• Journal of the Korean Crystal Growth and Crystal Technology
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• v.12 no.2
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• pp.73-79
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• 2002

The polyol process which applies to cobalt, nickel. copper and precious metals is a interesting and unexpected example of such a method for preparing uniform metal powders. The reaction proceeds via dissolution, and the polyol acts simultaneously as a solvent, a reducing agent, and to some extent a protective agent. Submicrometer uniform cobalt particles can be obtained by seeding the reactive medium ($AgNO_3$) to achieve a complete substitution of homogeneous by heterogeneous nucleation. By varying the number of nuclei it is possible to control to some extent the average particle size in the submicrometer (0.5$\mu$m) range.

• Resources Recycling
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• v.4 no.1
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• pp.52-59
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• 1995

Treating bulk superalloy scrap with molten zinc has been studled to facililate recycling and recovery- of cobalt.Superalloys investigated were the cobalt-base Mar-M-509 and X45 and the nickel-base Rene 80. Charges withZnlscrap ratlos of 1.5-6.5 were heated to 750-9002 far 1-7.5 hours in a nitrogen atmosphere. The moltenzinc dissolved superalloy scrap and zinc was removed by vacuum distillation at 850-Wk for 4-6 hours. Ithas been concluded that the optimum conditions of decomposition for Mar-M-509 and Rene 80 \"ere dissolutiontemperature of about 850k, Znlscrap ratlo of about 5, and dissalution time of about 5.5 hours. The zinc-treatedsuperalloy prouducts were friable and reacted rapidly with acid solutions. Leaching 9mm pieces of unalloyedMar-M-509 or Rene 80 with 5 times the stolchlometric amount oi 6N HCI at 90t ior 3 hours dissolved about1.5-7.270, while leachmg of the minus 20-mesh products dissolved about 89.0-93.0%.ved about 89.0-93.0%.