• Title/Summary/Keyword: Network diameter

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A Study on the Thermal and Chemical Properties of Carbon Nanotube Reinforced Nanocomposite in Power Cables

  • Yang, Sang-Hyun;Jang, Hyeok-Jin;Park, Noh-Joon;Park, Dae-Hee;Yang, Hoon;Bang, Jeong-Hwan
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.6
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    • pp.217-221
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    • 2009
  • The use of the carbon nanotube (CNT) is superior to the general powder state materials in their thermal and chemical properties. Because its ratio of diameter to length (aspect ratio) is very large, it is known to be a type of ideal nano-reinforcement material. Based on this advantage, the existing carbon black of the semiconductive shield materials used in power cables can acquire excellent properties by the use of a small amount of CNTs. Therefore, we fabricated specimens using a solution mixing method. We investigated the thermal properties of the CNT, such as its storage modulus, loss modulus, and its tan delta using a dynamic mechanical analysis 2980. We found that a high thermal resistance level is demonstrated by using a small amount of CNTs. We also investigated the chemical properties of the CNT, such as the oxidation reaction by using Fourier transform infrared spectroscopy (FT-IR) made by Travel IR. In the case of the FT-IR tests, we searched for some degree of oxidation by detecting the carboxyl group (C=O). The results confirm a tendency for a high cross-linking density in a new network in which the CNTs situated between the carbon black constituent molecules show a bond using similar constructive properties.

Structure damage estimation due to tunnel excavation based on indoor model test

  • Nam, Kyoungmin;Kim, Jungjoo;Kwak, Dongyoup;Rehman, Hafeezur;Yoo, Hankyu
    • Geomechanics and Engineering
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    • v.21 no.2
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    • pp.95-102
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    • 2020
  • Population concentration in urban areas has led traffic management a central issue. To mitigate traffic congestions, the government has planned to construct large-cross-section tunnels deep underground. This study focuses on estimating the damage caused to frame structures owing to tunnel excavation. When constructing a tunnel network deep underground, it is necessary to divide the main tunnel and connect the divergence tunnel to the ground surface. Ground settlement is caused by excavation of the adjacent divergence tunnel. Therefore, predicting ground settlement using diverse variables is necessary before performing damage estimation. We used the volume loss and cover-tunnel diameter ratio as the variables in this study. Applying the ground settlement values to the settlement induction device, we measured the extent of damage to frame structures due to displacement at specific points. The vertical and horizontal displacements that occur at these points were measured using preattached LVDT (Linear variable differential transformer), and the lateral strain and angular distortion were calculated using these displacements. The lateral strain and angular distortion are key parameters for structural damage estimation. A damage assessment chart comprises the "Negligible", "Very Slight Damage", "Slight Damage", "Moderate to Severe Damage", and "Severe to Very Severe Damage" categories was developed. This table was applied to steel frame and concrete frame structures for comparison.

Performance Analysis of a $CO_2$ Two-Stage Twin Rotary Compressor ($CO_2$ 2단 트윈 로타리 압축기 성능해석)

  • Kim, Woo-Young;Ahn, Jong-Min;Kim, Hyun-Jin;Cho, Sung-Oug
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.1
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    • pp.19-27
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    • 2007
  • Analytical investigation on the performance of a two stage twin rotary compressor for $CO_2$ heat pump water heater system has been carried out. A computer simulation program was made based on analytical models for gas compression in control volumes, leakages among neighboring volumes, and dynamics of moving elements of the compressor. Calculated cooling capacity, compressor input, and COP were well compared to those of experiments over the compressor speeds tested. For the operating condition of suction pressure of 3 MPa, and discharge pressure of 9 MPa, and compressor inlet temperature of $35^{\circ}C$, the compressor efficiency was calculated to be 80.2%: volumetric, adiabatic, and mechanical efficiencies were 88.3%, 93.2%, and 92.7%, respectively. For the present compressor model, volumetric and adiabatic efficiencies of the second stage cylinder were lower by about $6{\sim}7%$ than those of the first stage mainly due to the smaller discharge port at the second stage. Parametric study on the discharge port size showed that the compressor performance could be improved by 3.5% just by increasing the discharge port diameter by 20%.

Microstructure of Non-Sintered Inorganic Binder using Phosphogypsum and Waste Lime as Activator

  • Kim, Ji-Hoon;An, Yang-Jin;Mun, Kyung-Ju;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.305-312
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    • 2018
  • This study is about the development of a non-sintered binder (NSB) which does not require a sintering process by using the industrial by-products Phosphogypsum (PG), Waste Lime (WL) and Granulated Blast Furnace Slag (GBFS). In this report, through SEM analysis of the NSB paste hardening body, micropore analysis of paste using the mercury press-in method and microstructure observation were executed to consider the influence of the formation of the pore structure and the distribution of pore volume on strength, and the following conclusions were reached. 1) Pore structure of NSB paste of early age is influenced by hydrate generation amount by GBFS and activator. 2) Through observing the internal microstructure of NSB binder paste, it was found that the strength expression at early age due to hydration reaction was achieved with a large amount of ettringite serving as the frame with C-S-H gel generated at the same time. It was confirmed that C-S-H gel wrapped around ettringite, and as time passed, the amount generated continually increased, and C-S-H gel tightly filled the pores of hardened paste, forming a dense network-type web structure. 3) For NSB-type cement, the degree of formation of gel pores below $10{\mu}m$ had a greater influence on strength improvement than simple pore reduction by charging capillary pores, and the pore size that had the greatest effect on strength was micropores with diameter below $10{\mu}m$.

