• Title/Summary/Keyword: NiCoCrAlY

Search Result 179, Processing Time 0.025 seconds

Study on annealing of $Cr/Co/Al-O_x/Co/Ni-Fe$ Magnetic Tunneling junctions

  • 이종윤;전동민;박진우;윤성용;백형기;서수정
    • Proceedings of the Korean Magnestics Society Conference
    • /
    • 2002.12a
    • /
    • pp.72-73
    • /
    • 2002
  • MR(Magnetoresistance)현상이란 인가된 자장에 의해 저항이 변하는 현상이다. 이 현상은 여러 측면에서 연구되고 있고 그 중 TMR(Tunneling Magnetoresistance)현상은 sensor, head, memory device의 적용에 대한 연구가 진행 중에 있다. 특히 memory 소자 측면에서 MRAM은 현재 사용되고 있는 DRAM이나 SRAM들과는 달리 비휘발성과 기록밀도의 고집적 등 많은 장점을 갖는 소자로써 연구되고 있다. (중략)

  • PDF

Comparison of Liver, Kidney, Bone Metal Concentration in OhJeokSan-Treated Rats (오적산(五積散)을 투여한 흰쥐의 간장, 신장, 골중 금속농도 비교에 관한 연구)

  • Park Chul-Soo;Lee Sun-Dong;Park Hae-Mo;Park Yeong-Chul
    • Journal of Society of Preventive Korean Medicine
    • /
    • v.6 no.2
    • /
    • pp.66-85
    • /
    • 2002
  • Traditional herbal medicine is used extensively among the Korean populations, and other Asian countries employ similar therapies as well In recent years, extensive focus was laid on adulteration of the herbal medicine with heavy metals. This may be mainly due to a soil contamination by an environmental pollution. The objective of this study is to identify the contents of various heavy metals in the blood from OhJeokSan-Decoction (OD) treated-rats. For this study, 13 kinds of metals including essential and heavy metals, i.e. Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Se and Zn were analyzed by a slight modification of EPA methods and the following results are obtained. ; 1. There is no significant difference between the OD-treated groups and control group in liver, kidney, bone, brain, weight, food intake. 2. The amount of each metal analyzed in the liver are as follows; Al ; $0.235{\sim}4.215mg/kg$, As ; $0.103{\sim}0.461mg/kg$, Cd ; $0.005{\sim}0.010mg/kg$, Co ; $0.017{\sim}0.046mg/kg$, Cr ; $0.137{\sim}0.403mg/kg$, Cu ; $1.736{\sim}4.827mg/kg$, Fe ; $54.472{\sim}381.447mg/kg$, Hg ; not detected, Mn ; $1.159{\sim}2.803mg/kg$, Ni ; $0.007{\sim}0.095mg/kg$, Pb ; not detected, Se ; $0.682{\sim}1.887mg/kg$, Zn ; $10.213{\sim}26.119mg/kg$, by groups, respectively. In control and other experimental group, several metal (Co, Cu, Mn, Zn, As, Cr) has a significant difference, but in experimental I and other experimental II, III, IV, V groups, there are no significant difference. 3. The amount of each metal analyzed in the kidney are as follows; Al ; $1.712{\sim}31.230mg/kg$, As ; $0.062{\sim}0.439mg/kg$, Cd ; $0.010{\sim}0.062mg/kg$, Co ; $0.000{\sim}0.101mg/kg$, Cr ; $0.125{\sim}0.636mg/kg$, Cu ; $3.385{\sim}12.502mg/kg$, Fe ; $41.148{\sim}99.709mg/kg$, Hg ; $0.000{\sim}0.270mg/kg$, Mn ; $0.433{\sim}2.301mg/kg$, Ni ; $0.000{\sim}0.221mg/kg$, Pb ; $0.000{\sim}0.584mg/kg$, Se ; $0.540{\sim}1.600mg/kg$, Zn ; $8.775{\sim}17.060mg/kg$, by groups, respectively. The concentration of Cu, Se, Cr, and Hg are variated significantly in control and other experimental group, and Cu, Se, Cd, Cr are variated significantly in experimental I and other experimental II, III, IV, V groups. 4. The amount of each metal analyzed in the bone(tibia and fibula) are as follows; Al ; $9.557{\sim}119.464mg/kg$, As ; $0.139{\sim}12.250mg/kg$, Cd ; $0.000{\sim}0.295mg/kg$, Co ; $0.022{\sim}0.243mg/kg$, Cr ; $0.239{\sim}1.999mg/kg$, Cu ; $0.000{\sim}2.291mg/kg$, Fe ; $240.249{\sim}841.956mg/kg$, Hg ; $0.000{\sim}0.983mg/kg$, Mn ; $0.214{\sim}7.353mg/kg$, Ni ; $5.473{\sim}11.453mg/kg$, Pb ; $0.000{\sim}8.502mg/kg$, Se ; $0.000{\sim}3.005mg/kg$, Zn ; $61.158{\sim}195.038mg/kg$, by groups, respectively. The concentration of Se, Cd are variated significantly in control and other experimental groups, and Se is variated significantly in experimental I and other experimental II, III, IV, V groups. 5. Exceptionally several metal concentration is increased or decreased. but there is no significant harmful difference of metal concentration in the liver, kidney and bone, from the OD-treated-rats compared to those of the control group even if higher dosage($1{\sim}8$ times dosage of person) of OD was administered. Thus, it is expected that the herbal decoction in the traditional herbal medicine would not lay any burden on the body and the heavy metal toxins would not affect our physiological system. However, other kinds of herbal treatment, such as i.v. and i.p. should be considered in terms of metal toxicity in the body since the level of certain metal.

