• 제목/요약/키워드: Negative temperature coefficient

검색결과 245건 처리시간 0.025초

(1-x)MgxSr$TiO_3$(x=0.03~0.04) 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of the (1-x)MgxSr$TiO_3$(x=0.03~0.04) ceramics)

  • 최의선;이문기;류기원;배선기;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.547-550
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    • 2000
  • The (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.03~0.04) ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were 125$0^{\circ}C$~135$0^{\circ}C$, 2hr., respectively. From the X-ray diffraction patterns, it was found that the perovskite SrTiO$_3$ and ilmenite MgTiO$_3$ structures coexisted in the (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.03~0.04) ceramics. The dielectric constant($\varepsilon$$_{r}$) was increased with addition of SrTiO$_3$. The temperature coefficient of resonant frequency($\tau$$_{f}$) was gradually varied from negative value to the positive value with increasing the SrTiO$_3$. The negative temperature coefficient of resonant frequency of the magnesium titanate was adjusted to near zero at x=0.036, where the dielectric constant, quality factor, and $\tau$$_{f}$ were 20.65, 95120, and +1.3ppm/$^{\circ}C$, respectively. The temperature stability of qualify factor in (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.03~0.04) ceramics increased as the amount of MgTiO$_3$./TEX>.

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Analyses and improvement of fuel temperature coefficient of rock-like oxide fuel in LWRs from neutronic aspect

  • Shelley, Afroza
    • Nuclear Engineering and Technology
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    • 제52권6호
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    • pp.1156-1163
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    • 2020
  • Fuel temperature coefficient (FTC) of PuO2+ZrO2 (ROX) fueled LWR cell is analyzed neutronically with reactor- and weapons-grade plutonium fuels in comparison with a U-free PuO2+ThO2 (TOX), and a conventional MOX fuel cells. The FTC value of a ROX fueled LWR is smaller compared to a TOX or a MOX fueled LWRs and becomes extremely positive especially, at EOL. This is because when fuel temperature is increased, thermal neutron spectrum is shifted to harder, which is extreme at EOL in ROX fuel than that in TOX and MOX fuels. Consequently at EOL, 239Pu and 241Pu contributes to positive fuel temperature reactivity (FTR) in ROX fuel, while they have negative contribution in TOX and MOX fuels. The FTC problem of ROX fuel is mitigated by additive ThO2, UO2 or Er2O3. In ROX-additive fuel, the atomic density of fissile Pu becomes more than additive free ROX fuel especially at EOL, which is the main cause to improve the FTC problem. The density of fissile Pu is more effective to decrease the thermal spectrum shifts with increase the fuel temperature than additive ThO2, UO2 or Er2O3 in ROX fuel.

Co1-xMgxO세라믹스의 MgO함량에 따른 전기적 성질 및 산소가스 감지특성 (Effect of MgO Contents on Electrical Properties and Oxygen Sensing Characteristics in Co1-xMgxO Ceramics)

  • 최현국;이덕동;조상희
    • 한국세라믹학회지
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    • 제26권1호
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    • pp.7-12
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    • 1989
  • The effects of composition ratios and sintering conditions in Co1-xMgxO ceramics on the sintering characteristics, electrical properties and oxygen sensing characteristics were investigated. In the same sintering conditions, porosity decreased with increase of MgO contents. The relationshiop of temperature and resistance in Co1-xMgxO ceramics showed NTC(negative temperature coefficient) characteristics at the temperature range from $700^{\circ}C$ to 1,10$0^{\circ}C$. In the case of pure CoO, however, the PTC(positive temperature coefficient) characteristics were shown over about 90$0^{\circ}C$. The electrical conductivity of Co1-xMgxO ceramics decreased proportionally with decrease of oxygen partial pressure at the range from 1 to 10-4(atm). Particularly, Co0.5Mg0.5O ceramics showed the highest sensitivity to oxygen gas.

