• Korean Journal of Materials Research
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• v.19 no.12
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• pp.657-660
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• 2009

Optical characteristics and structural changes depending on CuO content in phosphate glasses that are used in near-infrared (near-IR) filters were investigated. With phosphate glasses that contain 1-9 mol% CuO, changes in optical transmittance, optical absorption, and color coordinate were measured with a UV-VIS spectrophotometer. An XPS (X-ray photoelectron spectroscopy) analysis was performed to determine valence of copper ion that influences optical characteristics in near-IR filter glasses. Structural changes in glasses depending on CuO content were also analyzed by FT-IR (Fourier transform infrared) and Raman spectrophotometers. From the UV-VIS spectrophotometer results, strong absorption peaks at 220 & 900 nm were found and transmittance was decreased. The color coordinates of the glasses were shifted to the green color direction with CuO addition for increasing absorption of long wavelength range spectra, in spite of the amount of $Cu^{2+}$, which gives a blue color to glasses, and which was increased in XPS results. Also, structural de-polymerization of glasses with CuO addition were found by FT-IR and Raman results.

• Proceedings of the Korean Fiber Society Conference
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• 2003.10a
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• pp.71-72
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• 2003

The aim of our study is to prepare nanocomposites consisting polymer/inorganic nanoparticles and investigate their physical properties as a functional material. In this study, a nanocomposite of copper sulfide (CuS) nanoparticles introduced into a poly(acrylic acid) matrix was prepared and the optical absorption property was measured. The composite exhibited strong absorption of both ultraviolet and near-infrared rays, indicating that the composite is applicable to a solar radiation shielding filter. The wavelength of the near infrared absorption was controlled from ca.1000 nm to 1700 nm by heat and acidic solution treatments.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1526-1526
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• 2001

To improve the accuracy of sweetness sensor in automated sorting operations, it is necessary to clarify unevenness of the sugar content distribution within fruits. And it is expected that the technique to evaluate the content distribution in fruits contribute to the development of the near-infrared (NIR) imaging spectroscopy. Sugiyama (1999) had succeeded to visualize the distribution of the sugar content on the surface of a half-cut green fresh melon. However, this method cannot be applied to red flesh melons because it depends on information of the absorption band of chlorophyll (676 nm), which is affected by the color of the fresh. The objective of this study was to develop the universal visualization method depends on the absorption band of sugar, which can be applied to various kinds of melons and other fruits. The relationship between the sugar contents and absorption spectra of both green and red fresh melons were investigated by using a NIR spectrometer to determine the absorption band of sugar. The combination of 2$\^$nd/ derivative absorbances at 902 nm and 874 nm was highly correlated with the sugar contents. The wavelength of 902 nm is attributed to the absorption band of sugar. A cooled charge-coupled device (CCD) imaging camera which has 16 bit (65536 steps) A/D resolution was equipped with rotating band-pass filter wheel and used to capture the spectral absorption images of the flesh of a vertically half-cut red fresh melon. The advantage of the high A/D resolution in this research is that each pixel of the CCD is expected to function as a detector of the NIR spectrometer for quantitative analysis. Images at 846 nm, 874 nm, 902 nm and 930 nm were acquired using this CCD camera. Then the 2$\^$nd/ derivative absorbances at 902 nm and 874 nm at each pixel were calculated using these four images. On the other hand, parts of the same melon were extracted for capturing the images and squeezed for the measurement of sugar content. Then the calibration curve between the combination of 2$\^$nd/ derivative absorbances at 902 nm and 874 nm and sugar content was developed. The calibration method based on NIR spectroscopy techniques was applied to each pixel of the images to convert the 2$\^$nd/ derivative absorbances into the Brix sugar content. Mapping the sugar content value of each pixel with linear color scale, the distribution of the sugar content was visualized. As a result of the visualization, it was quantitatively confirmed that the Brix sugar contents are low at the near of the skin and become higher towards the seeds. This result suggests that the visualization technique by the NIR imaging spectroscopy could become a new useful method fer quality evaluation of melons.

