency reached 87% and the maximum specific denitrification rate ($V_{max,den}$) reached $9.8mg\;NO_3{^-}-N/g\;MLVSS{\bullet}h$. From the analysis the main reason of nitrite accumulation in the SBR was free nitrous acid rather than free ammonia. Nitrite accumulation increased with the decrease of organic content in the wastewater and the mechanism is not well understood yet. From the result of fluorescent in situ hybridization, the distribution of nitrite oxidizing bacteria was in equilibrium with ammonium oxidizing bacteria when nitrite accumulation did not occur.

Monitoring Nutritional Status of Dairy Cows in Taiwan Using Milk Protein and Milk Urea Nitrogen

  • Hwang, Sen-Yuan;Lee, Mei-Ju;Chiou, Peter Wen-Shyg
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.12
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    • pp.1667-1673
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    • 2000
  • The climate and marketing system of raw milk in Taiwan create problems in balance feeding of protein and energy in lactating cows in Taiwan. Level of urea nitrogen both in bulk milk and serum reflects ruminal protein degradation and post-ruminal protein provision, whereas milk protein concentration responds to dietary energy intake and bacterial protein production in the rumen. Establishment of a range of reference standards in milk protein and urea nitrogen levels can be applied as a noninvasive economical feeding guide to monitor the balance of protein and energy intake. Standard reference levels of 3.0% milk protein and 11-17 mg/dL milk urea nitrogen (MUN) were established. Level of milk protein below 3.0% is regarded as indicating inadequate dietary energy whereas MUN below or above the range is regarded as a deficiency or surplus in dietary protein. Results from analysis of bulk a milk samples collected from 174 dairy herds over Taiwan showed that only one quarter (25.29%) of the herds received a balanced intake of protein and energy, 33.33% adequate protein with energy inadequate, 22.99% herds in protein surplus with energy inadequate, 10.35% herds in protein surplus with energy adequate, 4.6% protein deficiency with energy adequate, and 3.45% herds with both protein and energy inadequate. Energy inadequate herds accounted for 60% of the total dairy herds in Taiwan with 56% adequate, 38% surplus and 6% inadequate in protein. In comparing milk sampled from bulk milk on different seasons from Lee-Kang area in the southern Taiwan, the concentrations of milk fat and milk protein were significantly higher in the cool season (February) than in the warm season (August) (p<0.05), whereas the urea nitrogen in the milk was significantly lower in the cool season than in the warm season (p<0.05). This indicated that lactating cows had excess protein and/or inadequate energy intake in the warm season in this area. It appears that the major problem feeding in lactating cows is energy intake shortage, especially during the warm season in Taiwan.

A Study on the Memory Trap Analysis and Programming Characteristics of Reoxidized Nitrided Oxide (재산화 질화산화막의 기억트랩 분석과 프로그래밍 특성)

  • Nam, Dong-Woo;An, Ho-Myung;Han, Tae-Hyun;Seo, Kwang-Yell;Lee, Sang-Eun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.17-20
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    • 2001
  • Nonvolatile semiconductor memory devices with reoxidized nitrided oxide(RONO) gate dielectrics were fabricated, and nitrogen distribution and bonding species which contribute to memory characteristics were analyzed. Also, memory characteristics of devices depending on the anneal temperatures were investigated. The devices were fabricated by retrograde twin well CMOS processes with $0.35{\mu}m$ Nonvolatile semiconductor memory devices with reoxidized nitrided oxide(RONO) gate dielectric were fabricated, and nitrogen distribution and bonding species which contributing memory characteristics were analyzed. Also, memory characteristics of devices according to anneal temperatures were investigated. The devices were fabricated by $0.35{\mu}m$ retrograde twin well CMOS processes. The processes could be simple by in-situ process of nitridation anneal and reoxidation. The nitrogen distribution and bonding state of gate dielectric were investigated by Dynamic Secondary Ion Mass Spectrometry(D-SIMS), Time-of-Flight Secondary Ion Mass Spectrometry(ToF-SIMS), and X-ray Photoelectron Spectroscopy(XPS). Nitrogen concentrations are proportional to nitridation anneal temperatures and the more time was required to form the same reoxidized layer thickness. ToF-SIMS results show that SiON species are detected at the initial oxide interface and $Si_{2}NO$ species near the new $Si-SiO_{2}$ interface that formed after reoxidation. As the anneal temperatures increased, the device showed worse retention and degradation properties. These could be said that nitrogen concentration near initial interface is limited to a certain quantity, so excess nitrogen are redistributed near the $Si-SiO_{2}$ interface and contributed to electron trap generation.