  • PDF

A Study on the Erosion Behavior of the Ceramic Sprayed Coating Layer in the Molten 55% Al-Zn (용융 55%Al-Zn 중에서 세라믹 용사 피막의 침식 거동에 관한 연구)

  • 강태영;임병문;최장현;김영식
    • Journal of Welding and Joining
    • /
    • v.18 no.3
    • /
    • pp.51-59
    • /
    • 2000
  • Sink roll has been used in molten 55%Al-Zn alloy bath of continuous galvanizing line for sinking and stabilizing working steel strip in molten metal bath. In the process, the sink roll body inevitably build up dross compounds and pitting on the sink roll surface during 55%Al-Zn alloy coated strip production, and the life time of the sink roll is shorten by build up dross compounds and pitting. The present study examined the application of thermally sprayed ceramic coatings method on sink roll body for improving erosion resistance at molten 55% Al-Zn pool. In this experiment, the stainless steels such as STS 316L and STS 430F were used as the substrate materials. The CoNiCr and WE-Co powder were selected as bond coating materials. Moreover $Al_2O_3-ZrO_2-SiO_2 and ZrO_2-SiO_2$ powders selected as the top coating materials. Appearances of the specimens before and after dipping to molten 55%Al-Zn pool were compared and analyzed. As a result of this study, STS430F of substrate, WC-Co of bond spray coatings, $ZrO_2-SiO_2$ power of top spray coatings is the best quality in erosion resistance test at molten 55%Al-Zn pool

  • PDF

Characteristics of Heavy Metal Pollution in Contaminated Roadside Sediments in Jeonju City, Korea (전주시 도로변 퇴적물의 중금속 오염 특성)