Resonance May Elucidate New Bone Formation Induced by Low amplitude and High frequency Mechanical Stimuli (고주파 미세자극에 의한 뼈의 생성에 관한 모델링)

  • Yoon, Young June;Kim, Moon-Hwan;Bae, Cheol-Soo
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.1 no.3
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    • pp.27-32
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    • 2008
  • Bone is a self-assembly material. It is known that the low amplitude and high frequency mechanical stimulus, which is much less amplitude but higher frequency than those induced by the normal activity, can induce new bone formation. The vibrating resonance is employed to elucidate why new bone is formed by this kind of mechanical stimulus. For example, as 30 Hz and $5{\mu}{\epsilon}$ mechanical stimulus is applied at the wall of canaliculus (the tiny tube type pathway of bone fluid flow and the diameter of canaliculus is less than 200nm), the osteocytic cell membrane experiences $1,000{\mu}{\epsilon}$ strain due to the vibrating resonance. Two experiments will follow after this pilot study; (1) observing the MAPK pathway of osteocytes by using in-vitro cell culture and (2) visualizing the actin filament network in the osteocytes by using the imaging technique, such as confocal laser scanning microscope.

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Hydrogels with diffusion-facilitated porous network for improved adsorption performance

  • Pei, Yan-yan;Guo, Dong-mei;An, Qing-da;Xiao, Zuo-yi;Zhai, Shang-ru;Zhai, Bin
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2384-2393
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    • 2018
  • Porous alginate-based hydrogel beads (porous ABH) have been prepared through a facile and sustainable template-assisted method using nano-calcium carbonate and nano-$CaCO_3$ as pore-directing agent for the efficient capture of methylene blue (MB). The materials were characterized by various techniques. The sorption capacities of ABH towards MB were compared with pure sodium alginate (ABH-1:0) in batch and fixed-bed column adsorption studies. The obtained adsorbent (ABH-1:3) has a higher BET surface area and a smaller average pore diameter. The maximum adsorption capacity of ABH-1:3 obtained from Langmuir model was as high as $1,426.0mg\;g^{-1}$. The kinetics strictly followed pseudo-second order rate equation and the adsorption reaction was effectively facilitated, approximately 50 minutes to achieve adsorption equilibrium, which was significantly shorter than that of ABH-1:0. The thermodynamic parameters revealed that the adsorption was spontaneous and exothermic. Thomas model fitted well with the breakthrough curves and could describe the dynamic behavior of the column. More significantly, the uptake capacity of ABH-1:3 was still higher than 75% of the maximum adsorption capacity even after ten cycles, indicating that this novel adsorbent can be a promising adsorptive material for removal of MB from aqueous solution under batch and continuous systems.

Evaluation of Thermal Conductivity of Porous TiO2-SiO2-Base Thermal Insulation (다공성 TiO2-SiO2 복합 단열재의 열전도율 평가)

  • Choi, Byugchul;Kim, Jon-Ho;Kim, Jon Beom;Jung, Woonam;Lee, Sang-Hyun
    • Journal of Institute of Convergence Technology
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    • v.8 no.1
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    • pp.21-25
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    • 2018
  • We developed nano-porous $TiO_2-SiO_2$ composites (commercial name : PTI, porous titania insulator) with low thermal conductivity as thermal insulating material as well as function of photocatalyst. The objectives of this paper are, firstly, to evaluate of the thermal conductivity of the PTI powder in the temperature range from -160 to $250^{\circ}C$, secondly to evaluate of thermal conductivities of insulation materials that is applied PTI powder. The structure of the PTI powder that has the pores size of 20-30 nm and the particle diameter of 2-10 nm. The PTI had a high surface area of $400m^2/g$ and a mean pore size of $45{\AA}$, which was fairly uniform. The thermal conductivity was measured by GHP(guarded hot plate) method and HFM(heat flux method). The PTI structure is a three-dimensional network nano-structures composed by a pearl-necklace that involved a precious stone in the center of the necklace. The thermal conductivities of PTI-PX powder by the GHP and HFM were 0.0366 W/m.K, 0.0314 W/m.K at $20^{\circ}C$, respectively. This is similar to values that are proportional to the square of the absolute temperature of the thermal conductivity of static air. The thermal conductivities of insulating sheets coated with PTI powder were similar results with that of the PTI powder.