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Changes in Taste Characteristics of Traditional Korean Soy Sauce with Ripening Period - Analysis of Nitrogen Compound Contents and Sensory Characteristics - (숙성 기간에 따른 전통 간장의 맛 특성 변화(II) - 질소 화합물 분석 및 관능 특성 -)

  • Joo, Myoung-Sook;Sohn, Kyung-Hee;Park, Hyun-Kyung
    • Journal of the Korean Society of Food Culture
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    • v.12 no.4
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    • pp.383-389
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    • 1997
  • This study was carried out in order to analyze the changes in nitrogen containing taste compounds of traditional Korean soy sauce with varying Meju concentrations (Meju-water ratios of 1:4 and 1.3:4) and ripening periods (up to 2 years), and to investigate correlation between sensory characteristics and taste compound contents via contents assay and sensory evaluation of soy sauce samples. Nitrogen compound contents were higher in 1.3:4 than in 1:4 for all nitrogen compounds. Free amino acid contents were highest in soy sauce ripened for 210 days. Among amino acids, glutamic acid was highest concentration. Nucleotides and their related compound contents did not vary with concentrations and were highest in the sample ripened for 210 days. In direct sensory evaluation of soy sauce, overall taste preference showed positive correlation to sweet taste. Likewise, overall taste preference showed positive correlation to umami, nutty, sweet taste in the sensory evaluation of seaweed soup seasoned with soy sauce. Sensory evaluation score was higher in 1.3:4 than in 1:4. According to the correlation assay of taste compound contents and sensory evaluations, nitrogen compounds (such as amino type nitrogen), amino acids (such as glutamic acid, aspartic acid, and lysine, and etc.), nucleotides (such as AMP, IMP, and etc) had significant influence on the sensory characteristics of soy sauce, and therefore we can conclude that these compounds affect the taste and quality of soy sauce.

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Nitrogen Dilution Effects on Liftoff Flame Stability in Non-premixed Turbulent Hydrogen Jet with Coaxial Air (질소희석이 부상된 수소 난류확산화염의 화염안정성에 미치는 영향)

  • Oh, Jeong-Seog;Yoon, Young-Bin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.393-396
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    • 2008
  • The study of nitrogen dilution effect on flame stability was experimentally investigated in non-premixed turbulent lifted hydrogen jet with coaxial air. hydrogen gas was used as a fuel and coaxial air was injected to make flame liftoff. And both of the fuel jet and coaxial air velocity were fixed as $u_F$=200 m/s and $u_A$=16 m/s, while nitrogen diluents mole fraction was varied from 0 to 0.2. For the analysis of flame structure and flame stabilization mechanism, the simultaneous measurement of PIV/OH PLIF had been performed. It was found that the turbulent flame propagation velocity increased as decreasing of nitrogen mole fraction. We concluded that the turbulent flame propagation velocity was expressed as a function of turbulent intensity, even though the mole fraction of nitrogen diluents gas was changed.

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Assessment of Nitrogen Impaction on Watershed by Rice Cultivation (벼농사에서 질소유출이 수질에 미치는 영향평가)

  • Roh, Kee-An;Kim, Min-Kyeong;Lee, Byeong-Mo;Lee, Nam-Jong;Seo, Myung-Chul;Koh, Mun-Hwan
    • Korean Journal of Environmental Agriculture
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    • v.24 no.3
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    • pp.270-279
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    • 2005
  • It is important to understand and evaluate the environmental impacts of rice cultivation for developing environmentally-friendly agriculture because rice is main crop in Korea and rice cultivation have both functions of water pollution and purification with environmental and cultivation conditions. This paper presents the evaluation of nitrogen impact by rice cultivation on water system. A simple protocol was proposed to assess the potential amount of nitrogen outflow from paddy field and most of parameters affect on the nitrogen outflow from paddy field such as the amount of fertilizer application, water balance, the quality and quantity of irrigation water, soil properties, nitrogen turnover in the soil and cultivation method were considered. To develop the protocol, coefficients for parameters affected nitrogen turnover and outflow were gotten and summarized by comparison and analysis of all possible references related, and by additional experiments at field and laboratory. And potential amount of nitrogen input and output by water in paddy field were estimated with the protocol at the conditions of the nitrogen contents of irrigation water, amount of fertilizer application, and irrigation methods. Where irrigation water was clean, below 1.0 mg $L^{-1}$ of nitrogen concentration, rice cultivation polluted nearby watershed. At the conditions of 2.0 mg $L^{-1}$ of nitrogen concentration, 110 kg $ha^{-1}$ of nitrogen fertilizer application and flooding irrigation, rice cultivation had water pollution function, but it had water purification function with intermittent irrigation. At the conditions of 3.0 mg $L^{-1}$ of nitrogen concentration and 110 kg $ha^{-1}$ of nitrogen fertilizer application, rice cultivation had water purification function, but that had water pollution function with 120 kg $ha^{-1}$ of nitrogen application. Where irrigation water was polluted over 6.0 mg $L^{-1}$ of nitrogen, it was evaluated that rice cultivation had water purifying effect, even though the amount of nitrogen application was 120 kg $ha^{-1}$.

