• Title/Summary/Keyword: Nitrogen Oxides

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Effect of Engine Operating Conditions on Combustion and Exhaust Emission Characteristics of a Gasoline Direct Injection(GDI) Engine Fueled with Bio-ethanol (직접분사식 가솔린엔진에서 운전조건에 따른 바이오에탄올의 연소 및 배기배출물 특성)

  • Yoon, Seung Hyun;Park, Su Han
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.7
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    • pp.609-615
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    • 2015
  • In this study, the combustion and exhaust emission characteristics in a gasoline direct injection engine with variations of the bio-ethanol-gasoline blending ratio and the excess air factor were investigated. To investigate the effects of the excess air factor and the bio-ethanol blends with gasoline, combustion characteristics such as the in-cylinder combustion pressure, rate of heat release (ROHR), and the fuel consumption rate were analyzed. The reduction of exhaust emissions such as carbon monoxide (CO), unburned hydrocarbon (HC), and nitrogen oxides ($NO_x$) were compared with those of gasoline fuel with various excess air factors. The results showed that the peak combustion pressure and ROHR of bio-ethanol blends were slightly higher and were increased as bio-ethanol blending ratio is increased. Brake specific fuel consumption increased for a higher bio-ethanol blending ratio. The exhaust emissions decreased as the bio-ethanol blending ratio increased under all experimental conditions. The exhaust emissions of bio-ethanol fuels were lower than those of gasoline.

Detailed Local Chemiluminescence Measurement (OH*, CH* and C2*) and Nitrogen Oxides Emissions in Laminar Partially Premixed CH4/Air Flames (메탄/공기 층류 부분예혼합화염의 상세 라디칼(OH*, CH* 그리고 C2*) 정보와 배기매출물에 관한 실험적 연구)

  • Jeong Yong Ki;Oh Jeong Seog;Jeon Chung Hwan;Chang Young June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.2 s.233
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    • pp.263-270
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    • 2005
  • An experimental study was performed to investigate the effects of partially premixing, varying the equivalence ratios from $0.79{\sim}{\infty}$, on NOx emissions and chemiluminescence of excited $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ radicals in laminar partially premixed flames. the signal from the electronically excited state of $OH^{\ast},\;CH^{ast}\;C_2^{\ast}$ was detected through a band pass filter with a photo multiplier tube, which are processed to the intensity ratio ($C_2^{\ast}/CH^{\ast},\;C_2^{\ast}/OH^{\ast},\;and\;CH^{\ast}/OH^{\ast}$) to reveal the correlation with local equivalence ratio. And measurements of NOx emission were made to investigate the relationship between visible flame appearance, chemiluminescence, and EINOX. The results demonstrated that (1) the flames at ${\phi}<1.59$ exhibited classical double flame structure, at ${\phi}>4.76$, the flames exhibited diffusion flame structure, and the intermediate flames at $1.59<{\phi}<4.76$ was a merged flame, (2) the $OH^{\ast}$ peak was located inside the $CH^{\ast}\;and\;C_2^{\ast}$ radical for all measured conditions and the emission intensity ratio of $C_2^{\ast}/CH^{\ast}\;and\;C_2^{\ast}/OH^{\ast}$ were identified as good marker for local equivalence ratio over a range of ${\phi}=0.79{\sim}1.2\;and\;CH^{\ast}/OH^{\ast}\;is\;0.79<{\phi}<1.9$. However, it was difficult to predict the equivalence ratio in partially premixed flames using this system for ${\phi}>2.38$, (3) the minimum NOX emission index (EINOx) is obtained for a equivalence ratio of 3.19 in the intermediate flames.

Improvement in Reduction Performance of LNT-Catalyst System with Micro-Reformer in Diesel Engine (연료 개질장치의 적용에 따른 디젤 LNT 환원성능 개선 특성)

  • Park, Cheol-Woong;Kim, Chang-Gi;Kim, Kwan-Tae;Lee, Dae-Hoon;Song, Young-Hoon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.7
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    • pp.689-696
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    • 2010
  • The Because of its high thermal efficiency, the direct injection (DI) diesel engine has emerged as a promising potential candidate in the field of transportation. However, the amount of nitrogen oxides ($NO_x$) increases in the local high-temperature regions and that of particulate matter (PM) increases in the diffusion flame region during diesel combustion. In the de-$NO_x$ system the Lean $NO_x$ Trap (LNT) catalyst is used, which absorbs $NO_x$ under lean exhaust gas conditions and releases it in rich conditions. This technology can provide a high $NO_x$-conversion efficiency, but the right amount of reducing agent should be supplied to the catalytic converter at the right time. In this research, the emission characteristics of a diesel engine equipped with a micro-reformer that acts as a reductants-supplying equipment were investigated using an LNT system, and the effects of the exhaust-gas temperature were also studied.

