• Title/Summary/Keyword: New alternative fuel

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Degradation Properties and Production of Fuels from Cellulose - Solvolysis - (셀룰로오스의 분해특성 및 연료물질 생성[II] - 용해분해 반응 -)

  • Lee, Jong-Jib;Lee, Byung-Hak
    • Journal of Hydrogen and New Energy
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    • v.16 no.2
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    • pp.159-169
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    • 2005
  • Cellulose, consisted of 45 wt% in wood, is usable as fuels and heavy oil additives if depolymerized to monomer unit, because the chemical structures are similar to high octane materials found in gasoline. In this study, thermochemical degradation by solvolysis reaction of cellulose such as the effect of reaction temperature, reaction time and type of solvent on conversion yield and degradation products were investigated. It was found that the effectiveness of the solvent on the sovolysis reaction was as follows; acetone>n-butanol>tetralin. When acetone was used as a solvent, the highest cellulose conversion was observed to be 91.8% at 500$^{\circ}C$, 40min. Combustion heating value of liquid products from thermochemical conversion processes was in the range of 7,330${\sim}$7,410cal/g. The energy yield and mass yield in acetone-solvolysis of cellulose was as high as 66.8% and 37.0 g oil/100g raw material after 40min of reaction at 400$^{\circ}C$. Various aliphatic and aromatic compounds were detected in the cellulose solvolysis products. The major components of the solvolysis products, that could be used as fuel, were mesityl oxide, mesitylene, isophorone.

Degradation Properties and Production of Fuels of Cellulose - Pyrolysis-Liquefaction - (셀룰로오스의 분해특성 및 연료물질 생성 (I) -열분해·액화반응-)

  • Lee, Jong-Jip;Lee, Byeong-Hak
    • Journal of Hydrogen and New Energy
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    • v.15 no.4
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    • pp.333-340
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    • 2004
  • In this study, thermochemical degradation by pyrolysis-liquefaction of cellulose, the effects of reaction time, reaction temperature, conversion yield, degradation properties and degradation products were investigated . Experiments were performed in a tube reactor by varying reaction time from 20 to 80 min at $200{\sim}500^\circ{C}$. Combustion heating value of liquid products from thermochemical conversion processes of cellulose was in the range of 6,920~6,960cal/g. After 40min of reaction at $400^\circ{C}$ in pyrolysis-liquefaction of cellulose, the energy yield and mass yield was as high as 54.3% and 34.0g oil/100g raw material, respectively. The liquid products from pyrolysis-liquefaction of cellulose contained various kinds of ketones, phenols and furans. ketones and furans could be used as high-octane-value fuels and fuel additives. However, phenols are not valuable as fuels.

Production of Fuels from an Agricultural by-Product Biomass (농부산물 바이오매스를 이용한 연료물질의 생성)

  • Lee, Jong-Jib
    • Journal of Hydrogen and New Energy
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    • v.18 no.1
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    • pp.85-94
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    • 2007
  • Rice straw, produced as an agricultural by-product, is usable biomass as fuels if depolymerized to monomer unit, because the chemical structure are similar to high octane materials found in gasoline. In this study, parameters of thermochemical degradation by solvolysis reaction of rice straw such as the effect of reaction temperature, reaction time and type of solvent on conversion yield and degradation products were investigated. It was found that the effectiveness of the solvent on the solvolysis reaction was as follows; acetone>cresol>butanol. When acetone was used as a solvent, the highest rice straw conversion was observed to be 91.5% at $500^{\circ}C$, 40 min. Combustion heating value of liquid products from thermochemical conversion processes was in the range of 7,380 cal/g. The energy yield and mass yield in acetone-solvolysis of rice straw was as high as 69.0% and 38.2 g-oil/100g-raw material after 40 min of reaction at $350^{\circ}C$. Various aliphatic and aromatic compounds were detected in the rice straw solvolysis products. The major components of the solvolysis products, that could be used as fuel, were 4-methyl-2-pentanone, 3,5,5-trimethyl-2-cyclopentan-1-one as ketones.

Effects of Cooled EGR on Exhaust Emission Characteristics of DI DME Engine (대체에너지 DME를 사용하는 직접분사엔진의 배기특성에 미치는 Cooled EGR의 영향)

  • Pyo, Youngduk;Nam, Sanghoon;Kim, Gangchul;Kim, Youngkil;Lee, Yongjae
    • Journal of Hydrogen and New Energy
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    • v.14 no.2
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    • pp.138-145
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    • 2003
  • There are high expectations for DME(Dimethyl Ether) as a new alternative fuel for diesel engine. Compared with the conventional diesel engine, nearly zero soot emission and high thermal efficiency have been reported from DME fuelled CI engines. However, higher NOx emission is one of the disadvantages from DME Engines. In the present study, cooled EGR(Exhaust Gas Recirculation) was applied to DME engine modified from conventional Dl diesel engine, and effects of EGR were examined under various EGR temperature. Finally, it was concluded that the cooled EGR is an effective solution to reduce NOx emission from DME engine.

