• Journal of Korean Society of Water and Wastewater
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• v.26 no.4
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• pp.579-589
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• 2012

To reduce extensive energy costs of the internal recycling for the purpose of denitrification in the advanced wastewater treatment, a post-treatment process using an electro-coagulation to treat nitrate in the secondary effluents is evaluated in this study. Removals of phosphorus and organics in the secondary effluents by the electro-coagulation were also evaluated to propose an alternative advanced wastewatert treatment process. A series of experiments of the electro-coagulation were carried out with the following 4 different samples: synthetic solution containing nitrate only, synthetic solution containing nitrate as well as phosphorus, secondary effluents from activated sludge cultivated in laboratory, and secondary effluents from real wastewater treatment plants. Removals of nitrate and phosphorus in the synthetic solution were 30 and 97 % respectively, which verified the feasibility of the process. Removals of nitrate, phosphorus and COD in the secondary effluents from the cultivated sludge in laboratory were 49, 90 and 19 % respectively. Removal efficiency of the total nitrogen, nitrrate, phosphorus and COD in the secondary effluent from real wastewater treatment plant were 50, 61, 98 and 80 % respectively. The removal of the total nitrogen was less than the nitrate as expected, which is due to the formation of ammonia nitrogen in the cathode. But the proposed scheme could be an energy saving and alternative process for the advanced wastewater treatment if further studies for the process optimization are carried out.

• Journal of environmental and Sanitary engineering
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• v.20 no.2 s.56
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• pp.12-20
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• 2005

Most of sewage treatment plants in Korea is operated for the removal of organic material. Because of low C/N ratio of domestic wastewater it is very difficult to remove nitrogen and phosphorus from wastewater. Therefore C/N ratio is key factor for the removed of nitrogen and phosphorus. PSB(photosynthetic bacteria) can remove the nutrient materials, so this study is focused on PSB characterization of nutrient removal. PSB is possible to remove nitrogen, phosphorus in anaerobic and aerobic condition. This study try to find out condition of the PSB in SBR reactor, Batch reactor. It consists of three Mode. Mode 1, 2 is to apply activated sludge process and Mode 3 is that seeded PSB in the activated sludge process. As a result of SBR process, Mode 1, 2 which was activated sludge Process showed $79\~90\%,\;66\~90\%$ of SCODcr, $94.67\~95.89\%,\;95.76\~98.56\%$ of TKN, and Mode 3 has $84\~92\%$ of SCODcr, $95.39\~99.52\%$ of TKN removal efficiency, respectively. When comparison with Mode 1, 2 and 3, most of nitrogen and phosphorus is removed at the anaerobic condition in Mode 3. but Mode 1, 2 has just revealed activated sludge process characterization. It would because of characterization of PSB.

• Journal of Environmental Health Sciences
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• v.35 no.1
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• pp.64-70
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• 2009

The aims of this study is to examine the effects of the changes in HRT(Hydraulic Retention Time) and media charge in a water-mill, among other operation factors, on the nitrogen and phosphorus removal in order to use up-flow anaerobic reactors, anoxic reactors and water-mill aerobic reactors for sewage treatment. The extension of HRT improved the nitrogen removal efficiency, however the removal pattern was constant regardless of HRT. The removal of phosphorus was constant (80%-90%) regardless of the change in HRT. The removal rate with change in influx load varied such that at the OLR (Organic Load Rate) of 1-3 kg/d, the T-N removal efficiency was 80.7%-88.9% and the T-P removal efficiency was 82.9%-89.3% while at the NLR (Nitrogen Loading Rate) of 0.108-0.156 kg/d the removal efficiencies were 80.7-88.9% (T-N) and 82.9-89.3% (T-P). The analyses of the nitrogen and phosphorous removal characteristics with the C/N and C/P ratio showed that the mean T-N removal rate was 88% at the C/N ratio of 1.2-2.6, and that the mean T-P removal rate was 86% at the C/P ratio of 7.2-14.1. Also, the analysis of nitrogen and phosphorous removal characteristics were analyzed in relation to media charge. The comparison between with and without media charge in the water-mill showed that while the nitrogen removal efficiencies were 86-94% and 85-89% respectively, the difference of phosphorous removal efficiencies were between the two conditions was not significant, thus it suggested that the media charge has less effect on the removal efficiency of phosphorous compared to that of nitrogen.

