• 자원환경지질
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• 제30권5호
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• pp.443-450
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• 1997

The main purpose of this study is to investigate mineralogical and chemical changes during natural weathering, and assess the mobility of major and trace elements. Yongwol power plant utilize anthracite coal which is mainly composed of illite, kaolinite, pyrophyllite and quartz in mineralogy. Coal and coal-derived fly ash samples were sampled by the electrostatic precipitator in Yongwol coal-fired power plant in Korea. Short term weathered fly ash were also collected in ash disposal mound, and two profile soil samples were taken from an ash near the power plant. Amorphous materials are the main component of the fly ash, and mullite, quartz, magnetite and heamatite are present in all coal-derived fly ash. In chemistry, Si and Al are the most abundant elements of the total content. The ash samples were fractionated into upper $90{\mu}m$ and under $45{\mu}m$ size. Finer particles show higher concentrations in metal contents including Co, Cr, Cu, Ni, V, Zn and Pb. Concentration of Zn and Pb are nearly 4 times higher concentration in the finer particles. For the profile samples, the concentrations of $SiO_2$, $Na_2O$, MgO and $K_2O$ generally show increasing trends with depth, whereas those of $Fe_2O_3$ and $TiO_2$ appear to decrease with depth. Content of MnO does not show any specific depth trend. For the trace elements, Co, Cu, Ni and V show increasing concentrations with depth.

• 한국수소및신에너지학회논문집
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• 제19권6호
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• pp.514-519
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• 2008

In the present study, biomass pyrolysis was done using five different kinds of catalysts with change in the support species and their compositions. Ni was loaded on alumina, ceria and alumina-ceria supports using co-precipitation method. In all the catalysts, 30wt% of nickel was loaded on the support materials. The paper used in daily writing purposes was taken into account as biomass sample. In the experiment, 19 of biomass was mixed with o.1g of each catalyst separately. Thermogravimetric analysis (TGA) was performed with all the catalysts diminished the initial degradation temperature of paper biomass sample considerably. During the pyrolysis process, the temperature was raised from room temperature to $800^{\circ}C$ with the heating rate of $10^{\circ}C$/min in the furnace. The cumulative $H_2$ volume had reached the best value of l4.02ml with the Ni/$Al_2O_3-CeO_2$ 30wt%/(50wt%-50wt%) catalysts. In presence of all the catalysts, the highest amount of $H_2$ was produced at $800^{\circ}C$, 10min. of residence time.

• Korean Chemical Engineering Research
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• 제49권6호
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• pp.720-725
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• 2011

금속질산염과 염화금산을 전구체로 사용하여 다양한 금속산화물($$Al_{2}O_{3}$, ZnO, $Fe_{2}O_{3}$, $Cr_{2}O_{3}$, $MnO_{2}$, CuO, NiO, $Co_{3}O_{4}$)에 담지된 금촉매를 공침법을 이용하여 제조한 후, 일산화탄소 산화반응에서 수분첨가의 영향을 검토하였다. 이들 중 $Co_{3}O_{4}$와 ZnO에 담지된 금촉매가 일산화탄소에 대하여 높은 활성을 보여주었다. 반응가스 중에 수분이 첨가될 때 Au/$Co_{3}O_{4}$ 촉매는 활성이 약간 감소하였으나, Au/ZnO 촉매에서는 활성이 크게 증가하여 수분에 의한 일산화탄소 산화 활성은 담체의 종류에 크게 의존함을 알 수 있었다. 반응가스 중에 포함된 수분에 관계없이 반응 전과 후의 Au(5 wt%)/ZnO 촉매의 금입자 크기는 거의 변하지 않아 활성이 감소되는 이유는 금입자들의 소결에 의한 영향보다는 카보네이트와 같은 화학종에 의해 불활성화가 일어남을 알 수 있었으며, 이 화학종은 수분의 첨가에 의해 이산화탄소로 분해되어 활성이 증가한 것으로 생각된다.