Comparison Study of Nitrogen Dioxide and Asthma Doctor's Diagnosis in Seoul - Base on Community Health Survey 2012~2013 - (서울시 대기 중 이산화질소 농도와 천식증상의 비교 연구 - 2012~2013년 지역사회건강조사 자료를 중심으로 -)

  • Lee, Sang-Gyu;Lee, Yong-Jin;Lim, Young-Wook;Kim, Jung-Su;Shin, Dong-Chun
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.575-582
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    • 2016
  • Seoul city has high population density as well as high traffic congestion, which are vulnerable to exposure of environmental pollutions caused by car traffic. However, recent studies are only on local regions about road traffic and air pollution or health effect of road traffic on residents. Thus, comprehensive study data are needed in terms of overall Seoul regions. In this study utilized the nitrogen dioxide concentration through the national air pollution monitoring network data, 2012 to 2013. It also divided regions into high and low exposure districts via the Origin destination data developed by the Korea transport institute to quantify and evaluate the effect of transport policies and analyzed a correlation of asthma symptoms with high and low exposure districts through raw data of community health survey from the Korea centers for disease control and prevention. Based on the collected data, the pearson's correlation analysis was conducted between air pollution substance concentration and high exposure district and multiple logistic regression analysis was conducted to determine the effect of traffic environment and factors on asthma symptoms of residents. Accordingly, the following results were derived. First, the high exposure district was higher concentrations of nitrogen dioxide ($NO_2$) as per time compared to those of the low exposure district (p<0.01). Second, analysis on correlation between average daily environmental concentration in the air pollution monitoring network and road traffic showed that nitrogen dioxide had a significant positive correlation (p<0.01) with car traffic and total traffic as well as with truck traffic (p<0.05) statistically. Third, an adjusted odds ratio about asthma doctor's diagnosis in the high and low exposure districts was analyzed through the logistic regression analysis. With regard to an adjusted model 2 (adjusted gender, age, health behavior characteristics, and demographic characteristics) odds ratio of asthma doctor's diagnosis in the high exposure district was 1.624 (95% CI: 1.269~2.077) compared to that of the low exposure district, which was significant statistically (p<0.001).

Analysis on Food Waste Compost by Near Infrared Reflectance Spectroscopy(NIRS) (Near Infrared Reflectance Spectroscopy(NIRS)에 의한 음식물 쓰레기 퇴비 분석에 관한 연구)

  • Lee Hyo-Won;Kil Dong-Yong
    • Korean Journal of Organic Agriculture
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    • v.13 no.3
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    • pp.281-289
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    • 2005
  • In order to find out an alternative way of analysis of food waste compost, the Near Infrared Reflectance Spectroscopy(NIRS) was used for the compost assessment because the technics has been known as non-detructive, cost-effective and rapid method. One hundred thirty six compost samples were collected from Incheon food waste compost factory at Namdong Indurial Complex. The samples were analyzed for nitrogen, organic matter (OM), ash, P, and K using Kjedahl, ignition method, and acid extraction with spectrophotometer, respectively. The samples were scanned using FOSS NIRSystem of Model 6500 scanning mono-chromator with wavelength from $400\~2,400nm$ at 2nm interval. Modified partial Least Squares(MPLS) was applied to develop the most reliable calibration model between NIR spectra and sample components such as nitrogen, ash, OM, P, and K. The regression was validated using validation set(n=30). Multiple correlation coefficient($R^2$) and standard error of prediction(SEP) for nitrogen, ash, organic matter, OM/N ratio, P and K were 0.87, 0.06, 0.72, 1.07, 0.68, 1.05, 0.89, 0.31, 0.77, 0.06, and 0.64, 0.07, respectively. The results of this experiment indicates that NIRS is reliable analytical method to assess some components of feed waste compost, also suggests that feasibility of NIRS can be Justified in case of various sample collection around the year.

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