  • Cho, Ktu-Seong
    • Journal of the Korean earth science society
    • /
    • v.24 no.8
    • /
    • pp.711-720
    • /
    • 2003
  • To study characteristics of the heavy metal pollution, sediment samples were collected at 67 sites on the roadside of Jeonju city during summer and winter, 2002. The total concentration of metals including Cd, Co, Cr, Cu, Ni, Pb, Zn, and Mn in the sediment samples were determined. The results indicate that the roadside sediments in Jeonju city have lower (1/2 to 1/7 times) concentrations of Zn, Cu, Pb and Cd than the metal concentrations previously reported for roadside soil, dust and sewage sludges in Seoul. However, the metal concentrations are higher than environmental quality criteria in soil suggested from several countries, and Zn, Cu, Pb and Cd contents are usually 2-7 times higher than the world average contents of the metals in natural soil. Although pollution index and concentrations of Cr, Ni, Pb and Zn in the roadside sediments at industrial area were usually higher than those of downtown and residential area, the metal having small vehicle- and steel-related industries had high concentrations of metals. The results of chemical partitioning analysis showed that Pb, Zn and Mn are mainly associated with carbonate/adsorbed and Fe-Mn oxide phases but that Cu is largely associated with the organic and sulfide fractions. It thus indicates that both large and small (vehicle- and steel-related) industries are main sources of heavy metal contamination. Due to high solubility of the carbonate phases by natural leaching episodes, the carbonate/adsorbed Cd, Co, Ni, Pb, Zn and Mn in the roadside sediments may serve as a potential source of contamination.

A Study On Heavy Metal Contamination in the Different Size Fractions of Deposited Road Particles(DRPs) (노면퇴적물의 입자 크기에 따른 중금속 오염에 관한 연구)

  • Kim, Boo-Gil;Lee, Byung-Cheol
    • Journal of Environmental Science International
    • /
    • v.15 no.12
    • /
    • pp.1171-1175
    • /
    • 2006
  • Deposited road particles (DRPs) were analysed for heavy metal concentrations at four different roads in a city, Korea. The samples were collected using a roadway surface vacuum cleaning vehicle which was commonly used in collecting roadway surface particles. Six particle size ranges were analyzed separately for twelve heavy metal elements (Cd, Cr, Pb, Ni, Al, As, Co, Cu, Fe, Mn, Zn and Hg). At all sampling sites, the high concentration of the heavy metals occurred in the <74um particle size range, which conventional roadway cleaning vehicles do not remove efficiently. The Pb concentration significantly increased with decreasing particle size of DRPs, and other toxic heavy metals (Cd, Cr and Ni) also showed similar results. The heavy metal concentrations in the smaller size fraction of DRPs is important because they are contaminants that are preferentially transported by road runoff during rainfall.

Chemistry of Talc Ores in Relation to the Mineral Assemblages in the Yesan-Gongju-Cheongyang Area, Korea (충남 예산-공주-청양 지역 활석광석의 광물조합에 따른 화학적 특징)

  • 김건영;김수진
    • Journal of the Mineralogical Society of Korea
    • /
    • v.10 no.1
    • /
    • pp.60-73
    • /
    • 1997
  • The talc of the Daeheung, Pyeongan, and Cheongdang (Shinyang) talc deposits in the Yesan-Gongju-Cheongyang area is a hydrothermal alteration product of serpentinite originated from ultramafic rocks. The mineral assemblages in alteration zones are: serpentine, serpentine-talc, talc, talc-chlorite, talc-phlogopite-chlorite, and talc-tremolite-chlorite. Chemical distributions in both the Al2O3-FeO-MgO system and the immobile elements suggest that the serpentine-talc and talc rocks are the reaction product of ultramafic rocks and silicic hydrothermal solution without addition of other granitic components, whereas chlorite-, phlogopite-, and tremolite-bearing rocks are the metasomatic alteration product of serpentinite by hydrothermal solution affected by granitic gneiss. Discontinuities in the immobile element ratios of mineral assemblages are due to changes in their mineralogy. The relative contents of Al2O3, TiO2, Zr in the talc-phlogopite-chlorite and talc-tremolite-chlorite rocks increase irregularly with increasing phlogopite, tremolite, and/or chlorite contents in contrast to other ore types. But the relative contents of Cr, Ni, and Co are uniform in all the mineral assemblages. Chemistry of each mineral assemblage formed by steatitization of serpentinite suggests that Cr, Co, Ni, MgO, and Fe2O3 are relatively immobile during the alteration, whereas SiO2, Al2O3, CaO, and K2O are highly increased. The contents of chlorite, phlogopite, and tremolite in each mineral assemblage might be controlled by addition of Al2O3, K2O, and CaO, respectively. The high contents of other elements than immobile elements in the altered rocks as compared with unaltered rocks indicate that a large amount of elements were introduced from hydrothermal solution up to about 8∼41% in total mass showing maximum value in the talc-phlogopite-chlorite rock.