• 한국지구과학회지
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• 제30권4호
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• pp.427-443
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• 2009

영남육괴 남서부에 분포하는 백악기 화성암들은 태평양(Pacific)판의 섭입에 의해서 야기된 활발했던 백악기 화성활동의 산물이다. 암석학적 및 지화학적 접근을 통하여 이 지역에 분포하는 화강암류의 성인과 지구조환경을 유추하여 보았다. 연구지역의 화강암류는 칼크-알칼리(calc-alkaline)계열로, 분화에 따른 주성분원소와 미량원소의 변화 경향은 전반적으로 다른 지역의 백악기 화강암류의 분화 경향과 유사하게 나타나지만, 각 암체의 분화경향이나 화학조성을 살펴볼 때 각 암체의 마그마 근원물질은 서로 다른 것으로 사료된다. 복내지역 동교리 부근에 분포하는 화강섬록암(DGd)은 연구지역 내에 분포하는 다른 화강암류와 비교하여 $Al_2O_3$, MgO의 함량 및 분화에 따른 변화 경향이 다르게 나타나며, Ba, Sr, Pb, Ni, Cr, Y등 미량원소의 함량에서 뚜렷한 차이를 보인다. 동교리 화강섬록암(DGd)의 지화학적 특징은 높은 $Al_2O_3$, Sr 함량과 높은 Sr/Y La/Yb 비를 가지며, 낮은 Y과 Yb함량과 같은 슬랩용융(slab-melting)으로 생성된 아다카이트에서 흔히 관찰되는 지화학적 특성을 나타낸다. 주성분 및 미량원소의 함량을 살펴보면 동교리화강섬록암은 아다카이트의 판별도로 가장 널리 이용되는 Sr/Y vs. Y 관계도에서 호상열도형ADR(Island Arc Andesite, Dacite, Rhyolite)영역에 도시되는 다른 백악기 화강암류들과 명확히 구분되어 아다카이트 영역에 잘 도시된다. ANK vs. A/CNK과 지구조판별도에서 화강암류의 모마그마는 I-type의 화산호화강암의 특성을 나타내며, 태평양판의 섭입에 의한 압축장응력이 작용하는 대륙연변부에서 생성된 것으로 해석된다. 지화학적특성 및 지구조적 환경을 종합하면 동교리화강섬록암의 아다카이틱한 특성은 섭입슬랩의 용융(해령 섭입에 의한 열로 생성)에 의하여 생성된 마그마와 맨틀 페리도 타이트와의 상호작용 그리고 상승하는 동안 지각물질과의 동화작용 등 복합적인 과정을 겪었을 것으로 추정된다.

• 한국응용과학기술학회지
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• 제21권2호
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• pp.174-181
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• 2004

Multi-walled carbon nanotubes (CNTs) were prepared by thermal chemical vapor deposition (CVD) and microwave plasma chemical vapor deposition (MPCVD) using various combination of binary catalysts with four transition metals such as Fe, Co, Cu, and Ni. In the preparation of CNTs from acetylene precursor by thermal CVD, the CNTs with very high yield of 43.6 % was produced over $Fe-Co/Al_2O_3$. The highest yield of CNTs was obtained with the catalyst reduced for 3 hr and the yield was decreased with increasing reduction time to 5 hr, due to the formation of $FeAl_2O_4$ metal-aluminate. On the other hand, the CNTs prepared by acethylene plasma CVD had more straight, smaller diameter, and larger aspect ratio(L/D) than those prepared by thermal CVD, although their yield had lower value of 27.7%. The degree of graphitization of CNTs measured by $I_d/I_g$ value and thermal degradation temperature were 1.04 and $602^{\circ}C$, respectively.

• 한국수소및신에너지학회논문집
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• 제26권6호
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• pp.507-515
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• 2015

HI decomposition reaction requires a catalyst for the efficient production of hydrogen as a key reaction for hydrogen production in sulfur-iodine thermochemical water-splitting (SI) cycle. As a catalyst used in the reaction, the performance of platinum catalyst is excellent. While, the platinum catalyst is not economical. Therefore, studies of a nickel catalyst that could replace platinum have been carried out. In this study, the characteristics of the catalytic HI decomposition on the amount of loaded nickel (Ni = 0.1, 0.5, 1, 3, 5, 10 wt%) were investigated. As the supported Ni amount increased up to 3 wt%, HI decomposition was found to increase in linear proportion. However, the conversion of $Ni/Al_2O_3$ catalyst loaded above 3 wt% was not linear. It was thought that the different HI decomposition characteristics was caused in the size and metal dispersion of Ni particles of catalyst. The physical property of catalyst before and after HI decomposition reaction was characterized by BET, chemisorption, XRD and SEM analysis.