Effects of Biodiesel Fuel on Characteristics of Specific Fuel Consumption and Exhaust Emissions in DJ Diesel Engine;Using Rape Oil (직접분사식 디젤기관에서 연료소비율 및 배기배출물 특성에 미치는 바이오디젤유의 영향;유채유를 중심으로)

  • Lim, J.K.;Choe, S.Y.;Cho, S.G.
    • Proceedings of KOSOMES biannual meeting
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    • 2007.11a
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    • pp.133-137
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    • 2007
  • An experimental study is conducted to evaluate and compare the use of BiodieseDI Fuel supplements at blend ratio of 10/90(BDF10) and 20/80(BDF20), in four stroke, direct injection diesel engine located at the authors' laboratory. especially this Biodiesel is produced from Rape oil at the authors' laboratory. The tests are conducted using each of the above fuel blends, in the engine working at a speed of 1800rpm and at a various loads. In each test, specific fuel consumption, exhaust emissions such as nitrogen oxides(NOx), carbon monoxide(CO) and Soot are measured. The results of investigation at various operating conditions are as follows (1) Specific fuel consumption is increased average 1.52%, maximum 1.84% at load 25% in case of BDF10, and average 1.98%, maximum 2.80% at load 25% in case of BDF20. (2) CO emission is decreased average 5.14%, maximum 6.09% at load 0% in case of BDF10, and average 7.75%, maximum 9.13% at load 0% in case of BDF 20. (3) NOx emission is increased average 2.97%, maximum 3.74% at load 0% in case of BDF10, and average 3.84%, maximum 4.67% at load 0% in case of BDF20. (4) Soot emission is decreased average 9.36%, maximum 10.85% at load 75% in case of BDF10, and average 11.99%, maximum 13.95% at load 75% in case of BDF20.

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A Study on High Efficiency Power Conditioning System for Safety Operation of PEMFC_type Fuel Cell Generation System (고분자전해질형 연료전지 발전시스템의 안전운전을 위한 고성능 전력변환기에 관한 연구)

  • Kwak Dong-Kurl
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.1 s.38
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    • pp.57-61
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    • 2006
  • Fuel cells are direct current (DC) power generators. They generate electricity through an electrochemical process that converts the energy stored in a fuel directly into electricity. Fuel cells have many benefits, which produce no particulate matter, nitrogen or sulfur oxides. And they have few moving parts and produce little or no noise. When fueled by hydrogen, they yield only heat and water as byproducts. Their wide application can reduce our dependence on fossil fuels and foreign sources of petroleum. This paper is studied on a high efficiency power conditioning system (PCS) applied to the proton exchange membrane fuel cell (PEMFC) generation system. This paper is designed to a novel PCS circuit topology of high efficiency. Some experimental results of the proposed PCS is confirmed to the validity of the analytical results.

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Comparative Reaction Characteristics of Methane Selective Catalytic Reduction with CO Generation Effect in the N2O Decomposition over Mixed Metal Oxide Catalysts (MMO 촉매 하에서 N2O 분해에 대한 메탄 SCR 반응 및 CO 생성 효과의 비교 연구)

  • Park, Sun Joo;Park, Yong Sung
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.624-628
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    • 2008
  • Nitrous oxide ($N_2O$), known as one of the major greenhouse gases, is an important component of the earth's atmosphere, and gives rise to precursor of acid rain and photochemical smog. For the removal of $N_2O$ and other nitrogen oxides, the SCR reaction system with various reductants is widely used. This study is based on the results of experimental and theoretical examinations on the catalytic decomposition of sole nitrous oxide ($N_2O$) and selective catalytic reduction of $N_2O$ with $CH_4$ in the presence of oxygen using mixed metal oxide catalysts obtained from hydrolatcite-type precursors. When $CH_4$ is fed together with a reductant, it affects positively on the $N_2O$ decomposition activity. At an optimum ratio of $CH_4$ to $O_2$ mole ratio, the $N_2O$ conversion activity is enhanced on the SCR reaction with partial oxidation of methane.