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FAST (floating absorber for safety at transient) for the improved safety of sodium-cooled burner fast reactors

  • Kim, Chihyung;Jang, Seongdong;Kim, Yonghee
    • Nuclear Engineering and Technology
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    • 제53권6호
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    • pp.1747-1755
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    • 2021
  • This paper presents floating absorber for safety at transient (FAST) which is a passive safety device for sodium-cooled fast reactors with a positive coolant temperature coefficient. Working principle of the FAST makes it possible to insert negative reactivity passively in case of temperature rise or voiding of coolant. Behaviors of the FAST in conventional oxide fuel-loaded and metallic fuel-loaded SFRs are investigated assuming anticipated transients without scram (ATWS) scenarios. Unprotected loss of flow (ULOF), unprotected loss of heat sink (ULOHS), unprotected transient overpower (UTOP) and unprotected chilled inlet temperature (UCIT) scenarios are simulated at end of life (EOL) conditions of the oxide and the metallic SFR cores, and performance of the FAST to improve the reactor safety is analyzed in terms of reactivity feedback components, reactor power and maximum temperatures of fuel and coolant. It is shown that FAST is able to improve the safety margin of conventional burner-type SFRs during ULOF, ULOHS, UTOP and UCIT.

MgTiO$_3$-SrTiO$_3$세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of the MgTiO$_3$-SrTiO$_3$Ceramics)

  • 최의선;이문기;정장호;김강;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.843-846
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    • 2000
  • The (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.02∼0.08) ceramics were fabricated by conventional mixed oxide method. The sintering temperature and time were 1250$^{\circ}C$∼1400$^{\circ}C$, 2hr., respectively. The structural and microwave dielectric properties were investigated by varying sintering temperature and composition ratio. In the (1-x)MgTiO$_3$-xSrTiO$_3$(x=0.02) ceramics, the cubic SrTiO$_3$and hexagonal MgTiO$_3$phases were coexisted. The dielectric constant was increased and the temperature coefficient of resonant frequency( $\tau_f$) was decreased with addition of SrTiO$_3$. The temperature coefficient of resonant frequency($\tau_f$) was gradually varied from negative value to positive value with increasing the SrTiO$_3$.

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연속 조성 확산 증착 방법을 통한 저항 온도 계수의 튜닝 (Tuning for Temperature Coefficient of Resistance Through Continuous Compositional Spread Sputtering Method)

  • 박지훈;선정우;최우진;진상준;김진환;전동호;윤생수;천재일;임진주;조욱
    • 한국전기전자재료학회논문지
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    • 제37권3호
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    • pp.323-327
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    • 2024
  • The low-temperature coefficient of resistance (TCR) is a crucial factor in the development of space-grade resistors for temperature stability. Consequently, extensive research is underway to achieve zero TCR. In this study, resistors were deposited by co-sputtering nickel-chromium-based composite compositions, metals showing positive TCR, with SiO2, introducing negative TCR components. It was observed that achieving zero TCR is feasible by adjusting the proportion of negative TCR components in the deposited thin film resistors within certain compositions. Additionally, the correlation between TCR and deposition conditions, such as sputtering power, Ar pressure, and surface roughness, was investigated. We anticipate that these findings will contribute to the study of resistors with very low TCR, thereby enhancing the reliability of space-level resistors operating under high temperatures.

Matrix-Assisted Variable Wavelength Laser Desorption Ionization of Peptides; Influence of the Matrix Absorption Coefficient on Expansion Cooling

  • Ahn, Sung-Hee;Bae, Yong-Jin;Kim, Myung-Soo
    • Bulletin of the Korean Chemical Society
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    • 제33권9호
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    • pp.2955-2960
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    • 2012
  • Product ion yields in the in- and post-source decays of three peptide ions, $[Y_5X+H]^+$ (X = Y (tyrosine), K (lysine), and R (arginine)), generated by matrix-assisted laser desorption ionization (MALDI) were measured at six wavelengths, 307, 317, 327, 337, 347, and 357 nm, using ${\alpha}$-cyano-4-hydroxycinnamic acid (CHCA) and 2,5-dihydroxybenzoic acid (DHB) as the matrices. The temperatures of the early and late plumes generated by MALDI were estimated via kinetic analysis of the product ion yield data. For both matrices, the temperature drop (${\Delta}T$), i.e. the difference in the temperature between the early and late plumes, displayed negative correlation with the absorption coefficient. This was in agreement with the previous reasoning that deeper laser penetration and larger amount of material ablation arising from smaller absorption coefficient would result in larger extent of expansion cooling. The results support the postulation of the expansion cooling occurring in the plume presented previously.

