• Proceedings of the Materials Research Society of Korea Conference
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• 2000.11a
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• pp.95-95
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• 2000

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 1995.11a
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• pp.16-16
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• 1995

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 1996.04a
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• pp.23-23
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• 1996

• Korean Journal of Materials Research
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• v.29 no.5
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• pp.328-335
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• 2019

Nb-doped $TiO_2$(NTO) coated NiCrAl alloy foam for hydrogen production is prepared using ultrasonic spray pyrolysis deposition(USPD) method. To optimize the size and distribution of NTO particles based on good physical and chemical stability, we synthesize particles by adjusting the weight ratio of the Nb precursor solution(5 wt%, 10 wt% and 15 wt%). The morphological, chemical bonding, and structural properties of the NTO coated NiCrAl alloy foam are investigated by X-ray diffraction(XRD), X-ray photo-electron spectroscopy(XPS), and Field-Emission Scanning Electron Microscopy(FESEM). As a result, the samples of controlled Nb weight ratio exhibit a common diffraction pattern at ${\sim}25.3^{\circ}$, corresponding to the(101) plane, and have chemical bonding(O-Nb=O) at 534 eV. The NTO particles with the optimum weight ratio of N (10 wt%) show a uniform distribution with a size of ~18.2-21.0 nm. In addition, they exhibit the highest corrosion resistance even in the electrochemical stability estimation. As a result, the introduction of NTO coated NiCrAl alloy foam by USPD improves the chemical stability of the NiCrAl alloy foam by protecting the direct electrochemical reaction between the foam and the electrolyte. Thus, the optimized NTO coating can be proposed for excellent protection of NiCrAl alloy foam for hydrocarbon-based steam methane reforming(SMR).

• Journal of the Microelectronics and Packaging Society
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• v.30 no.2
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• pp.60-64
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• 2023

In this study, the electrical contact resistance characteristics between graphene and metals, which is one of important factors for the performance of graphene-based devices, were compared. High-quality graphene was synthesized by chemical vapor deposition (CVD) method, and Al, Cu, Ni, and Ti as electrode materials were deposited on the graphene surface with equal thickness of 50 nm. The contact resistances of graphene transferred to SiO₂/Si substrates and metals were measured by the transfer length method (TLM), and the average contact resistances of Al, Cu, Ni, and Ti were found to be 345 Ω, 553 Ω, 110 Ω, and 174 Ω, respectively. It was found that Ni and Ti, which form chemical bonds with graphene, have relatively lower contact resistances compared to Al and Cu, which have physical adsorption properties. The results of this study on the electrical properties between graphene and metals are expected to contribute to the realization of high-performance graphene-based devices including electronics, optoelectronic devices, and sensors by forming low contact resistance with electrodes.

• Corrosion Science and Technology
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• v.15 no.3
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• pp.129-134
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• 2016

The effects of Ti on the high temperature oxidation of Ni-based superalloys were investigated by cyclic oxidation at $850^{\circ}C$ and $1000^{\circ}C$. The oxide scale formed at $850^{\circ}C$ consists of $Cr_2O_3$, $Al_2O_3$, and $NiCr_2O_4$ layers, while a continuous $Al_2O_3$ layer was formed at $1000^{\circ}C$. The oxidation rate of the alloy with higher Ti content was higher than the alloy with less Ti content at $850^{\circ}C$, possibly due to the increase in the metal vacancy concentration in the $Cr_2O_3$ layer involved by incorporation of $Ti^{4+}$. However, Ti improved the oxidation resistance of the superalloy at $1000^{\circ}C$ by reducing oxygen vacancy concentration in $Al_2O_3$ layer.

• Bulletin of the Korean Chemical Society
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• v.28 no.10
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• pp.1763-1770
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• 2007

Strong solid acid catalysts, NiO/Al2O3-TiO2/WO3 for ethylene dimerization were prepared by the addition of Al2O3 and the modification with WO3. The acid sites and acid strength were increased by the inductive effect of WO3 species bonded to the surface of catalysts. The larger the dispersed WO3 amount, the higher both the acidity and catalytic activity for ethylene dimerization. The addition of Al2O3 to TiO2 up to 5 mol% enhanced acidity and catalytic activity gradually due to the interaction between Al2O3 and TiO2 and consequent formation of Al-O-Ti bond.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2001.04a
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• pp.687-691
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• 2001

Al alloy matrix composite with TiNi shape memory fiber as reinforcement has been fabricated by hot pressing to investigate mechanical properties. The stress-strain behavior of the composites was evaluated at temperatures between 363K and room temperature as a function of pre-strain by using experimental and finite element analysis, and both cases showed that the tensile stress at 363K was higher than that of the room temperature. Especially, the tensile stress of this composite increases with increasing the amount of pre-strain, and it also depends on the volume fraction of fiber and heat treatment. The smartness of the composite is given due to the shape memory effect of the TiNi fiber which generates compressive residual stress in the matrix material when heated after being pre-strained.

• Journal of Mechanical Science and Technology
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• v.18 no.3
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• pp.453-459
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• 2004

TiNi/ Al6061 shape memory alloy (SMA) composite was fabricated by hot press method to investigate the microstructure and mechanical properties. Interface bonding between TiNi reinforcement and A1 matrix was observed by using SEM and EDS. Pre-strain was imposed to generate compressive residual stress inside composite. A tensile test for specimen, which under-went pre-strain, was performed at high temperature to evaluate the variation of strength and the effect of pre-strain. It was shown that interfacial reactions occurred at the bonding between matrix and fiber, creating two inter-metallic layers. And yield stress increased with the amount of pre-strain. Acoustic Emission technique was also used to nondestructively clarify the microscopic damage behavior at high temperature and the effect of pre-strain of TiNi/ Al6061 SMA composite.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.21 no.3
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• pp.405-413
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• 1997

In the present paper, it is attempted to reconfirm the "Intelligent" material properties using both the sintered TiNi/Al(1100) matrix composite made by powder metallurgy method and the squeeze-casted TiNi/Al6061 specimens. A metal matrix composite is, its fault has been considered to deteriorate a strength of composite by heating residual stress of the matrix. Therefore, it is necessary to remove a tensile residual stress, to produce the strength of a composite better. On the contrary, if compressive residual stress happens in matrix of composite in place of tensile residual stress, it will make the strength of composite better. So that, this paper introduce the development of a high strength of composite, by using compressive residual stress well, on the study. By using these specimens, shape memory strengthening effects in tensile strength and fatigue crack propagation above inverse transformation temperature of TiNi fiber were investigated. We occurs the prestrain and volume fraction for to discuss the effects of a composite strength. Moreover, by SEM observation, the effect of the residual stress at the interface between Al matrix and TiNi fiber and some brittle precipitation layers such as inter metallic compounds on fracture mechanisms was discussed metallurgically.urgically.