• Journal of the Semiconductor & Display Technology
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• v.20 no.4
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• pp.62-67
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• 2021

In this study, we have successfully developed an unique NVIS Green A compatible LED by combining two technologies. One is white LED made with a black EMC (epoxy molding compound) lead frame. The other is NVIS Green A filter that shields the near infrared region made in the film method. The form factor of the developed NVIS Green A compatible LED was 2.0 × 2.0 × 0.95 mm. And it is possible to satisfy NVIS radiance and color limit specified in MIL-STD-3009 by controlling the concentration of Green A dye and the thickness of the NVIS filter as well as adjusting of color temperature of the white LED. From these results, we are expected that the developed NVIS Green A suitable LED is a promising solution for the weight reduction and the cost reduction of avionic applications.

• Bulletin of the Korean Chemical Society
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• v.34 no.3
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• pp.731-734
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• 2013

Reduced tungsten bronze nanoparticles of ternary and quaternary compounds were prepared by adding sodium and cesium to crystal structures of tungsten trioxides ($Na_xCs_{0.33-x}WO_3$, x = 0, 0.11) while maintaining the overall alkali metal fraction at 0.33, in an attempt to control near infrared (NIR) shielding property in the particular wavelength range of 780 to 1200 nm. The structure and composition analysis of the quaternary compound, $Na_{0.11}Cs_{0.22}WO_3$, revealed that 93.1% of the hexagonal phase was formed, suggesting that both alkali metals were mainly inserted in hexagonal channel. The NIR shielding property for $Na_{0.11}Cs_{0.22}WO_3$ was remarkable, as this material demonstrated efficient transmittance of visible light up to 780 nm and enhancement in NIR shielding because of the blue-shifted absorption maximum in comparison to $Cs_{0.33}WO_3$.

• Journal of the Korean Vacuum Society
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• v.12 no.S1
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• pp.88-91
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• 2003

Electromagnetic interference shielding and near-infrared cutoff filters for plasma display panel application were designed and fabricated by radio frequency magnetron sputtering. Three types of the filters were prepared: the basic structure of type A consisted of [$TiO_2$ Ti Ag $TiO_2$]; type B, of [$TiO_2$ ITO Ag $TiO_2$]; type C, of [$TiO_2$ ITO Ag ITO $TiO_2$]. Ti and ITO layers deposited on Ag layers were employed as barriers to prevent the oxidation and the diffusion of Ag film into the adjacent oxide layers. Optical, electrical, chemical, and structural properties were investigated, and the result shows that the filters with the ITO barrier layers provided an enhancement in transmittance in the visible owing to a lower absorption of ITO layers than Ti layers. Type C filter showed better optical and electrical performances and smoother surface roughness than Type B and C filters: the average sheet resistance was as low as 1.51 $\Omega\Box$ (where $\square$ stands for a square film), the peak transmittance in the visible was as high as 78.2 %, and the average surface roughness was 1.48 nm.

• Journal of the Semiconductor & Display Technology
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• v.19 no.4
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• pp.1-5
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• 2020

By adapting black body leadflame and thin film type Green A filter, we successfully demonstrated night vision imaging system (NVIS) Green A compatible LED. Fabricated NVIS compatible LEDs show small form factor compared to that of commercialized NVIS compatible LED. Especially, NVIS radiance and chromaticity of MIL-STD-3009 specification can be satisfied simultaneously and easily by controlling the color temperature of the white LED as well as the concentration of the Green A dye and the thickness of the Green A filter. The optimal dye concentration of the NVIS Green A filter is expected to be about 1 wt%. The results of this study are expected to contribute to miniaturization, weight reduction and localization of avionic display and lighting devices.