Microstructure and Mechanical Property of TiFe Compounds with Zr or Ce Prepared at Different Solidification Rates (TiFe금속간 화합물의 Zr과 Ce첨가와 냉각속도에 따른 응고 조직 변화 및 기계적 특성)

  • No, Hye-In;Choi, Chang-Wan;Yi, Seonghoon
    • Journal of Korea Foundry Society
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    • v.39 no.2
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    • pp.21-25
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    • 2019
  • Microstructural and corresponding hardness changes of TiFe compounds with Zr (0~6 at%) or Ce (0~3 at%) were studied using samples prepared at different solidification rates. In arc-melted (TiFe)-Zr samples, the $Fe_{23}$ $Zr_6$ and $(Ti,\;Zr)_2Fe$ phases formed in the TiFe matrix, while in the (TiFe)-Ce sample, the $CeO_2$ phase formed along the grain boundary of the TiFe matrix. As the Zr content was increased, the volume fractions of the $Fe_{23}$ $Zr_6$ and $(Ti,\;Zr)_2Fe$ phases increased, forming a network structure. Accordingly, the hardness values of the samples also increased. With a small addition of Ce of approximately 0.1 at%, the as-cast microstructure could be effectively refined, reducing the average grain boundary diameter from ${\sim}100{\mu}m$ to ${\sim}14{\mu}m$. In the rapidly solidified sample prepared through a melt-spinning method, the constituent phases were identical to those of the arc-melted samples while the grains were refined. The microstructural changes of TiFe alloys can affect the hydrogen storage ability as well as the mobility of the hydrogen atoms in the alloys.

Evaluation on Sensitivity and Approximate Modeling of Fire-Resistance Performance for A60 Class Deck Penetration Piece Using Heat-Transfer Analysis and Fire Test

  • Park, Woo Chang;Song, Chang Yong
    • Journal of Ocean Engineering and Technology
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    • v.35 no.2
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    • pp.141-149
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    • 2021
  • The A60 class deck penetration piece is a fire-resistance apparatus installed on the deck compartment to protect lives and to prevent flame diffusion in the case of a fire accident in a ship or offshore plant. In this study, the sensitivity of the fire-resistance performance and approximation characteristics for the A60 class penetration piece was evaluated by conducting a transient heat-transfer analysis and fire test. The transient heat-transfer analysis was conducted to evaluate the fire-resistance design of the A60 class deck penetration piece, and the analysis results were verified via the fire test. The penetration-piece length, diameter, material type, and insulation density were used as the design factors (DFs), and the output responses were the weight, temperature, cost, and productivity. The quantitative effects of each DF on the output responses were evaluated using the design-of-experiments method. Additionally, an optimum design case was identified to minimize the weight of the A60 class deck penetration piece while satisfying the allowable limits of the output responses. According to the design-of-experiments results, various approximate models, e.g., a Kriging model, the response surface method, and a radial basis function-based neural network (RBFN), were generated. The design-of-experiments results were verified by the approximation results. It was concluded that among the approximate models, the RBFN was able to explore the design space of the A60 class deck penetration piece with the highest accuracy.

A Study on Purification Process of Sialic Acid from Edible Bird's Nest Using Affinity Bead Technology (식용 제비집으로부터 비극성 비드기술을 활용한 시알산의 분리정제방법에 관한 연구)

  • Kim, Dong-Myong;Jung, Ju-Yeong;Lee, Hyung-Kon;Kwon, Yong-Sung;Baek, Jin-Hong;Han, In-Suk
    • Journal of Marine Bioscience and Biotechnology
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    • v.12 no.2
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    • pp.81-90
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    • 2020
  • Sialic acid, which is contained in about 60-160 mg/kg in the edible bird's nest (EBN), is known to facilitate in the proper formation of synapses and improve memory function. The objective of this study is to extract effectively the sialic acid from edible bird's nest using affinity bead technology (ABT). After preparing the non-polar polymeric bead "KJM-278-28A" having a porous network structure, and then desorbed sialic acid was concentrated and dried. The analysis of the physicochemical properties of bead "KJM-278-28A" showed that the particle size was 400-700 ㎛, the moisture holding capacity was 67-70%, the surface area (BET) was 705-900 ㎡/g, and the average pore diameter 70-87 Å. The adsorption capacity of the bead "KJM-278-28A" for sialic acid was shown a strong physical force to bind sialic acid to the bead surface of 400 mg/L. In addition, as a result of analyzing the adsorption and desorption effects of sialic acid on water, ethanol, and 10% ethanol on the bead, it was confirmed that desorption effectively occurs from the beads when only ethanol is used. As a result of HPLC measurement of the separated sialic acid solution, a total of four sialic acid peaks of N-acetyl-neuraminic acid (Neu5Ac), α,β-anomer of Neu5Ac and N-glycoly-neuraminic acid were identified. Through these results, it was confirmed that it is possible to separate sialic acid from EBN extract with efficient and high yield when using ABT.