• Bulletin of the Korean Chemical Society
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• 제25권12호
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• pp.1948-1950
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• 2004

• 한국가스학회지
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• 제19권6호
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• pp.72-79
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• 2015

천연가스 감압기지에 터보팽창기 감압시스템을 도입하여 천연가스의 감압과정에서 전기에너지를 생산할 수 있다. 터보팽창기의 효율은 천연가스의 유량과 터보팽창기 설계유량의 비에 따라 달라진다. 따라서 터보팽창기로 들어가는 유량을 조절함으로써 감압시스템을 운전하기 위한 최적조건을 결정할 수 있다. 본 연구에서는 두 곳의 저압 정압기지에서 천연가스의 압력이 17.5 bar에서 8.5 bar로 감압될 때 천연가스의 유량에 따라 생산 가능한 전력을 계산하고 계산결과의 비교를 통해 터보팽창기 감압시스템이 최적으로 운전되기 위한 조건을 찾았다. 천연가스의 평균 유량이 크고 유량의 변화가 작을 때 터보팽창기가 효율적으로 운전되었고 터보팽창기의 설계유량은 천연가스의 유량을 가장 많이 포함하는 용량에서 결정되었다. 선정된 두 정압기지에서 회수 가능한 전력생산량은 9 MW(B 기지), 12 MW(D 기지)로 추산되었다.

• Bulletin of the Korean Chemical Society
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• 제27권9호
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• pp.1329-1334
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• 2006

The electrochemical reduction of coumarin, 7-acetoxy-4-methyl coumarin (AMC), and 7-acetoxy-4-bromomethyl coumarin (ABMC), in 0.1 M tetraethyl ammonium perchlorate/acetonitrile solution was carried out by direct current, differential pulse polarography, cyclic voltammetry, and controlled potential coulometry. The electrochemical reduction of ABMC was proceeded through three steps of electron transfer coupled with the chemical reactions. The color of solution was changed to yellow when the carbonyl group was reduced during 2nd step (-1.8 volts) and independented with cleavage of bromo group. Highest fluorescence intensity showed when the electrochemical reduction of AMC was controlled at near the potential (-2.3 volts vs. Ag/AgCl).

• 분석과학
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• 제18권1호
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• pp.89-95
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• 2005

Studies on the electrochemical reduction of 7-acetoxy-4-bromomethyl-coumarin (ABMC), 7-acetoxymethyl coumarin (AMC), and coumarin in 0.1 M tetraethyl ammonium perchlorate acetonitrile solution were carried out with direct current, differential pulse polarography, cyclic voltammetry, and controlled potential coulometry. The electrochemical reduction of ABMC was proceeded through three irreversible steps coupled with the chemical reactions. The solution color was changed to yellow when the carbonyl group was reduced during second step and the color change was independent with bromo group of ABMC. Fluorescent intensity was highest when the electrochemical reduction was controlled at near the overpotential of supporting electrolyte (-2.3 volts).

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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• pp.1-4
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• 2001

A new non-destructive fatigue prediction model of the composite laminates is developed. The natural frequencies of fatigue-damaged laminates under extensional loading are related to the fatigue lift of the laminates by establishing the equivalent flexural stiffness reduction as a function of the elastic properties of sublaminates. The flexural stiffness is derived by relating the $90^{\circ}$-ply elastic modulus reduction, and using the laminate plate theory to the degraded elastic modulus and the intact elastic modulus of other laminate. The natural frequency reduction model, in which the dominant fatigue mode can be identified from the sensitivity scale factors of sublaminate elastic properties, provides natural frequency vs. fatigue cycle curves for the composite laminates. Vibration tests were also conducted on $[\textrm{90}_{2}\textrm{0}_{2}]_s$ carbon/epoxy laminates to verify the natural frequency reduction model. Correlations between the predictions of the model and experimental results are good.

• International Journal of Automotive Technology
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• 제6권6호
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• pp.591-598
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• 2005

A three-way catalyst system of a natural gas vehicle (NGV) has characteristics of higher fuel consumption and higher thermal load than a lean-bum catalyst system. To meet stringent emission standards in the future, NGV with the lean-bum engine may need a catalyst system to reduce the amounts of HC, CO and NOx emission, although natural gas system has low emission characteristics. We conducted experiments to evaluate the conversion efficiency of the NOx reduction catalyst for the lean-burn natural gas engine. The NOx reduction catalysts were prepared with the ${\gamma}-Al_{2}O_3$ washcoat including Ba based on Pt, Pd and Rh precious metal. In the experiments, effective parameters were space velocity, spike duration of the rich condition, and the temperature of flowing model gas. From the results of the experiments, we found that the temperature for maximum NOx reduction was around $450^{\circ}C$, and the space velocity for optimum NOx reduction was around $30,000\;h^{-1}$ And we developed an evaluation model of the NOx reduction catalyst to evaluate the conversion performance of each other catalysts.

• Bulletin of the Korean Chemical Society
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• 제25권5호
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• pp.603-604
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• 2004

• Bulletin of the Korean Chemical Society
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• 제27권5호
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• pp.667-671
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• 2006

The new MPV-type reagents, B-acetoxydiisopinocampheylborane ($Ipc _2$BOAc) and B-trifluoroacetoxydiisopinocampheylborane $(Ipc _2BO _2CCF _3)$, have been prepared and their reducing characteristics in the reduction of carbonyl compound have been examined in order to find out a new reducing system with unique applicability in organic synthesis. In general, the reactivity of $Ipc _2BO _2CCF _3$ appears to be stronger than that of $Ipc _2$BOAc, presumably due to the acidity increase by the electron-withdrawing fluorine-substituent. Both reagents show an excellent selectivity in 1,2-reduction of $\alpha,\beta$-unsaturatedcarbonyl compounds and in competitive reduction between structurally different carbonyl compounds. In addition, $Ipc _2BO _2CCF _3$ shows interesting features in the stereoreduction of cyclic ketones.

• Bulletin of the Korean Chemical Society
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• 제32권spc8호
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• pp.3183-3186
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• 2011

• Bulletin of the Korean Chemical Society
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• 제3권3호
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• pp.119-122
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• 1982

Rigid ${\alpha}$-oximino ketones containing two functional groups such as 2-oximino-1-acenaphthenone and 2-oximino-1-indanone were synthesized and the simultaneous reduction of the two functional groups of ${\alpha}$-oximino ketones by $LiAlH_4$ gave the corresponding amino alcohols, 2-amino-1-acenaphthenol and 2-amino-1-indanol. The yields of the reduction products of the ${\alpha}$ -oximino ketones remarkably increased, as the increase of molar ratio of hydride used to the reactant. The use of 24 moles of $LiAlH_4$ was found to afford the best result in the reduction of the rigid ${\alpha}$-oximino ketones to the corresponding amino alcohols. The yields was not affected by the variation of solvents such as ether, THF and diglyme.