• Progress in Superconductivity
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• 제10권1호
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• pp.35-39
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• 2008

By using the hybrid physical-chemical vapor deposition (HPCVD) technique, we have fabricated $MgB_2$ thick films on $Al_{2}O_3$ substrates with various impurity layers of Ni, Ti, and SiC. We have found a significant enhancement of the critical current density ($J_c$) for $MgB_2$ films grown on impurity layered substrates, indicating that additional impurity layers were provided as possible pinning sites by chemical doping in $MgB_2$ films. All samples doped by Ni, Ti, and SiC were observed to have high superconducting transition temperatures of 39 - 41 K. The $J_c$ of $MgB_2$ films grown on SiC impurity layered substrates showed three times higher than that of undoped films at high magnetic fields above 1 T.

• 한국광물학회지
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• 제6권2호
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• pp.80-93
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• 1993

Jido kaolin deposits developed in the rhyolitic tuff of Cretaceous are located in the western part of Sinan-gun, Jeonranam-do. Jido kaolin deposits is predominantly composed of pyrophyllite, kaolinite and illite. On the basis of mineral assemblage Jido kaolin deposits can be divided into three alteraion zone from the center of alteration to the margin; kaolinite, kaolinite-pyrophyillite and pyrophyillite zones. Discriminant analysis show that $Al_2O_3$, $K_2O$, $Na_2O$, CaO of major elements are discriminant elements classifying kaolinite, kaolinite-pyrophyllite and pyrophyllite zones, while in case of trace elements Cr, Ni, Sc, Zn, and Zr are discriminant elements. Kaolin deposits has been formed by the hydrothermal alterations of the volcano rocks such as rhyolitic tuff and lapilli tuff, in late cretaceous. On the basis of the results of X-ray diffraction analysis, the deposits can be classified into three types of minerals assemblages; kaolinite, kaolinite-pyrophyllite and pyrophyllite zones. All the assemblages contain quartz and muscovite, but the kaolinite zone contains kaolinite, illite and chlorite, the kaolinite-pyrophyllite zone contains kaolinite, pyrophyllite and the pyrophyllite zone contains illite and pyrite.

• 자원리싸이클링
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• 제10권5호
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• pp.29-35
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• 2001

본 연구는 폐컴퓨터 인쇄회로기판으로부터 Au와 Ag 및 유가금속을 회수하기 위해 수행하였다. 시료는 슈레더를 사용하여 1 mm이하 입자로 분쇄한 후 정전선별하여 약 70%의 부도체를 분리제거하고, 회수된 30%의 도체는 자력선별에 사용하였다. 자력선별에 의해 42%의 자성체는 제거되고 58%의 비자성체를 유가물 침출 원료로 사용하였으며, 비자성체의 Au및 Ag의 함량은 각각 0.227mg/g, 0.697 mg/g 이였다. 회수된 물질로부터 Cu, Fe, Zn, Ni, Al를 침출분리하기 위해 황산과 과산화수소수를 혼합한 침출용매를 사용하였다. 2.0M 황산, 0.2M과산화수소수, 반응온도 $85^{\circ}C$에서 95%이상의 Cu, 로n, Fe, Ni, Al를 침출 할 수 있었으며, Au와 Ag는 침출되지 않았다. 반면에 황산침출 후 잔사로부터 Au, Ag의 선택적인 침출을 위해 혼합용매(0.2M(NH$_4$)$_2$S$_2$O$_3$, 0.02M $CusO_4$,0.4M NH$_4$OH)를 사용하였을 때 Ag는 100%, Au는 95%이상 침출하였다 또한 최종 잔사로부터 Pb침출은 NaCl용액을, Sn침출은 황산용액을 사용하였으며 침출율은 각각 95%, 98%를 나타냈다.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2004년도 학술대회지
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• pp.66-74
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• 2004

The sliding wear behavior of $ZrO_2-22wt\%MgO\;(MZ)\;and\;ZrO_2-8wt\%Y_2O_3\;(YZ)$ deposited on a casting aluminum alloy with bond layer (NiCrCoAlY) by plasma spray against an SiC ball was investigated under dry test conditions at room temperature. At all load conditions, the wear mechanisms of the MZ and the YZ coatings were almost the same. The wear mechanisms involved the forming of a smooth film by material transferred on the sliding surface and pullout. The wear rate of the MZ coating was less than that of the YZ coating. With an increase normal load the wear rate of the studied coatings increased. The SEM was used to examine the sliding surfaces and elucidate likely wear mechanisms. The EDX analysis of the worn surface indicated that material transfer was occurred from the SiC ball to the disk. It was suggested that the material transfer played an important role in the wear performance.