• Title/Summary/Keyword: Ni-Mo

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Stress Corrosion Cracking of Alloys 600, 690, and 800 in a Tetrathionate Solution at $340^{\circ}C$

  • Lee, Eun-Hee;Kim, Kyung-Mo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.587-588
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    • 2006
  • The stress corrosion cracking (SCC) susceptibility of Alloy 600 MA, Alloy 600 TT, Alloy 800, and Alloy 690 TT were investigated in a deaerated 0.01 M solution of sodium tetrathionate using reverse u-bend test samples at $340^{\circ}C$. The results showed that SCC occurred in all alloys, excluding Alloy 690 TT. The SCC susceptibility decreased with an increase in the chromium content of the alloys. The results of the deposits and spectra taken from an energy dispersive X-ray system confirmed the existence of a reduced sulfur causing SCC.

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Nominally Equivalent Powders for P/M Steels: Analysis of Response to Sintering and Differences at Various C Content

  • Bocchini, G. F.;Ienco, M. G.;Pinasco, M. R.;Stagno, E.;Baggioli, A.;Gerosa, R.;Rivolta, B.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.405-406
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    • 2006
  • Raw materials from different sources, produced by a given process and having equal chemical composition, are supposed to be equivalent. The differences in sintering behavior have been investigated on P/M steels obtained from four diffusion-bonded powders (Fe + Ni + Cu + Mo) on atomized iron base, at the same alloy contents. Two levels of carbon and two sintering conditions have been investigated. Dimensional changes, C content, hardness, microhardness pattern, universal hardness, fractal analysis, pore features, microstructure features, and rupture strength have been compared to characterize different raw materials. The results show that the claimed equivalence is not confirmed by experimental data.

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CIGS thin film solar cells prepared by one-step sputtering using a quaternary compound target (4성분계 화합물 타겟을 이용한 단일공정 스퍼터링에 의한 CIGS 박막태양전지)

  • Kim, Tae-Won;Park, Jae-Cheol;Park, Sin-Yeong;Song, Guk-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.45-46
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    • 2015
  • Se 원소가 포함된 $CuIn_xGa_{1-x}Se_2$(CIGS) 단일 스퍼터링 타겟을 이용하여 후처리 공정없이 단일 스퍼터링 공정만으로 CIGS 흡수층 박막을 증착하여 소자 특성을 확인하였다. 단일 CIGS 흡수층 공정이 적용된 CIGS 박막태양전지 소자(유리기판/Mo/단일 CIGS 흡수층 박막/CdS/i-ZnO/Al-doped ZnO/Ni-Al grid)에서 10.0%의 태양광 변환 효을을 달성하였으며, 이는 기존의 복잡한 공정구조를 해결하여 대면적 양산화 CIGS 제조 공정에도 적용할 수 있음을 확인하였다.

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Impact Behavior of Large SF590A Forged Product (SF 590A 대형 단조품의 충격특성에 관한 연구)

  • Jin, Sang-Uk;Kim, Sang-Shik;Lee, Young-Seon;Lee, Seung-Uk;Kim, Nam-Soo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.61-66
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    • 2008
  • Impact behavior of large SF590A (Fe-0.65C-1.5Mn-0.035P-0.035S-0.3Cr-0.15Mo-0.4Ni-0.3Cu) forged propeller shaft was studied in this study. Charpy impact specimens were prepared from the forged product with different heat number. The impact value of each specimen with different heat number tends to vary greatly depending on the prior austenite grain size and, less significantly, on the amount of sulfur. The dominant metallurgical factors affecting impact behavior of SF590A forged product are discussed based on fractographic and metallographic observations.

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Precipitation Behavior and Mechanical Properties of High Strength Invar Alloy (고강도 인바합금의 석출거동 및 기계적 특성)

  • Jung, J.Y.;Lee, K.D.;Ha, T.K.;Jeong, H.T.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.547-550
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    • 2008
  • Precipitation characteristics of the Fe-36Ni based high strength Invar alloy for power transmission wire was investigated in this study. High strength can be obtained in this alloy through precipitation hardening and strain hardening by cold working. $FactSage{(R)}$ in this study, revealing that equilibrium phases which can be formed are two kind of MC-type precipitates and MoC carbide. The latter stoichiometric carbide was expected to be formed at relatively lower temperature $770^{\circ}C$. High strength above 1000MPa and 40% of elongation were obtained at room temperature in both cases.

