• 보존과학회지
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• 제34권4호
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• pp.295-303
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• 2018

The application of reinforcing agents with hydraulic property and strength development characteristics was studied under conditions similar to those of mural-painting mortar made with oyster shell powder. Reinforcement mortar made with oyster shell powder showed hydraulic properties and strength to supplement the weaknesses of natural hydraulic lime(NHL); this confirmed its possibility as a wall-reinforcing material with enough strength for preserving mural paintings. Reinforcement mortar 1 showed hydraulic property and general characteristics of lime mortar, such as consistency and viscosity, as well as lower strength and higher whiteness compared to an NHL product. For Reinforcement mortar 2, the original wall sample characteristics were reflected by mixing more shell produced through calcination; and it showed similar strength to that of Reinforcement mortar 1 as well as high whiteness. In measuring the contraction ratio of reinforcement mortar samples, Reinforcement mortar 1 and 2 showed more stability in property change compared to the NHL Group.

• 한국세라믹학회지
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• 제51권2호
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• pp.72-81
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• 2014

The main mineral phases of natural hydraulic lime (NHL) as a hydraulic lime binderare $Ca(OH)_2$, $C_2S$, $C_3S$, $C_3A$, and $SiO_2$ residues. Also, NHL has the characteristic of setting and hardening by a hydration reaction with water and by carbonation reactions with carbon dioxide from the air. In this study, in an effort to investigate changes of the mineral phases by NHL hydration and carbonation reactions, transitions of mineral phases and the microstructures of hardened pastes were analyzed by XRD, DSC, SEM, and by pore size distributions using domestic and foreign-sourced NHL pastes after curing at 1, 3, 7, and 28 days. On the basis of the analysis results, it was confirmed that domestic low-grade limestone can be used for the manufacturing of NHL. The main hydration mineral phases were $Ca(OH)_2$, $CaCO_3$, $C_2S$, and $SiO_2$ residues, while in the case of foreign-sourced NHL, a small amount of an aluminium hydration phase formed. Also, the $CaCO_3$ content after the carbonation reaction increased with an increase in the curing time. After hydration for 28 days, NHL containing considerable amounts of $C_2S$ and $C_3S$ showed higher carbonation ratios than others types.

• 한국세라믹학회지
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• 제53권2호
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• pp.206-214
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• 2016

This study aims to produce dolomitic hydraulic lime (D-NHL) using domestic low grade dolomitic limestone and to determine the effect of adding blast furnace slag (BFS) and gypsum as part of an investigation of the hydration properties of D-NHL to increase the mechanical properties. The main mineral phases of D-NHL as a hydraulic lime binder were $Ca(OH)_2$, $Mg(OH)_2$, $C_2S$, $C_3S$, and MgO residues. $Ca(OH)_2$ transformed into $CaCO_3$ in D-NHL paste over the period of 28 days, but the carbonation of $Mg(OH)_2$ and the hydration of $C_2S$ did not occur until hydration, after 28 days. Through an investigation of the hydration properties of D-NHL pastes mixed with BFS and gypsum, Al-based compounds such as calcium aluminate hydrates ($C_4AH_{13}$) and ettringite were observed at early hydration time. The compressive strength was improved due to the increased quantities of these hydration products. These results show that good performance results from the application of dolomitic hydraulic lime and that a high value product can be made from domestic waste materials.

• 건축역사연구
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• 제25권3호
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• pp.37-45
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• 2016

This study was to investigate the firing method of limestone in Joseon Dynasty, and analyze the physical chemical properties of lime mortars in Joseon Dynasty. This study was to manufacture and evaluate the firing experiment and mortar of Limestone by each sort in order to reproduce the traditional lime mortars in Joseon Dynasty, and investigate the behavior to improve physical properties according to the firing method of Limestone. This study has found out that there were screening criteria and standard of appropriate firing temperature about the Limestone in Joseon Dynasty. Accordingly, this study was to improve its strength through various additives and mixture. In particular, in case of Limestone, the black and blue Limestone were preferred, and most of domestic Limestones were low grade Limestone including the clay and took ivory white or blue with low whiteness. This study has shown that the low grade Limestone was mined by the surface mining compared with the high grade Limestone as underground mining method, and could be used because it was easy to mine relatively and there was possibility that Natural Hydraulic Lime(NHL) was used with the traditional lime mortars in Joseon Dynasty.