  • PDF

Characteristics of Heavy Metal Distribution in Surface Sediments from the south Sea of Korea (남해 대륙붕 표층퇴적물 중 중금속 원소의 분포 특성)

  • 조영길;이창복
    • 한국해양학회지
    • /
    • v.29 no.4
    • /
    • pp.338-356
    • /
    • 1994
  • Sediment samples from the continental shelf of the South Sea of Korea are analysed to determine the concentration of Al, Fe, Mn, cu, Ni, Zn, Co, Cr and Pb. among these samples, fine-grained sediments were also analysed by a sequential extraction technique to know geochemical forms of the metals in this environments. The total concentration of Al, Fe, Cr, Ni, Cu and Zn in bulk sediments decreased gradually with the increase of distance from the coastal zone. This distribution patterns are well coincide with grain size distribution. However, the patterns of Mn, co and Pb do not follow such and overall distribution. The concentration of Pb, particularly, did not show any features in areal distribution, which may be result from different pathways to the sediments, compared to the other metals. the speculation data show that a considerable amount of Cd, Mn and Co are bounded in the carbonate fraction, accounting for 42.8%, 40.3% and 30.6%, respectively. Cu, Zn, Mn and Fe are largely associated to oxide fraction with proportions of 34.4%, 23.1%, 15.5% and 13.7%, respectively. However, the metals in residual fraction account for more than 50% of the total metal concentration, except for Mn. These observations emphasize that residual fraction in the dominant component controlling the elemental concentration.quartz and glauconite grains.Accordingly,these sediments are interpreted as an extension part of transgressive sand deposit that are widely distributed on the continental shalf floor of southern Yellow Sea.

  • PDF

A Study on the Formation of Spinel Pigment(Green Pigment based on Magnesium-Chrome) (Spinel Pigment의 생성반응에 관한 연구)

  • 이응상;박철원;황성연
    • Journal of the Korean Ceramic Society
    • /
    • v.12 no.1
    • /
    • pp.29-36
    • /
    • 1975
  • This study was conducted to research the formation, color development and application for colored glazes of the spinel solid solutions of the green pigment. On specimens prepared by calcining the oxide and basic carbonate mixture at 1250℃ for 1.5 hour, the x-ray analysis, measurement of reflectance and the test of their stabiality as a glaze pigment were carried out. The results are summarized as follows 1) Each sample is composed of single spinel and not of mixture of spinel. 2) Formation of continuous soild solution, except for a few instances, pertaining to Vegard's law was confirmed by means of the x-ray analysis. 3) The more difference between absorption and reflectance lies, the lighter colors are. When the absorption occurs at the high-reflectance, the excitation purity becomes low. On the contrary when the absorption takes place at the low-reflectance, the excitation purity becomes low. On the contrary when the absorption takes place at the low-reflectance, the excitation purity is higher. 4) Colors obtained in the CdO-MgO-Cr2O3-Al2O3 system, as the amounts of Al3+ increased, change from green through brown to pink, and the absorption peak shifts towards violet region. 5) An increase in Co2+ in the CoO-MgO-Cr2O3-Al2O3 system, changes the color from blue green to dark blue. The excitation purity is higher, and the absorption peak shifts toward regions. 6) Colors are green in the NiO-MgO-Cr2O3 and CdO-MgO-Cr2O3 systems in general, but in the ZnO-MgO-Cr2O3 system brillant hue is not obtained. 70 According to the results of the colored glaze test, the spinels turn outto be stable as brilliant glaze pigment in the calcium-magnesia glaze.