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The Effect of Chemical Composition and Destabilization Heat Treatment on the Amount of Retained Austenite in High Chromium Cast Irons (고크롬주철의 잔류오스테나이트함량에 미치는 화학조성 및 불안정화열처리의 영향)

  • Ryu, Seong-Gon
    • Korean Journal of Materials Research
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    • v.6 no.4
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    • pp.372-378
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    • 1996
  • 고크롬주철에 있어서 기지 및 탄화물의 조직제어는 내마모성의 향상을 위해 필수적이다. 특히 기지조직내의 잔류오스테나이트함량은 최적 내마모성을 얻기위해 반드시 조절되어야 한다. 본 연구에서는 3% C-18%(or 25%)Cr-Mo-Ni-Mn 고크롬주철을 80$0^{\circ}C$, 90$0^{\circ}C$, 100$0^{\circ}C$ 및 110$0^{\circ}C$의 질소분위기 하에서 각각 20분 불안정화열처리를 행한 후 공냉시켰다. 잔류오스테나이트의 함량은 Xtjs 회절시험을 통해 측정하였으며 회절 peak는 $\alpha$200, $\alpha$220, ${\gamma}$220그리고 ${\gamma}$311을 이용하였다. 화학조성, 불안정화열처리의 온도 및 시간, 그리고 잔류오스테니이트함량강의 관계식을 도출하였다.

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Analysis of the Residual Stress of CIGS Layer with the Different Thickness of Solar Cell Element Layers and Fe-52wt% Substrate (연성 CIGS 태양전지의 Fe-52wt% 기판과 박막층의 두께에 따른 잔류응력해석)

  • Han, Yun-Ho;Lee, Min-Su;Eom, Ho-Gyeong;Kim, Dong-Hwan;Im, Tae-Hong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.137-138
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    • 2012
  • 박막태양전지의 경우 기판재와 태양전지를 구성하는 반도체 층간의 열팽창 거동 차이가 태양전지의 변형을 야기한다. 이러한 열변형은 태양전지의 효율에 영향을 주는 것으로 알려져 있다. 그러므로 태양전지를 구성하는 반도체 층과 열팽창 거동이 유사한 기판재의 적용이 필요하다. 본 연구에서는 연성 CIGS 태양전지를 구성하는 기판과 박막층의 두께변화가 열공정 중 발생하는 잔류응력에 미치는 영향을 전산해석 하고자 하였다. 전산해석 결과 Fe-52wt%Ni 기판재의 두께가 증가함에 따라 CIGS 박막층 내부의 잔류응력은 감소하였다. SiO2 절연층의 두께가 증가하면 CIGS 박막층의 잔류응력이 증가하였다. Mo 후면전극층이 얇아지면 잔류응력이 감소하였으나 CIGS층의 두께변화는 CIGS층의 잔류응력에 큰 영향을 미치지 않았다.

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Removal torque of sandblasted large grit, acid etched treated mini-implant (Sandblasted large grit, acid etched 표면처리에 따른 교정용 미니 임플랜트의 제거회전력에 관한 연구)

  • Oh, Nam-Hee;Kim, Seong-Hun;Kook, Yoon-Ah;Lee, Keun-Hye;Kang, Yoon-Goo;Mo, Sung-Seo
    • The korean journal of orthodontics
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    • v.36 no.5
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    • pp.324-330
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    • 2006
  • Objective: The purposes of this study were to evaluate the differences between sand blasted, large grit and acid-etched (SLA) treated mini-implants and smooth surface orthodontic mini-implants in relation to the removal torque as well as the histologic analysis. Methods: Custom-made, screw-shaped, titanium implants with a length of 9.5 mm and an outer diameter of 1.8 mm were divided into 2 groups; the SLA group (20 SLA treated orthodontic mini-implants) and the smooth surface group (20 smooth surface mini-implants), and placed In the tibia metaphysis of 10 rabbits. Each rabbit had 4 mini-implants placed, 2 in each tibia. The right tibia were implanted with the SLA group mini-implants and the left tibia had the smooth group mini-implants placed. Each mini-implant group were immediately applied with a continuous traction force of 150 g using a Ni-Ti coil spring. The rabbits were sacrificed 6 weeks post-surgically. Subsequently, the legs were stabilized, the Ni-Ti coil springs were removed and the mini-implants were removed under reverse torque rotation with a digital torque gauge. Results: 6 weeks after placement, the SIA group presented a higher mean removal torque value (8.29 Ncm) than the smooth group (3.34 Ncm) and histologic analysis revealed a higher new bone formation aspect along the screw in the SLA group. Conclusion: Results of this study indicates that SLA treated mini-implants may endure higher orthodontic forces without loosening.

