• Journal of Soil and Groundwater Environment
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• v.26 no.1
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• pp.1-7
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• 2021

Air-water interfacial area is of great importance for the analysis of contaminant mass transfer processes occurring in the soil systems. Capillary bundle model has been proposed to estimate the specific air-water interfacial areas in unsaturated soils. In this study, the measured air-water interfacial areas of a soil (loam) using the gaseous interfacial tracer technique were compared to those from capillary bundle model. The measured values converged to the specific solid surface area (7.6×104 ㎠/㎤) of the soil. However, the simulated air-water interfacial areas based on the capillary bundle model deviated significantly from those measured. The simulated values were substantially over-estimated at low end of the water content range, whereas the model under-estimated the air-water interfacial area for the most of the water content range. This under-estimation is considered to be caused by the nature of the capillary bundle model that replaces the soil pores with a bundle of glass capillaries and thus no surface roughness at the inner surface of the capillaries is taken into account for the estimation of the air-water interfacial area with the capillary bundle model. Subsequently, appropriate correction is necessary for the capillary bundle model to estimate the air-water interfacial area in soils. Since the soil-moisture release curve data is the basis of the capillary bundle model, the model can be of use due to its simplicity, while the gaseous tracer technique requires complicated experimental equipment followed by moment analysis of the breakthrough curves. The size distribution profile of the pores filled with gas estimated by the water retention curve was found to be similar to that of particle size at different size range. The shifted distribution of gas-filled pores toward smaller size side compared to the particle size distribution was also found.

• New & Renewable Energy
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• v.18 no.4
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• pp.1-11
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• 2022

Landfill gas (LFG) generation characteristics in a construction waste landfill zone (block E) and mixed landfill zone (block A) were analyzed. During the period from October 2018 to April 2022, a total of 936×10³ and 1,001×10³ tons of waste were disposed in block E and block A, respectively. Out of this, 27.1% and 55.6% were biodegradable waste in block E and block A, respectively. The landfill masses of the two blocks were converted to be comparable. Then, the biodegradable waste and organic carbon were estimated by element analysis, biodegradable carbon by biochemical methane potential experiment (DC), and sulfate ion by acid decomposition. Results showed that biodegradable waste, organic carbon, biodegradable carbon, and sulfate ions in block A were 2.1, 1.6, 5.2, and 0.4 times greater than those in block E, respectively. The amount of LFG generated by block A was 4.8 times greater than that by block E. The average concentrations of methane (CH₄) were 60.8% and 60.9% in block E and block A, respectively, which were unrelated to the nature of disposed waste. The average concentrations of hydrogen sulfide (H₂S) were significantly high in block E (4,489 ppm) and block A (8,478 ppm). As the DC/SO₄^2- of block E and block A were 0.35 and 4.56, respectively, increase in DC/SO₄^2- caused increase in not only the total amount but also the concentration of H₂S generated.

• Proceedings of the KIEE Conference
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• 1999.07d
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• pp.1699-1701
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• 1999

We prepared diamond thin films on WC-Co substrate in $H_2-CH_4-O_2$ gas mixture using 13.56MHz RF PACVD. Scanning electron microscopy, X-ray diffraction and Raman spectroscopy were used to analyze the nature of thin film. and Rockwell test to analyze the adhesion between thin film and substrate. The good diamond quality and adhesion was appeared with cemented tungsten carbide substrate treated with oxygen plasma.

• 한국연소학회:학술대회논문집
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• 2003.05a
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• pp.75-83
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• 2003

Diode laser absorption system is advantageous of their non-invasive nature, fast response time, high sensitivity and real-time measurement capability. Furthermore, recent advances in room-temperature, near-IR and visible diode laser sources for telecommunication, optical data storage applications are enabling combustion diagnostics system based on diode laser absorption spectroscopy. So, combined with fiber-optics and high sensitive detection strategies, compact and portable sensor system are now appearing for a variety of applications. The objective of this research is to take advantage of distributed feed-back diode laser and develope new gas sensing system. It experimentally found out that the wavelength, power characteristics as a function of injection current and temperature. In addition to direct absorption and wavelength modulation spectroscopy have been demonstrated in these experiments and have a bright prospect to this diode laser system.

