• 제목/요약/키워드: Negative charge

검색결과 580건 처리시간 0.027초

고분자 재료의 고온하분포특성 (Space charge characteristics in several polymers at high temperature)

  • 남진호;고정우;서광석
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.84-87
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    • 2001
  • Space charge formation at high temperature was investigated in several polymers using pulsed electro-acoustic (PEA) method. In SXLPE, homocharge is found and increased as an increase of temperature. In a charge of polarity of poling voltage(positive to negative), space charge mainly cause of hole injection. In Ionomer, heterocharge is found because of ion. As an increase of temperature heterocharge is also increased. In PET, As an increase of temperature homocharge is decreased.

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리튬이온전지용 부극재료인 페트롤리엄 및 콜타르 피치 카본의 전지반응 특성에 관한 연구 (Study on the Characteristics of Cell Reactions for Petroleum- and Coal Tar Pitch-based Carbons as a Negative Electrode for Li-iion Batteries)

  • 박영태;유광수;김정식
    • 한국세라믹학회지
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    • 제37권2호
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    • pp.128-133
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    • 2000
  • In this work, soft carbons produced by pyrolysis of petroleum and coal-tar pitch were used as the negative electrode for Li-ion batteries. We studeid the charge/discharge capacity and the interfacial reaction of these electrodes by constructing a half cell. Charge/discharge property was studied by a constant-current step and the interfacial reaction between the electrolyte and the surface of a carbon electrode was studied by the cyclic voltammetry. The initial charge/discharge capacity for the coal-tar pitch carbon increased exceedingly with the heat treatment temperature. On hte other hand, the capacity of the petroleum pitch carbon increased with temperature up to 1000$^{\circ}C$, thereafter decreased continuously. While the charge capacity decreased with the cycle number, the reversibility increased above 90%. In addition, the thermal stability and crystallization of petroleum and coal-tar pitches were analyzed by TGA and XRD, respectively.

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Tuning the surface charge of mixed matrix membranes using novel chemistry

  • Priyanka Mistry;C.N. Murthy
    • Membrane and Water Treatment
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    • 제15권3호
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    • pp.139-152
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    • 2024
  • Mixed matrix membranes have gained significant recognition in the wastewater treatment industry for their effectiveness in removing dyes, proteins, and heavy metals from water sources. Researchers have developed an innovative technique to enhance properties of these membranes by incorporating amine-functionalized carbon nanotubes into the polymer matrix. This approach introduces amine functional groups onto the membrane surface, which are then modified with trimesoyl chloride and cyanuric chloride. The modified membranes are characterized by XPS to confirm successful bonding of amines with the trimesoyl chloride and cyanuric chloride. The surface charge of the modified membrane also plays a role in the modification process; the membrane modified with trimesoyl chloride has a negative surface charge, while the one modified with cyanuric chloride has a more positive charge. At the same acidic pH, the positive or negative charge of the mixed matrix membranes assists in enhancing the rejection of heavy metals. This results in improved antifouling properties for both modified membranes. The heavy metal rejection for all modified membranes is higher than for unmodified membranes, due to both adsorption and complexation abilities of the functional groups on the membrane surface with heavy metal ions. As the membrane surface functionalities increase through modification, the separation due to complexation also increases. The bulk morphology of the membrane remains unchanged, while roughness slightly increases due to the surface treatment.

Transport Properties of Charged Mosaic Membrane Based on Non-equilibrium Thermodynamics

  • Song, Myung-Kwan;Yang, Wong-Kang
    • Korean Membrane Journal
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    • 제7권1호
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    • pp.67-70
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    • 2005
  • It is well known as the role of ion exchange membrane with functional group in membrane matrix. Recently, we were reported that the charged mosaic membrane within parallel array of negative and positive charge groups. In this study we are reported the properties for the various transport coefficients of metal and heavy metal ions across charged mosaic membrane based on non-equilibrium thermodynamics is not based on equilibrium state.

고전계 인가 산화막의 트랩 분포 (Trap distributions in high voltage stressed silicon oxides)

  • 강창수
    • 한국결정성장학회지
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    • 제9권5호
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    • pp.521-526
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    • 1999
  • 산화막 트랩은 스트레스 바이어스 전압에 의해 산화막 계면과 산화막 안에 생성됨을 조사하였다. 이러한 실험은 게이트 면적 1$10^{-3}\textrm{cm}^2$를 갖는 산화막 두께 범위가 113.4$\AA$에서 814$\AA$까지의 산화막 안에서 상대적 트랩 위치를 결정하였다. 트랩은 캐소우드 부근에 음전하, 애노우드 부근에 양전하로 충전되어 있다. 트랩의 전하상태는 스트레스 고전압 인가 후 낮은 전압인가에 의해 쉽게 변화되었다. 고전압 스트레스에 의해 발생된 트랩의 산화막 전하상태는 양 또는 음전하를 포함한다.