Distribution Characteristics of PM10 and Heavy Metals in Ambient Air of Gyeonggi-do Area using Statistical Analysis (통계분석을 이용한 경기도 대기 중 미세먼지 및 중금속 분포 특성)

  • Kim, Jong Soo;Hong, Soon Mo;Kim, Myoung Sook;Kim, Yo Yong;Shin, Eun Sang
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.3
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    • pp.281-290
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    • 2014
  • This study was conducted to evaluate the distribution characteristics of $PM_{10}$ and heavy metals concentrations in the ambient air of Gyeonggi-do area by region and season from February, 2013 to March, 2014. The regression model for the prediction of formation characteristics and contamination degree of $PM_{10}$ and heavy metals by correlation analysis and regression analysis for using the multivariate statistical analysis was also established. The main wind direction during the investigation period was South East (SE) and West South West (WSW) winds, and the concentration of $SO_2$ at Ansan with industrial region showed 1.6 times higher than Suwon, Euiwang with residential region. The concentrations (median) of Pb, Cu and Ni at Ansan showed 3.2~4.5, 1.9~2.2 and 1.7~2.6 times respectively higher than those at Suwon. By the seasonal concentration variation, the concentrations of $PM_{10}$, Pb, Fe and As in winter and spring (December to May) showed 1.7, 1.9, 1.9 and 2.7 times respectively higher than those in summer and fall (June to November). As, Fe and $PM_{10}$ had a big difference by the seasonal factors, and Cu and Ni were evaluated to be influenced by the regional factors. From the results of correlation analysis among the target items, the correlation coefficient of PM and Mn had 0.82 (p/0.01) and that of Fe and Mn had 0.82 (p/0.01), which showed high correlation. And the correlation coefficients for $SO_2$ and Pb, CO and $PM_{10}$ were 0.66 (p/0.01) and 0.62 (p/0.01) respectively. The multiple linear regression models for $PM_{10}$, Pb, Cu, Cr, As, Ni, Fe and Mn were established by independent variables of CO, $SO_2$ and meteorological factors (wind speed, relative humidity). In the regression models, independent variable $SO_2$ was in cause-and-effect relationship with all dependent variables, and $PM_{10}$, Fe and Mn were influenced by CO and wind speed, and Pb, Cu, Ni and As had a main factor of $SO_2$.

Geochemical Origin, Behavior and Enrichment of Environmental Toxic Elements in Coaly Metapelite from the Deokpyeong Area, Korea (덕평지역의 탄질 변성니질암에 관한 환경적 독성원소의 지구화학적 기원, 거동 및 부화)

  • Lee, Hyun Koo;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.30 no.6
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    • pp.553-566
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    • 1997
  • Origin, behavior and enrichment of environmental toxic elements from the Deokpyeong area were investigated on the basis of major, trace and rare earth element geochemistry. Coaly metapelites of the Deokpyeong area are subdivided into grey phyllite, dark grey phyllite, coaly slate and black slate, which are interbedded along the Ogcheon Supergroup. The coaly slate had been mined for coal, but mining is closed. The coaly and black slates are lower contents of $SiO_2$ and $Al_2O_3$, and higher contents of LOI, CaO, $Na_2O$ and BaO as compared with the phyllitic rocks. Rare earth elements are highly enriched in the coaly and black slate. Average compositions (ppm) of minor and/or environmental toxic elements in the coaly and black slate are revealed as As=127, Ba=30,163, Cd=18, Cr=740, Cu=84, Mo=378, Pb=43, Sb=12, Se=44, U=144, V=8,147 and Zn=292, which are extremely high concentrations than those in the NASC compositions. Major elements (average enrichment index; 5.34) in the coaly metapelites are mostly depleted, excepting $P_2O_5$ and BaO, normalized by NASC. Rare earth elements (average enrichment index; 1.48) are enriched in the coaly slate. On the basis of NASC, minor and/or environmental toxic elements in the coaly metapelites were strongly enriched of all the elements with the exception of Co, Cs, Ni and Sr. Average enrichment index of trace elements in coaly metapelite is 31.51 (coaly slate; 51.94 and black slate; 15.46). Especially, enrichment index of potentially toxic elements (As, Ba, Cr, Cu, Mo, Ni, Sb, Se, U, V and Zn) of the rock is 46.10 (grey phyllite; 7.15, dark grey phyllite; 4.77, coaly slate; 88.96 and black slate; 22.11). These coal formations were deposited in basin of boundary between terrestrial and marine environments deduced to carbon, sulfur (C/S=2.2 to 275.7), trace and rare earth elements characteristics. Irregular behavior and dispersion between major, minor and rare earth elements of those metapelites indicates a variable source materials, incomplete mixing of differential source and/or reequilibrium of diagenesis and metamorphism.

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