• Journal of the Korean Electrochemical Society
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• v.4 no.4
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• pp.152-159
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• 2001

Electric vehicle performance is very dependent on traction batteries. For developing the electric vehicles with high performance and good reliability, the traction batteries have to be managed to get maximum performance under various operating conditions. The enhancement of the battery performance can be accomplished by implementing battery management system (BMS) that plays important roles of optimizing the control mechanism of charge and discharge of the batteries as well as monitoring battery status. In this study the battery management system has been developed for maximizing the use of Ni/MH batteries in electric vehicle. This system provides several tasks: the control of charging and discharging, overcharge and over-discharge protection, the calculation and display of state of charge, safety and thermal management. The BMS was installed in and tested using the DEV5-5 electric vehicle developed by Daewoo Motor Co. and Institute for Advanced Engineering in Korea. The 18 modules of Panasonic Ni/MH battery, 12 V-95 Ah, were used in the DEV5-5. The high accuracy within the range of $3\%$ and the good reliability were shown in the test results. The BMS can also improve the performance and cycle life of Ni/MH battery pack as well as the reliability and safety of the electric vehicles (EV).

• Journal of Hydrogen and New Energy
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• v.22 no.4
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• pp.495-503
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• 2011

The sealed nickel-metal hydride (Ni-MH) secondary battery are primarily used as energy storage for the HEV. But, the research on Ni-MH battery has focused on anode materials. In the present study, we investigate to improve the electrochemical characteristics of Ni-MH batteries using the surface treatment of $Ni(OH)_2$ cathode by CoOOH. Surface treated $Ni(OH)_2$ cathode showed significant improvement in the activation behavior, rate capability, charge retention, and cycle life of the batteries were significantly improved. In addition, the surface treated electrode exhibited the higher overvoltage for oxygen evolution than the untreated electrode. This phenomenon indicates that the charge efficiency can be improved by suppressing the oxygen evolution on cathode.

• Journal of the Korean Electrochemical Society
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• v.4 no.2
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• pp.53-57
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• 2001

When an EV is parked for a long period time, the battery capacity naturally decreases due to selfdischarge. Therefore, this effect must be considered for the accurate measurement of the state of charge of EV battery. Battery selfdischarge simulations using the design of experiments among computer simulation methods are compared with experimental data for Ni/MH batteries for electric vehicles. The motivation is to predict the selfdischarge rate of the battery for electric vehicle at all temperature conditions and standing time when electric vehicle could be operated. We developed a general equation representing the seudischarge rate of the electric vehicle battery using design of experiments, and the equation is determined by temperature and standing time of the battery. We selected Ni/MH battery, 12 V-95 Ah, for pure electric vehicle for this study. ID develop the equation using design of experiments we selected temperature range of $-20^{\circ}~30^{\circ}C$ and standing time of 1 day$\~15$ days. We conducted several selfdischarge tests of Ni/MH battery to verify the integrity of the equation. The results showed that the computation values were in good agreement with experimental data.

• Journal of Hydrogen and New Energy
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• v.17 no.4
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• pp.418-424
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• 2006

In order to improve the activation properties of the $AB_2$ type hydrogen storage alloys for Ni-MH battery, the alloy surface was modified by employing high energy ball milling. The $Zr_{0.54}Ti_{0.45}V_{0.54}Ni_{0.87}Cr_{0.15}Co_{0.21}Mn_{0.24}$ alloy powder was ball milled for various period by using the high energy ball mill. As the ball milling time increased, activation of the $AB_2$ type composite powder electrodes were enhanced regardless of additives. When the ball milling time was small discharge capacities of the $AB_2$ type composite powder electrodes increased with the milling time. On the other hand for large milling time it decreased with increasing milling time. The maximum discharge capacity was obtained by ball milling for 3-4 min.

• 한국전기화학회:학술대회논문집
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• 2005.04a
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• pp.25-25
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• 2005

• Journal of Surface Science and Engineering
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• v.28 no.2
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• pp.83-91
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• 1995

A new method for preparation of thin nickel foam for Ni-MH battery was investigated. In this method, fine graphite powders of $1\mu\textrm{m}$～$2\mu\textrm{m}$ diameter were pasted into pores of thin polyurethane foam film in order to supply electric conducting seeds for nickel deposition by electroless plating reaction. After electroless plating, remaining polyurethane foam was removed chemically by organic solvent treatment and graphite particles also removed by ultrasonic cleaning. Porosity of formed nickel foam was about 85% During electroplating, porosity of the nickel foam decreased less than 5% up to $30\mu\textrm{m}$ coating thickness. And then it was electroplated and heat-treated to improve mechanical strength and ductility. Finally, thin nickel foam for Ni electrode of Ni-MH battery with 80% porosity and $350\mu\textrm{m}$～X$400\mu\textrm{m}$ thickness was obtained.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.38 no.3
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• pp.227-234
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• 2014

Fuel consumption rates of electric vehicles strongly depend on their battery performance. Because the battery performance is sensitive to the operating temperature, temperature management of the battery ensures its performance and durability. In particular, the temperature distribution among modules in the battery pack affects the cooling characteristics. This study focuses on the thermal modeling of a battery pack to observe the temperature distribution among the modules. The battery model is a prismatic model of 10 NiMH battery modules. The thermal model of the battery consists of heat generation, convective heat transfer through the channel and conduction heat transfer among modules. The heat generation is calculated by the electric resistance heat during the charge/discharge state. The model is used to determine a strategy for proper thermal management in Electric vehicles.

• Korean Chemical Engineering Research
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• v.51 no.2
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• pp.263-266
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• 2013

It was investigated the electrochemical characteristics of the Ni-MH battery by hydrophilic process. For adopting the Ni-MH battery in water-electrolyte, polyolefin separator was processed the hydrophilic treatment. No treatment sample did not meet KS standard (KSC 8544) but hydrophilic treatment ones satisfied with the KS standard in electrochemical characteristics, such as discharge performance, retention capacity, and cycle performance. All hydrophilic treatment samples showed similar battery performances. Among them, sulfonation treatment sample exhibited the highest value in aspect of capacity retention rate (> 88%). Furthermore, fluoride treatment sample showed the best cycle performance during battery test. This sample maintained a good cycling performance until $1,480^{th}$ cycle, which was about 3 times as compared with that of KS standard (500 cycle).

• Journal of Hydrogen and New Energy
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• v.18 no.4
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• pp.365-373
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• 2007

We optimized the compositions of electrolyte and additives for anode in Ni-MH battery to improve the electrode characteristics at ambient and low temperatures using response surface method(RSM). Among various additives for anode, PTFE exhibited the greatest influence on the discharge capacity of the anode. Through response optimization process, we found the optimum composition of the additives to exhibit the greatest discharge capacity. When the amount of additives was too small, the anode was degraded with time due to the low binding strength among alloy powders and the resultant separation of powders from the current collector. In contrast, the addition of large amount of the additives increased in the resistance of the electrode. In addition, the discharge capacity of the anode at $-18^{\circ}C$ increased with decreasing the concentration of KOH, NaOH and LiOH in design range of electrolyte. The resistance and viscosity of electrolyte appear to affect the discharge capacity of the anode at low temperature.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 1998.11a
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• pp.186-191
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• 1998