• Journal of the Korean Geographical Society
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• v.51 no.4
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• pp.509-523
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• 2016

The soil prediction can provide quantitative soil information for sustainable mountainous ecosystem management. Visible near infrared spectroscopy, one of soil prediction methods, has been applied to predict several soil properties with effective costs, rapid and nondesctructive analysis, and satisfactory accuracy. Spectral preprocessing is a essential procedure to correct noisy spectra for visible near infrared spectroscopy. However, there are no attempts to evaluate various spectral preprocessing methods. We tested 5 different pretreatments, namely continuum removal, Savitzky-Golay filter, discrete wavelet transform, 1st derivative, and 2nd derivative to predict soil carbon(C) and nitrogen(N). Partial least squares regression was used for the prediction method. The total of 153 soil samples was split into 122 samples for calibration and 31 samples for validation. In the all range, absorption was increased with increasing C contents. Specifically, the visible region (650nm and 700nm) showed high values of the correlation coefficient with soil C and N contents. For spectral preprocessing methods, continuum removal had the highest prediction accuracy(Root Mean Square Error) for C(9.53mg/g) and N(0.79mg/g). Therefore, continuum removal was selected as the best preprocessing method. Additionally, there were no distinct differences between Savitzky-Golay filter and discrete wavelet transform for visual assessment and the methods showed similar validation results. According to the results, we also recommended Savitzky-Golay filter that is a simple pre-treatment with continuum removal.

• Journal of The Korean Astronomical Society
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• v.29 no.2
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• pp.245-253
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• 1996

We have analyzed infrared (IR) images of Jupiter which was observed at the McDonald Observatory, Texas, U.S.A., during the P/SHoemaker-LEvy 9 (SL9) impact period and about one week after the last impact. The IR images were obtained on the 2.7m telescope using a NICMOS array with filters to isolate the $1.5{\mu}m\;NH_3\; band,\;the\;2.3{\mu}m\;CH_4\;band,\;the\;2.12{\mu}m\;H_2\;S(0)$ pressure-induced absorption, and the continua at $1.58{\mu}m\;and\;2.0{\mu}m$ (short K-band). All images except those with the $1.58{\mu}m$ continuum filter show bright impact sites against the relatively dark Jovian disk near the impact latitude of about $45^{\circ}$ S. This implies that dusts originated from the impacts reflect the solar radiation at high altitudes before absorbed by stratospheric $CH_4,\;NH_3 \;or\;H_2$. The impact sites observed with the $2.3{\mu}m$ filter are conspicuously bright against a very dark background. The morphology of impact sites, G, L, and H at 2.3 and $2.12{\mu}m$ filters shows clearly an asymmetric structure toward the incident direction of the comet fragments, in agreement with the studies of visible impact images obtained with the Hubble Space Telescope. Comparisons of reflectances of G, L, and H sites with simple radiative transfer models suggest that optically thick dust layers were formed at high altitudes at which methane absorption attenuates incoming sunlight only by about $1\%$. The dust layers in these sites seem to form at about the same altitude regardless of the magnitude of the impacts, but they appear to descend gradually after the impacts. The dust layers have optical depths of 2-5, according to the models.

• Korean Journal of Optics and Photonics
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• v.35 no.1
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• pp.24-29
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• 2024

We propose a hyperbolic metastructure based on a nanopatterned metal (Ag)-dielectric (PDMS) multilayer and report on its performance in an infrared (IR) cut-off filter for imaging devices. By optimizing the size of the square-shaped Ag nanopattern and the thickness of PDMS surrounding the Ag nanopattern, the proposed IR cut-off filter blocks 99% of light in the 0.70-1.01 ㎛ wavelength band while maintaining a high transmittance of over 94% in the visible region. Here, the cut-off wavelength band starts at a region above the epsilon-near-zero wavelength of the hyperbolic metastructure and ends at the point where plasmonic absorption appears strongly. It is observed that transmittance in the wavelength region longer than the IR cut-off band increases again due to plasmonic coupling among horizontally adjacent Ag nanopatterns. This metastructure can improve the performance of IR-blocking filters as well as allow it to be manufactured ultra-thin, which is applicable to various planar optical elements and integrated optical components.