• 한국자기학회지
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• 제5권5호
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• pp.421-426
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• 1995

The magnetic properties of the hot-pressed magnets made from the Fe-Nd-B alloys, mechanically ground and subsequently blended with binary additives such as Al-Cu and Ag-Zn before hot pressing, were investigated. The coercivities of the magnets increased as the concentration of Al-Cu increased up to 1 wt.% or up to 3 wt.% in the case of Ag-Zn. At higher concentrations the coercivities decreased markedly. The maximum gain in coercivity by the addition was about 20 %. typical values of $_{i}H_{c}$ and $B_{r}$ of a hotpressed magnet containing 1 wt.% Al-Cu were 18 kOe and 7 kG, respectively. It was found that Cu, Ag, and Zn, which diffused into the magnet during hot pressing, were mostly concentrated on the Nd-rich grain boundary phase whereas Al was present not only in the grain boundary region but also in the matrix grains.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2017년도 임시총회 및 하계학술연구발표회
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• pp.121-121
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• 2017

• Journal of Magnetics
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• 제15권1호
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• pp.32-35
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• 2010

The effects of Cu-addition and die-upset temperature on the texture in the die-upset Nd-lean $Nd_xFe_{93.5-(x+y)}-Cu_yGa_{0.5}B_6$ (x = 9-12, y = 0-2) alloys were investigated. The die-upset Cu-containing Nd-lean $Nd_{12}Fe_{81.5-y}-Cu_yGa_{0.5}B_6$ (y = 1, 2) alloys showed a considerable texture. Texture in the Nd-lean alloys developed through basal plane slip deformation. The Cu-addition reduced the melting point of grain boundary phase facilitating grain gliding during the die-upsetting, and providing a greater chance for the $Nd_2Fe_{14}B$ grains to meet the deformation conditions. Die-upsetting at higher temperature facilitated grain gliding and plastic deformation, thus enhancing texture.

• Journal of Magnetics
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• 제2권3호
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• pp.67-71
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• 1997

A new hot-forming process has been studied to produce anisotropic Nd-Fe-B based magnets from melt-spun ribbons. The ribbon fragments were inserted in a Cu tube and hot-deformed together with one-stroke. At a height reduction ratio of 0.44, the melt-spun ribbons were densified into a magnet with a density of 7.14 g/cm3, and showed a (BH)max of 14.6 MGOe. With further deformation, the magnets were plastically deformed with Cu tubes in the lateral direction, and crystallographic anisotropy was introduced. The magnets with a height reduction ratio of 0.75 exhibited magnetic properties of (BH)max = 32.1 MGOe, Br = 11.7 kG, and iHc = 10.6 kOe. This process shows the possibility that the conventional hot-pressing and subsequent die-upsetting for anisotropic magnets can be simplified into a one-step process.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 1996년도 추계연구발표회 논문개요집
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• pp.58-59
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• 1996

• 한국자기학회:학술대회 개요집
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• 한국자기학회 1992년도 춘계연구발표회 논문개요집
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• pp.66-67
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• 1992

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2000년도 International Symposium on Magnetics The 2000 Fall Conference
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• pp.266-267
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• 2000

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1286-1287
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• 2006

[ $Nd_2Fe_{14}B/{\alpha}-Fe$ ] nanocomposite powders with a nominal composition of $Nd_{12}Fe_{82}B_6$ were prepared by HDDR combined with mechanical milling. The microstructure was studied by Mossbauer spectrometry and TEM. The magnetic properties were investigated by VSM using bonded magnet samples. The results showed that the annealing temperature had significant influence on both the recombination kinetics and the grain size of the $Nd_2Fe_{14}B$ and ${\alpha}-Fe$ phases, and the bonded magnets presented the best magnetic properties when the nanocomposite powders were prepared by annealing at $760^{\circ}C$ for 30 min.

• Journal of Magnetics
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• 제14권4호
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• pp.150-154
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• 2009

The effect of Ga and, Nb addition on the kinetics and mechanism of the disproportionation of a Nd-Fe-B alloy were investigated by isothermal thermopiezic analysis (TPA) using $Nd_{12.5}Fe_{(81.1-(x+y))}B_{6.4}Ga_xNb_y$ (x=0 and 0.3, y= 0 and 0.2) alloys. The addition of Ga and Nb retarded the disproportionation kinetics of the Nd-Fe-B alloy significantly, and increased the activation energy of the disproportionation reaction. The disproportionation kinetics of the $Nd_{12.5}Fe_{(81.1-(x+y))}B_{6.4}Ga_xNb_y$ alloys measured under an initial hydrogen pressure of 0.02 MPa were fitted to a parabolic rate law. This suggested that during the disproportionation of $Nd_{12.5}Fe_{(81.1-(x+y))}B_{6.4}Ga_xNb_y$ alloys with an initial hydrogen pressure of 0.02 MPa, a continuous disproportionation product is formed and the overall reaction rate is limited by the diffusion of hydrogen atoms (or ions).

• Journal of Magnetics
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• 제14권1호
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• pp.27-30
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• 2009

Various sintered magnets containing $28{\sim}31\;wt%$ Nd and $0{\sim}7\;wt%$ Dy were evaluated for coercivity and irreversible flux loss as a preliminary study to develop highly-coercive, high-temperature magnets that can be applied for driving motors in a hybrid vehicle. The sintered magnets were prepared in sequence of strip casting, HD treatment, jet milling, magnetic field pressing, sintering and post-annealing. Increasing Dy content and adjusting post-annealing temperature monotonically increased coercivity of magnets from about 14 kOe to 30 kOe. A magnet containing 28 wt% Nd and 7 wt% Dy exhibits a $(BH)_{max}$+$_i{H_c}$ value of almost 64. This is very close to what the automobile industry considers as the minimum value (65) for a hybrid vehicle system. Moreover, irreversible flux loss of the magnet was about 3% at $200^{\circ}C$, which is well less than the allowable limit (5%) to a driving motor in hybrid vehicles.