Study of the cap-and-trade system against the air pollutants in the Seoul Metropolitan Area and suggestion for its enforcement throughout South Korea (수도권 대기오염물질 배출권거래제에 대한 고찰 및 총량제 확대 시행을 위한 제언)

  • Park, Min Ha;Kim, Yong Pyo
    • Particle and aerosol research
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    • v.15 no.4
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    • pp.159-171
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    • 2019
  • The cap-and-trade system against the air pollutants in the Seoul Metropolitan Area (SMA), Korea has been implemented since 2008 and will be implemented other areas in Korea on 2020. In this study, to identify the outcome and effectiveness of the cap-and-trade system in the SMA, (1) the rate of change for NOx and SOx emissions, (2) differences between the real emission and allocated amount, and (3) the status of trading are reviewed. It was found that the NOx and SOx emissions from the sources under the cap-and-trade system decreased in the SMA but the reduction was mainly due to the reduction of fuel usage not related to the system. It was found that the average percentage of annual emission in the SMA to the allocated amount between 2008 and 2018 was 66.9% for NOx and 69.3% for SOx, respectively. It suggests that there was over allocation of the emission amounts. The average trading prices in the SMA were 0.193 $/kg for NOx and 0.128 $/kg for SOx, far lower than those in RECLAIM, 131.942 $/kg and 81.677 $/kg, respectively. It was suggested that (1) the cap system for NOx and SOx emissions should be implemented only for the area with high emission ratio from large point sources, (2) the trade system is not suitable for the effective implementation of the cap system, and (3) Korean government should not allow over allocation in order to ensure sound market function without delaying the introduction of technology.

Selection of Factors for Performance Optimization on Non-esterified Bio-diesel Fuel Using Fractional Factorial Design (부분요인배치법을 이용한 비에스테르화 바이오 디젤유의 성능 최적화를 위한 인자 선정)

  • Jung, Sukho;Koh, Daekwon
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.1
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    • pp.8-12
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    • 2015
  • Non-esterified bio-diesel fuel saves cost by no esterified process and its performance was more similar to diesel oil than esterified bio-diesel fuel when the fuel blended 95% diesel oil and 5% it was used on diesel engine with electronic control system. A performance optimization is necessary for application of non-esterified bio-diesel fuel blended with diesel oil 95% on the latest diesel engine. In this study, test using fractional factorial design was accomplished at 25% and 50% partial load in order to evaluate influence of controllable 6 factors on responses such as specific fuel consumption, nitrogen oxides and coefficiency of variation of indicated mean effective pressure as basic experiment for performance optimization of this fuel. It is cleared that the injection timing and common rail pressure of 6 factors are mainly effective and its effect level is different according to load.

A study of Stability of Emulsion Fuel (에멀젼 연료의 안정성에 대한 연구)

  • Kim, Moon-Chan
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.5
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    • pp.1330-1343
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    • 2020
  • In this study, emulsion fuel which contained water of 10 ~ 20% was prepared mixed with water and MDO(Marine Diesel Oil) which largely used in near sea. Diffusion stability of emulsion fuel was measured. Diffusion stability was measured at 30℃, 45℃, and 60℃ for 10 days respectively. The stability of the emulsion fuel was stabilized in the order of MDO-10 > MDO-13 > MDO-16 > MDO-20 and it means that the stability of the emulsion fuel was found to be stable in the order of low water content. Meanwhile, an engine dynamo-meter was used to test whether the manufactured emulsion fuel was actually available in the engine. The emulsified MDO emulsion fuel could be used as fuel for ships. For samples with more than 16% water added emulsion fuel, smoke was reduced by more than 50% in the load area of more than 50%, and nitrogen oxides were reduced by 20%.

Analysis of Relationship between O3, NO, and NO2 in Riyadh, Saudi Arabia

  • Shareef, Mohammed Mujtaba;Husain, Tahir;Alharbi, Bader
    • Asian Journal of Atmospheric Environment
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    • v.12 no.1
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    • pp.17-29
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    • 2018
  • For the first time in the city of Riyadh, the formation of $O_3$ and its relationship with NO and $NO_2$ ($NO_x$) was investigated. Throughout the summer $O_3$, NO, and $NO_2$ were collected from three locations: residential, industrial, and rural areas. During the sampling period $O_3$ concentrations exceeded 1-hour local standards a few times yet remained consistent with the standards most of the time. The $O_3$ concentrations were observed highest in the rural location and lowest in the industrial area. The diurnal variation of NO followed a double peak: one in the morning and the other in the evening, representing the traffic pattern. Early morning NO peaks were observed in the rural location, which were attributed to the movement of NO from other locations. The $O_3$ concentrations depicted typical pattern, increasing after sunrise and reaching its maximum during midday. The highest $O_3$ concentrations were observed in the rural location followed by the residential and industrial. $NO_2$ photolysis rates were 3-4 times higher compared to other similar investigations, potentially due to intense solar radiation. A strong negative correlation was observed between $NO_x$ and $O_3$ values in the industrial location indicating photochemical activities around the industrial area were higher, likely due to additional $NO_x$ emissions from industries. Regression analysis of $NO_x$ and OX ($O_3+NO_2$) indicated that in residential and industrial locations at nighttime there were large $NO_x$ independent regional contributions which is attributed to VOCs. The Weekend Effect was observed in the city potentially due to the production of the OH radical and subsequent reactions with VOCs implying that the area is VOC-sensitive.