활성오니공법에 있어서 수온이 처리효율에 미치는 영향에 관한 분석 -청계천 하수종말처리장에 대하여- (Analysis of Temperature Effect on Activated Sludge Process at Cheong-Gye Cheon Sewage Treatment Plant)

  • 이은경
    • 한국환경보건학회지
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    • 제7권1호
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    • pp.9-20
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    • 1981
  • This study was performed to determine the correlationship between temperature and overall removals of BOD, SS and to demonstrate the effect of temperature on treatment performance. These data for a period from February 1, 1977 to January 31, 1980 were obtained from the Cheong-Gye Cheon Sewage Treatment plant. The results of correlation and stepwise multiple regression analysis were as follows. 1) Secondary effluent BOD and SS showed negative correlationship with water temperature, with correlation coefficient of -0.1710, and -0.1654 respectively. 2) Correlation coefficient of BOD, SS removal rate and water temperature were 0.1823 and 0.0429 respectively. 3) Regresion equation for estimate of BOD removal rate was as follows $\widehat{Y}_1$ (BOD removal rate)=63.9994+0.5442X(water temperature). And BOD removal rate showed non significant change according to the water temperature. 4) Regression equation for estimate of SS removal rate was as follows $\widehat{Y}_2$ (SS removal rate)=61.6881+0.1514X(Water temperature). And SS removal rate showed non significant change according to the water temperature. 5) According to the Stepwise Multiple Regression analysis, water temperature ranked second order in the BOD removal rate estimation and the equation was as follows $\widehat{Y}_1$ (BOD removal rate)=69.7398+0.2665 $X_1$ (Primary effluent BOD)+0.3562 $X_2$ (Water temperature)-0.0122 $X_3(Flow)+4413.271X_4$ (Organic Loading).

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Ce첨가에 따른 MST 세라믹스의 마이크로파 유전특성 (Microwave Dielectric Properties of the MST Ceramics with addition of Ce)

  • 최의선;박인길;배선기;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.430-433
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    • 2001
  • The $0.96MgTiO_{3}-0.04SrTiO_{3}+xCe(x=0{\sim}1.6wt%)$ ceramics were fabricated by the conventional mixed oxide method. The sintering temperature and time were $1300^{\circ}C$, 2hr., respectively. From the X-ray diffraction patterns, it was found that the perovskite $SrTiO_{3}$ and ilmenite $MgTiO_{3}$ structures were coexisted in the $0.96MgTiO_{3}-0.04SrTiO_{3}+xCe(x=0{\sim}1.6wt%)$ ceramics. The dielectric constant$(\varepsilon_{r})$ was increased with addition of Ce. The temperature coefficient of resonant frequency$(\Gamma_{f})$ was gradually varied from positive value to the negative value with increasing the Ce. The temperature coefficient of resonant frequency of the $0.96MgTiO_{3}-0.04SrTiO_{3}+0.2Ce$ ceramics was near zero, where the dielectric constant, quality factor, and $\Gamma_{f}$ were 20.68, 50,272 and ${-0.5ppm/^{\circ}C}$, respectively.

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PSN-PMN-PZT 세라믹스의 Zr/Ti 비에 따른 전기적 특성과 공진주파수의 온도안정성 (Electrical Properties and Temperature Stability of resonant Frequency with Zr/Ti ratio in PSN-PMN-PZT Ceramics)

  • 류주현;윤광희;민석규;이명수;서성재
    • 한국전기전자재료학회논문지
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    • 제13권8호
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    • pp.675-680
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    • 2000
  • In this study the temperature coefficient of resonant frequency(TC $F_{r}$) dielectric and piezoelectric properties of Pb[(S $b_{1}$2//N $b_{1}$2/)$_{0.065}$)-(Z $r_{x}$, $Ti_{1-x}$ )$_{0.90}$] $O_3$ceramics were investigated with Zr/Ti ratio. The compositions near the morphotropic phase boundary (MPB) appeared when Zr/Ti ratio was 49.5/50.5 The dielectric constant and electromechanical coupling factor( $k_{p}$) also showed the highest values of 1,257, 0.653 respectively when the Zr/Ti ratio was 49.5/50.5 Moreover the mechanical quality factor( $Q_{m}$) showed th lowest value of 713 when the Zr/Ti ratio. The temperature coefficient of resonant frequency(TC $F_{r}$) abruptly change at the morphotropic phase boundary(MPB) which existed between the rhombohedral phase with highly negative TC $F_{r}$ of -106ppm/$^{\circ}C$ and the tetragonal phase with highly positive TC $F_{r}$ of +64pp $m^{\circ}C$ as Zr/Ti ratio varied from 50/50 to 49.5/50.5.50.5..50.5.

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