  • PDF

Abundances of refractory elements for stars with extrasolar planets : New samples

  • Park, Sun-Kyung;Kang, Won-Seok;Lee, Sang-Gak;Lee, Jeong-Eun
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.36 no.2
    • /
    • pp.147.1-147.1
    • /
    • 2011
  • We investigate the chemical differentiation in F, G, K type stars with and without planets to extend the work by Kang et al. (2011) to various spectral types. Since the primordial chemical composition has been preserved in the stellar atmosphere, stellar metallicity can provide the information on the primordial material, which is the potential building block of planets. Therefore, we can explore the favored conditions for planet formation through the comparison of chemical compositions between planet-host stars (PHSs) and stars without planets. In this work, we analyze 19 F, G, and K type stars. In each spectrum, we measure equivalent widths (EWs) of Fe, Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn, Co, and Ni using TAME (Tools for Automatic Measurement of Equivalent width). The abundances of these species can be derived with the measured EWs and MOOG code (Sneden 1973). Like results by precedent studies, we find that planet-host stars have abundances higher than stars without planets. The typical difference in the abundances of Na, Mn, Co and Ni is $0.4{\pm}0.2dex$. In addition, as found in Kang et al. (2011), Mn is the most different element between PHSs and comparison stars.

  • PDF

A Design Approach to $CrO_x/TiO_2$-based Catalysts for Gas-phase TCE Oxidation (기상 TCE 제거반응용 $CrO_x/TiO_2$계 복합 산화물 촉매 디자인)

  • Yang, Won-Ho;Kim, Moon-Hyeon
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.28 no.4
    • /
    • pp.368-375
    • /
    • 2006
  • Single and complex metal oxide catalysts supported onto a commercial DT51D $TiO_2$ have been investigated for gas-phase TCE oxidation in a continuous flow type fixed-bed reaction system to develop a better design approach to catalysts for this reaction. Among the $TiO_2$-supported single metal oxides used, i.e., $CrO_x,\;FeO_x,\;MnO_x,\;LaO_x,\;CoO_x,\;NiO_x,\;CeO_x\;and\;CuO_x$, with the respective metal contents of 5 wt.%, the $CrO_x/TiO_2$ catalyst was shown to be most active for the oxidative TCE decomposition, depending significantly on amounts of $CrO_x\;on\;TiO_2$. The use of high $CrO_x$ loadings greater than 10 wt.% caused lower activity in the catalytic TCE oxidation, which is probably due to production of $Cr_2O_3$ crystallites on the surface of $TiO_2$. $CrO_x/TiO_2$-supported $CrO_x$-based bimetallic oxide catalysts were of particular interest in removal efficiency for this TCE oxidation reaction at reaction temperatures above $200^{\circ}C$, compared to that obtained with $CrO_x$-free complex metal oxides and a 10 wt.% $CrO_x/TiO_2$ catalyst. Catalytic activity of 5 wt.% $CrO_x-5$ wt.% $LaO_x$ in the removal reaction was similar to or slightly higher than that acquired for the $CrO_x$-only catalyst. Similar observation was revealed for 5 wt.% $CrO_x$-based bimetallic oxides consisting of either 5 wt.% $MnO_x,\;CoO_x,\;NiO_x\;or\;FeO_x$. These results represent that such $CrO_x$-based bimetallic systems for the catalytic TCE oxidation on significantly minimize the usage of $CrO_x$ that is well known to be one of very toxic heavy metals, and offer a very useful technique to design new type catalysts for reducing chlorinated volatile organic substances.