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직류 코로나 하전된 강유전체구 층의 연면방전특성 (Surface Discharge Characteristics of a DC Corona Charged Ferroelectric Pellet Barrier)

  • 금상택;이근택;문재덕
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제48권5호
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    • pp.385-390
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    • 1999
  • Surface corona discharge characteristics of a dc corona charged ferroelectric pellet barrier have been investigated experimentally. Electric charges stored on the surfaces of the ferroelectric pellets by a dc corona discharge provide partial electric fields on the surfaces of the ferroelectric pellets, which could generate surface corona discharges on the ferroelectric pellets. This system utilizes both the surface discharges on the ferroelectric pellet barrier and the corona discharge between corona tip and mesh electrode. Positive and negative dc voltages were applied to the tip to generate partial discharges, and corona currents were estimated to investigate the buildup charge on ferroelectric pellets as a function of the applied time and the charge relaxation time constants of ferroelectric pellets. As a result, in the case of the negative corona discharge with the ferroelectric pellet barrier, the mean corona current and ozone generation increase greatly, and the surface discharges on the ferroelectric pellets can be fenerated efficiently. It is also found that, charge relaxation time, dielectric constants offerroelectric pellets, polarity of applied voltage and applied time affected to the surface discharges among the ferroelectric pellets.

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폴리이미드 박막의 공간전하현상에 관한 연구 동향 (A Research Trend on High Density Polyethylene Electrical Strength)

  • 최근호;오창근;신현만;황종선;최용성;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.1984-1985
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    • 2007
  • Polyimide is widely used as a high-temperature insulating material. Space charge distributions in polyimide (PI) films strongly depend upon electric field, temperature, water content and so on. We observed space charge distributions in PI films with various water contents. When a dc field was applied to as-received PI films or water-treated PI films, positive and negative homo space charges were observed near the respective electrodes at 333 K. In dried PI films, the homo space charges were much reduced, and positive and negative hetero space charges in the bulk were clearly observed. The space charge amounts in water-treated PI films were smaller than in as-received ones, while the current density in water-treated PI film was larger than that in as-received one by two or more orders of magnitude. These suggest not only that the charge injection from the electrode is enhanced by absorbed water but also that absorbed water makes carriers mobile. The decay of space charge was also faster in water-treated PI than in as-received or dried one. This also supports the enhancement of apparent mobilities of carriers in PI by absorbed water.

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Ultisol과 Alfisol 및 Inceptisol 토양에서 토양표면전하 측정에 사용된 이온흡착법, 전위차 적정법 및 역적정법간의 비교 (Comparison of the Ion Adsorption Method, Potentiometric Titraion and Backtitration Technique for Surface Charge measurement in Ultisol, Alfisol, and Inceptisol)

  • 이상은;;박준규;임수길
    • 한국토양비료학회지
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    • 제26권3호
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    • pp.160-171
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    • 1993
  • Ultisol(필리핀의 Luisiana 토양)과 Alfisol(필리핀의 Maahas 토양)및 Inceptisol(한국의 용지통) 토양의 표면전하 특성을 전위차 측정법과 역적정법 및 이온흡착법 등의 세가지 방법으로 정량하였고 분석법간의 차이를 비교한 결과는 아래와 같다. 1. 이온흡착법(또는 CEC-AEC method)으로 구한 PZNC(point of zero net charge)값은 Luisiana토양과 Maahas 토양 및 용지통에서 각각 3.1, 2.2 및 2.9였다. 따라서 이들 토양의 자연 pH조건에서는 음전하를 보였다. 2. 전위차 적정법과 역적정법에서 구한 PZSE(point of zero salt effect)값은 Maahas토양 외의 두 토양에서 일치하였다. 3. PZNC값은 PZSE값에 비해 모든 토양에서 낮았는데 이는 영구음전하의 영향으로 생각되었다. 한편 Uehara and gillman(1980)의 이론에 의해 구한 영구음전하는 Luisiana 토양과 Maahas 토양 및 용지통에서 각각 2.6, 4.5 및 0.4me/100g로 pH 7에서 측정된 CEC중 상당히 적은 부분을 차지하였다. 4. 역적정법은 pH가 너무 높거나 낮을 때 전위차 적정법이 표면전하를 과다 평가하는 결점을 보완해 주었으나 여전히 이온흡착법에 비해 과대 평가하고 있어 영구전하의 영향이 큰 보통 토양에서는 이온흡착법의 사용이 나을 것으로 판단되었다.

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PMIC용 저면적 64비트 MTP IP 설계 (Design of a 64b Multi-Time Programmable Memory IP for PMICs)

  • 최대용;김일준;하판봉;김영희
    • 한국정보전자통신기술학회논문지
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    • 제9권4호
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    • pp.419-427
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    • 2016
  • 본 논문에서는 저면적 64bit MTP IP를 설계하였다. 저면적 설계기술로는 MTP cell의 inhibit voltage를 기존의 VPP/3과 VNN/3 전압 대신 모두 0V를 사용하므로 VPPL(=VPP/3) regulator 회로와 VNNL(VNN/3) charge pump 회로를 제거하였다. 그리고 external pad를 이용하여 VPP program voltage를 forcing하므로 VPP charge pump 회로를 제거하였다. 또한 VNN charge pump는 VPP 전압을 이용하여 1-stage negative charge pump 회로로 pumping해서 -VPP의 전압을 공급하도록 설계를 하였다. 설계된 64bit MTP IP size는 $377.585{\mu}m{\times}328.265{\mu}m$(=0.124mm2)이며, DC-DC converter관련 layout size는 기존의 회로 대비 76.4%를 줄였다.