Heat Balance for the coal substitute materials in the Ferronickel manufacturing process (페로니켈 공정의 석탄대체 물질에 대한 열정산)

  • Kim, Hiyoul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.161.2-161.2
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    • 2010
  • 페로니켈 제조 공정에 있어서 석탄의 비중은 총 에너지원 중 70%에 상당하며, 온실가스 배출 또한 65%에 달한다. 이에 석탄을 대체할 물질로서 RPF, RDF, Biomass, TDF 등을 고려하였으며, 자체 개발한 열정산 프로그램을 활용하였다. 해석결과 석탄 대체물질의 사용할 경우 페로니켈 제조공정의 에너지 비용을 상당량 저감할 수 있을 것으로 기대된다.

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High performance switched reluctance drives with wide field weakening range

  • Marquardt Rainer;Hiller Marc
    • Proceedings of the KIPE Conference
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    • 2001.10a
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    • pp.779-784
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    • 2001
  • For electrical vehicles, switched reluctance drives present a promising alternative-compared to asynchronous and synchronous (permanent magnet) concepts. For these applications, a very wide field weakening range is a key issue. Other requirements include high torque output from a small machine and low current ripple at the DC-side without the use of bulky filters - when powered from fuel cells or advanced Lithium-Ion-batteries. A new converter and control strategy according to these requirements is presented and compared to existing designs. The comparison is done for a drive system with a continuous power rating of 30 to 40 kW.

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Performance and Safety Analysis of Marine Solid Oxide Fuel Cell Power System (선박동력용 SOFC시스템의 성능 및 안전성 해석)

  • Kim, Myoung-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.2
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    • pp.233-243
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    • 2009
  • The strengthened regulations for atmospheric emissions from ships like MARPOL Annex VI have caused a necessity of new, alternative power system in ships for the low pollutant emissions and the high energy efficiency. This paper attempts to investigate the configuration of SOFC system for LNG tanker taking into account the safety and to analyze the influence of design parameters on the system performance. The simulation results provide the basic data for the design and efficiency improvement of SOFC system and indicate the guidelines for the safe system operation.

Performance and Safety Analysis of Marine Solid Oxide Fuel Cell and Gas Turbine Hybrid Power System (under Conditions of Turbine Cooling and Constant TIT) (선박동력용 SOFC/GT 하이브리드시스템의 성능 및 안전성 해석 (터빈 냉각 및 TIT 일정 조건을 중심으로))

  • Kim, Myoung-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.4
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    • pp.484-496
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    • 2009
  • The strengthened regulations for atmospheric emissions from ships like MARPOL Annex VI have caused a necessity of new, alternative power system in ships for the low pollutant emissions and the high energy efficiency. This paper attempts to investigate the configuration of SOFC/GT hybrid power system for LNG tanker taking into account the safety and to analyze the influence of design parameters on the system performance. The simulation results provide the basic data for the design and efficiency improvement of SOFC/GT hybrid system and indicate the guidelines for the safe system operation.

Characteristics of Bio-diesel according to Irradiation for Ultrasonic Energy (초음파 에너지 조사에 따른 바이오 디젤 특성)

  • Park, Chungyeol;Choi, Dooseuk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.2
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    • pp.214-220
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    • 2015
  • Since resources of fossil fuels are limited, development of alternative energies is emphasized and research on new-regenerative energy is actively in progress worldwide. In present research, physical and chemical characteristics of mixed fuel are analyzed in detail for the different mixture rate of conventional and bio-diesel and ultrasonic irradiation time. Experimental setup consists of ultrasonic generator, vibrator, horn, and reflector. Various physical and chemical characteristics of fuel are investigated for volumetric mixture rate of bio-diesel from 0 to 100%. As results, viscosity and surface tension is increased as mixture rate of bio-diesel is increased. Also, molecular splits and reunions are increased and decreased repeatedly after some period of time as ultrasonic energy irradiation time is increased. As conclusion of experiments, Olefin rate, Branch index, and Aromatic rate are influenced by ultrasonic irradiation time.

A Numerical Study of Combustion Characteristics for HCCI Engine with Detailed Diesel Surrogate Chemical Mechanism (Diesel Surrogate 상세 반응 기구를 이용한 HCCI 엔진의 연소 특성에 관한 수치해석 연구)

  • Lee, Won-Jun;Lee, Seung-Ro;Lee, Chang-Eon
    • Journal of the Korean Society of Combustion
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    • v.16 no.2
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    • pp.9-15
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    • 2011
  • Homogeneous charge compression ignition(HCCI) is the best concept able to provide low NOx and PM in diesel engine emissions. This new alternative combustion process is mainly controlled by chemical kinetics in comparison with the conventional combustion in internal combustion engine. In this paper, combustion characteristics of HCCI engine with suggested diesel surrogate(heptane/toluene mixture fuel) reaction mechanism were numerically investigated by heptane/toluene mixture ratio and EGR ratio. As results, the ignition timing became faster with increasing of heptane, and an initial oxidation and the ignition timing of the mixture fuel were affected by heptane and toluene, respectively.