• 박물관보존과학
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• 제21권
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• pp.29-40
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• 2019

고분벽화 벽체 보강제로써 천연 수경성 석회의 적용 가능성을 확인하고자 실험연구를 실시하고 그 결과를 제시하였다. 선행된 고구려 고분벽화 관련 연구를 통해 벽체 의사시료와 NHL 제품을 활용한 조건별 보강제 시료를 제작하였다. 시료는 고분 내부 환경을 고려한 고습 조건에서 7일, 28일, 84일간 양생하였으며, 기간별 치수안정성 및 강도 등 물성평가를 수행하였다. 실험 결과, NHL 제품은 경화속도가 빠르고 수축률이 적어 보강제로써의 적합성은 확인되었으나 벽체 물성대비 강도 차이가 크고 백색도가 떨어지는 등의 단점이 확인되었다. 치수안정성 및 압축강도 평가 결과 NHL 제품과 고분벽화 벽체 의사시편을 혼합한 조건이 상대적으로 벽체 보강제로써 적합한 값을 지닌 것으로 나타났다. 따라서 손상된 고분벽화 벽체 보강제로 천연 수경성 석회를 적용하기 위해서는 대상 벽체의 조건에 따라 적합한 경화시간 및 강도를 발현할 수 있는 조건이 고려되어야 할 것으로 판단된다.

• 한국세라믹학회지
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• 제51권2호
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• pp.88-96
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• 2014

Natural hydraulic lime (NHL) is produced by burning a form of low-grade limestone containing silica and alumina which, above certain temperatures, combine with calcium oxide. The resulting silicates and aluminates impart hydraulic properties to the product. This study aims to determine the calcined characteristics of NHL using domestic low-grade limestone with maximized hydraulic properties. Six types of low-grade limestone containing $SiO_2$ were selected and experiments were carried out with different burning temperatures and holding times. The burning temperature and holding time as the most suitable burning conditions were $1,200^{\circ}C$ to $1,300^{\circ}C$ and 3 to 7 h, respectively, for the manufacturing of NHL from domestic low-grade limestone. These results demonstrate the feasibility of NHL using domestic low-grade limestone to produce NHL.

• 자원리싸이클링
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• 제24권6호
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• pp.61-68
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• 2015

본 연구에서는 천연수경성석회(NHL) 모르타르에 바잘트 섬유를 혼합하여 섬유혼합에 따른 강도특성을 연구하고자 하였다. 건식 및 습식 4가지로하여 혼합방법에 따른 물리적 특성발현을 확인하였으며, 압축강도 및 휨강도 등을 고려하여 강도 특성이 최대로 발현되는 혼합방법 한 가지를 선택하였다. 실험결과 물성 발현은 습식혼합보다 건식혼합에서 더 우수하였으며, 건식혼합 중 바인더(NHL)와 섬유를 pre-mixing 한 후 물과 골재를 순차적으로 혼합하여 섬유의 분산력을 높여주는 혼합방법을 선택하였다. 이후 섬유 길이에 따른 물리적 특성 발현성을 확인하였다. 바잘트 섬유 길이에 따른 압축강도 및 휨강도 측정결과, Plain 샘플 대비 섬유 혼합에 따라 압축강도는 감소하는 경향성을 보였으며, 휨강도는 증가하는 경향을 나타내었다. 또한 섬유를 혼합한 샘플 중에서 섬유길이 6 mm일 때 가장 우수한 강도 특성을 나타내었다.

• 자원리싸이클링
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• 제26권1호
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• pp.43-50
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• 2017

본 연구에서는 무기질 첨가재를 혼합한 천연수경성석회의 초기경화 거동분석을 위해 multiple light scattering 분석법을 이용하였다. 자체 제조한 천연수경성석회의 물성향상을 위해 고로수쇄슬래그 및 3종류의 석고를 혼합비에 따라 혼합하였으며 물-고체비 0.6으로 페이스트를 제조하였다. 제조한 페이스트를 이용하여 원통형의 용기에 일정량을 담아 장비(Turbiscan LAB, Formulaction)에 장입하여 분석을 실시하였다. 페이스트로부터의 backscattering flux(BS, %)는 $23^{\circ}C$의 온도에서 분석용기 전체높이(55 mm)에 대해 24시간 동안 10분 간격으로 측정되었다. 모든 시료에서 전체적으로 BS는 시간경과에 따라서 증가하는 경향성을 보였다. 고로수쇄슬래그와 석고를 첨가함에 따라서 시간에 따른 BS의 증가 속도는 0.02에서 0.38 BS %/hour 까지 증가하였다. 반수석고를 혼합하였을 경우 가장 높은 backscattering flux와 BS의 증가속도를 보였다.