• Journal of Environmental Health Sciences
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• v.35 no.3
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• pp.214-219
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• 2009

This study examined the removal efficiency of the nitrogen and phosphorus in order to compensate for the combined process of ATAD(Autothermal Thermophilic Aaerobic Digestion) and EGSB(Expended Granular Sludge Bed), which are treatment methods for livestock wastewater, by introducing SBR(Sequencing Batch Reactor) as post-treatment process. The analysis on the treatment efficiency of each operation mode showed that, in the case of T-N, the treatment efficiency were 67.1% and 74.2% for Run-1 and Run-2, respectively, and in the case of T-P, the values were 71.2 and 74.1, respectively, which are indicating that the treatment efficacy is higher in the condition of Run-1, in which the time period of Anoxic and Aerobic segments were increased. In addition, the result of analyzing removal characteristics of nitrogen and phosphorus by Influx load showed that removal efficiency of nitrogen was better in the case of high influx load than in the case of low influx load. Regardless of Influx load, phosphorus showed constant influx concentration, so that removal efficiency of phosphorus was influenced littler by Influx load than that of nitrogen. This study also fed methanol as an external carbon source and performed experiment to induce denitrification under anoxic condition by using nitrate among nitrogen compounds of SBR reactor, and the results showed that intermittent feeding was more effective in Nitrogen Removal than composite feeding.

• Journal of environmental and Sanitary engineering
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• v.13 no.1
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• pp.44-56
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• 1998

This study was performed to investigate the reaction characteristics of piggery wastewater for biological nutrient removal. The reaction characteristics were discussed the fraction of organics, the behavior of nitrogen, nitrification, denitrification, and the behavior of phosphorus. The fraction of readily biodegradable soluble COD was 11-12 percent. The ammonia nitrogen was removed via stripping, nitrification, autotrophic cell synthesis, and heterotrophic cell synthesis. The removal percents by each step were 12.1%, 68.9%, 15.0%, and 4.0%, respectively. Nitrification inhibition of piggery wastewater was found to occur at an influent volumetric loading rate over 0.2 NH$_{3}$-N kg/m$^{3}$/d. Denitrification rates were the highest in the raw wastewater and the lowest in the anaerobic effluent. The denitritation of piggery wastewater came out to be possible, and the rate of organic carbon consumption decreased about 10 percent. The phosphorus removed was released in the form of ortho-p in the aerobic fixed biofilm reactor, it was caused by autooxidation. The synthesis and release of phosphorus were related to the ORP and the boundary value for the phase change was about 170mV. In the synthesis phase, the phosphorus removal rate per COD removed was 0.023mgP$_{syn}$/mgCOD$_{rem}$. The phosphorus contents of the microorganism were 4.3-6.0% on a dry weight basis.

• The Korean Journal of Ecology
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• v.23 no.2
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• pp.163-167
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• 2000

To evaluate the water purification capacity of 4 emergent macrophytes in 4 tributaries of Mankyung River, nitrate reductase activity (NRA) and nutrient removal capacity were determined. Higher NRA occurred in emergent macrophytes such as Persicaria thunbergii and Oenanthe iavanica with 7.8 and 5.4 ${\mu}$moi NO$_2$ g$^{-1}$d.wt. h$^{-1}$. respectively. The nitrogen removal capacity of emergent macrophytes displaying higher NRA fell within the range of 0.85 to 1.95 mg g$^{-1}$d.wt. day$^{-1}$ and was higher in the order Phragmites communis > Persicaria thunbergii > Oenanthe iavanica > Zizania latifolia. The phosphorus removal capacity was within the range of 0.07 to 0.12 mg g$^{-1}$d.wt. day$^{-1}$ and was higher in the order Phragmites communis > Oenanthe iavanica > Persicaria thunbergii > Zizania latifolia. In all the domestic, industrial and agricultural wastewaters, Phragmites communis showed the highest nitrogen and phosphorus removal capacity; 1.36 and 0.0088 mg g$^{-1}$d.wt. day$^{-1}$ respectively. Among the 4 macrophytes. Phragmites communis was the most suitable species for water purification in 4 tributaries of Mankyung River.