• Proceedings of the KIEE Conference
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• 2004.07c
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• pp.1997-1999
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• 2004

In this paper, a novel method has been proposed by use of HY-Pockels sensor for the detection of PD in GITR(Gas Insulated Transformer) in order to improve reliability and to overcome the shortcomings of other techniques which are currently employed. For this work, different types of the test specimen, simulating the winding of the real GITR, have been designed and fabricated to generate the PD. And then, the detection of PD has been realized by conventional methods according to IEC 270 and also the proposed novel sensor as well. Afterwards, their results are well compared to understand the correlation between the nature of the defects in the winding and their PD pattern.

• Bulletin of the Korean Chemical Society
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• v.26 no.11
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• pp.1803-1806
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• 2005

Formation of octahedral shaped PbSe quantum dots at higher synthesis temperature is being reported in this paper. The synthesis includes the reaction between lead oleate and trioctylphosphine selenide under inert gas conditions to produce PbSe. TEM, SEM, XRD and EDS were used to characterize the samples. The SEM exhibited the formation of spherical shaped nanocrystals at temperature below 140 ${^{\circ}C}$ and octahedral shaped nanoparticles at higher temperatures. Moreover, the TEM also showed the well resolved (111) lattice fringes proving that the nanocrystals were crystalline in nature. Synthesis of highly pure PbSe nanocrystals was another interesting aspect of this research.

• Journal of the Korean Ceramic Society
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• v.30 no.10
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• pp.866-870
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• 1993

For VO2-based sensors applicable to temperature measurements and optical disk materials by the nature of semiconductor to metal transition, the crystallinity and temperature vs. resistance characteristics were investigated as a function of the heat treatment temperature. The bead-type sensors were prepared through typical sensor fabrication processing and heat-treated at 40$0^{\circ}C$, 50$0^{\circ}C$, and $600^{\circ}C$, respectively, for 30 minutes in H2 gas atmosphere. As results of the temperature vs. resistance measurements, the electrical resistance in the phase transition range was decreased by 102 order for the VO2 sensor and by 103 order for the V71P11Sra18 system. It was estimated that the hysteresis, temperature vs. resistance, and current vs. voltage characteristics of the V71P11Sr18 system could be utilized for commericialization as a temperature sensor.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.6
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• pp.602-608
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• 2014

The sequence of bond overlap population of metal hydrogen binding is in Al-H > Fe-H > Zr-H > V-H. This results shows the binding energy of Al-H is the biggest in this metals (Al, Fe, Zr, and V) and hydrogen interaction. The Vanadium-hydrogen binding shows the weakest binding energy compared to other metals and it causes easy hydrogen desorption from the corresponding metals. The net charge of Al-H show the biggest value of 0.2248 and the severe localizations of electrons around aluminum and imply strongest covalent binding nature in these metals. This study is applicable to the purification of hydrogen in other bulk gas.

• Mass Spectrometry Letters
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• v.8 no.4
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• pp.79-89
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• 2017

Ion mobility mass spectrometry (IM-MS) combines the advantages of ion mobility spectrometry (IMS) and MS for effective gas-phase ion analysis. Separation of ions based on their mobilities prior to MS can be performed without a great loss in other analytical figures of merit, and the extra dimension of analysis offered by IM can be beneficial for isomer and complex sample analyses. In this review, basic principles of IMS and IM-MS are described in addition to an introduction to various IMS techniques and commercial IM-MS instruments. The nature of collision cross-section (${\Omega}_D$), an important parameter determining the transport properties of ions in IMS, is also explained in detail.

• Carbon letters
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• v.12 no.1
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• pp.39-43
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• 2011

Synthesis of carbon fibers from cotton fiber by pyrolysis process has been described. Synthesis parameters are optimized using Taguchi optimization technique. Synthesized carbon fibers are used for studying hydrogen adsorption capacity using Seivert's apparatus. Transmission electron microscopy analysis and X-ray diffraction of carbon fiber from cotton suggested it to be very transparent type material possessing graphitic nature. Carbon synthesized from cotton fibers under the conditions predicted by Taguchi optimization methodology (no treatment of cotton fiber prior to pyrolysis, temperature of pyrolysis $800^{\circ}C$, Argon as carrier gas and paralyzing time for 2 h) exhibited 7.32 wt% hydrogen adsorption capacity.