• Journal of Environmental Health Sciences
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• v.32 no.1 s.88
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• pp.27-35
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• 2006

This study was carried out to investigate the removal of nitrogen and phosphorus in municipal sewage depending on existence of biological coated media in BCM reactor. The reactor with biological coated media is the process combining $A_2/O$ process. The removal efficiencies for $COD_{Mn},\; BOD_5,\;SS$, T-N and T-P were $78\%,\;90.5\%,\;92.3\%,\;61.9\%,\;60.2\%$, respectively. The specific nitrification rate$(mgNO_3-N/gMLSS{\cdot}d)$ of Contact aeration basin was 52.2 and the specific denitrification rate$(mgNO_3N/gMLSS{\cdot}d)$ in anoxic basin was 95.1. Also, phosphorus release$(mgPO_4-P/gMLSS{\cdot}d)$ in Anaerobic basin was 71.8 and Phosphorus uptake$(mgPO_4-P/gMLSS{\cdot}d)$ in contact aeration was 27.1.

• Journal of Environmental Science International
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• v.6 no.5
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• pp.521-529
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• 1997

In the study, we Investigated the behavior and removal efficiency of organics, nitrogen. phosphorus with operating conditions in SBRs. Substrate used was synthetic wastewater in which the ratio of $COD_{cr}$. : N : P was 100 : 12 : 2. The cycling the in SBRs was adjusted at 6 hours and 8 hours, and then certainly Included anaerobic and aerobic conditions. Also, for each cycling time. we performed 2 series of experiment simultaneously which was set up 10 days and 20 days as SRT. The removal efficiency of $COD_{cr}$. was over 97% in all operating conditions. In the 6 hours cycling time, the removal efficiency of $PO_4^{3-}-P$ reached almost 100% in steady state. And then we could observe a typical phonemena of phosphorus release and uptake, and the removal efficiency of N was 67%, Residual N source was almost TKN and most of the rest remained as $NO_2-N$. Also the difference in both SRTs was not observed practically. In the 8 hours cycling time, dissolution of sludge appeared. and, $PO_4^{3-}-P was not nearly removed but nitrogen was removed up to 75%, And the residual nitrogen was accumulated as $NO_2^--N$.

• Journal of environmental and Sanitary engineering
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• v.12 no.2
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• pp.1-12
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• 1997

This research aims to develop biofilm process for the nutrient removal of piggery wastewater. The developed process is the four stage anoxic-oxic biofilm process with recirculation of the final effluent. In summery, the results are as follows: 1. Nitrification in the piggery wastewater built up nitrite because of the high strength ammonia nitrogen. The nitrification of nitrobacter by free ammonia was inhibited in the total ammonia nitrogen loading rate with more than 0.2 kgNH$_{3}$-N/m$^{3}$·d. 2. The maximal total ammonia nitrogen removal rate was obtained at 22$\circ $C and without being affected by the loading rate. But total oxidized nitrogen production rate was largely affected by loading rate. 3. Autooxidation by the organic limit was a cause of the phosphorus release in the aerobic biofilm process. But the phosphorus removal rate was 90 percent less than the influent phosphorus volumetric loading rate of above 0.1 kgP/m$^{3}$·d. Therefore, the phosphorus removal necessarily accompanied the influent loading rate. 4. On the anoxic-oxic BF process, the total average COD mass balance was approximately 67.6 percent. Under this condition, the COD mass removal showed that the cell synthesis and metabolism in aerobic reactor was 42.8 percent and that the denitrification in anoxic reactor was 10.7 percent, respectively.

• Journal of Korean Society of Water and Wastewater
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• v.12 no.2
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• pp.106-114
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• 1998

In this research, single-, two- and four-stage intermittently aerated activated sludge system were investigated for simultaneous removal of nitrogen and phosphorus with swine wastewater. For the comparison of removal efficiency, conventional activated sludge system was operated. Operational conditions of intermittently aerated activated sludge system were SRT 20day, HRT 24hr and aeration/nonaeration time 1hr/1hr, respectively. Nitrogen and phosphorus removal efficiency in Intermittently aerated activated sludge system was upgraded compare with conventional activated sludge system. In single-stage intermittently aerated activated sludge system, release-uptake of $PO_4^{3-}-P$ was observed very well but, phosphosrus removal in effluent was not effective. In single-stage intermittently aerated activated sludge system, release-uptake of $PO_4^{3-}-P$ in first reactor, was observed very well but, in following reactor, $PO_4^{3-}-P$ concentation showed almost no change. T-N removal efficiency in conventional activated sludge system, single-, two-, and four-stage intermittently aerated activated sludge system were 48, 87, 90.9 and 95.5%, respectively, and phosphorus removal efficiency were 48, 75, 97 and 95%, respectively. Intermittently aerated activated sludge system as a alternative processes of conventional system leads to meet satisfactory effleunt with only on/off aeration regulation and save energy for aeration.