• Title/Summary/Keyword: Natural Degradation Phenomena

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Effect of Moisture Absorption on Dielectric Breakdown Phenomena of DGEBA/MDA/SN/Natural Zeolite System (DGEBA/MDA/SN/천연 제올라이트계의 절연파괴현상에 미쳐는 흡습의 영향)

  • Kim, You-Jeong;Lee, Hong-Ki;Kim, Sang-Wook
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.994-996
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    • 1999
  • Hygrothermal aging at the elevated temperature induces the long-term degradation of the epoxy resin. We investigated the effects of hydrothermal stress on the dielectric breakdown phenomena of epoxy composite filled with natural zeolite. The cured specimens absorbed the moisture in the autoclave at $120^{\circ}C$. $T_g$ of the deteriorated composite by moisture absorption decreased. The dielectric breakdown strength decreased with the moisture absorption cycle. It was concluded that the thermal stress and the high water-vapour-pressure deteriorated the natural zeolite filled epoxy resin system, consequently and the tree growth rate increased.

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A study on the self-life estimation of the propellant KM10 by using high temperature acceleration aging tests (고온가속노화시험을 이용한 추진제 KM10의 저장 수명 추정)

  • Cho, Ki-Hong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1735-1740
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    • 2010
  • The propellant KM10, a single propellant manufactured nitrocellulose, is known to cause natural degradation phenomena at long term storage. The self-life was estimated using generally used high temperature acceleration aging tests to analyze the content of stabilizer and using the Arrhenius equation & Berthelot equation to calculate reaction rate constants. According to the result of this study, self-life of propellant KM10 using the Arrhenius equation & Berthelot equation appear significantly different as 43.73, 16.53years and when compared with the paper of E. R. Bixon, self-life of propellant KM10 predicted using the Arrhenius equation was reasonably determined.

The Simulation of Semicale Natural Circulation Test 5-NC-3,S-NC-4 Using RELAP5/Mod3.1

  • Kim, S. N.;W. H. Jang
    • Nuclear Engineering and Technology
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    • v.30 no.5
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    • pp.424-434
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    • 1998
  • RELAP5/Mod3.1 code was assessed with the semiscale experiment S-NC-3, and S-NC-4, which simulated the two-phase natural circulation and reflux condensation for the SBLOCA of PWR, respectively . Test S-NC-3 and S-NC-4 calculation results showed that RELAP5/Mod3.1 quite well describes the influence of steam generator secondary side heat transfer degradation on both two-phase natural circulation and reflux condensation. A comparison between the calculated and measured two-phase mass flow rate in test S-NC-3 shows good agreement for primary mass inventory more than 92%. And RELAP5/Mod3.1 have a good mass flow rate prediction capability for the transient such as S-NC-4 except some flow oscillations. The reflux flow rate for S-NC-4 test is under predicted, and the overall results verify that the correct prediction of the reduced liquid level appears to be required for the correct calculation of the overall phenomena.

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Modeling and Simulation of the Photocatalytic Treatment of Wastewater using Natural Bauxite and TiO2 doped by Quantum Dots

  • Becheikh, Nidhal;Eladeb, Aboulbaba;Ghazouani, Nejib
    • International Journal of Computer Science & Network Security
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    • v.22 no.6
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    • pp.91-96
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    • 2022
  • The photocatalytic degradation of salicylic acid takes place in several stages involving coupled phenomena, such as the transport of molecules and the chemical reaction. The systems of transport equations and the photocatalytic reaction are numerically solved using COMSOL Mutiphysics (CM) simulation software. CM will make it possible to couple the phenomena of flow, the transport of pollutants (salicylic acid) by convection and diffusion, and the chemical reaction to the catalytic area (bauxite or TiO2 doped by nanoparticles). The simulation of the conversion rate allows to correctly fit the experimental results. The temporal simulation shows that the reaction reaches equilibrium after a transitional stage lasting over one minute. The outcomes of the study highlight the importance of diffusion in the boundary layer and the usefulness of injecting micro-agitation into the microchannel flow. Under such conditions, salicylic acid degrades completely.

Life Expectancy Estimation of the Propellants KM10 using High Temperature Acceleration Aging Tests and Stockpile Analysis Test (고온가속노화시험법과 저장분석시험법을 이용한 추진제 KM10의 기대수명 평가)

  • Cho, Ki-Hong;Kim, Eui Yong
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.695-699
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    • 2010
  • The propellant KM10, a single propellant manufactured from nitrocellulose, was known to cause natural degradation phenomena at long term storage. In this study, the self-life was estimated using high temperature acceleration aging tests and stockpile analysis test. For the life expectancy estimation, Arrhenius equation and Berthelot equation were used in the high temperature acceleration tests, and the first order regression was used in the Stockpile analysis test. The self-life of propellant KM10 using the Arrhenius equation and Berthelot equation showed significantly different results as 43.73, 16.53 years in the high temperature acceleration test, and it showed 42.94 years in the Stockpile analysis test. The value of self-life predicted by Arrhenius equation was reasonable when compared with the result of E. R. Bixon.

An Experimental Study on the Pump Operating Characteristics with Low Flow Operation (펌프의 저 유량 운전특성에 관한 실험적 연구)

  • 오광석;신필권;박종호;심우건;조두연
    • Journal of KSNVE
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    • v.9 no.1
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    • pp.85-96
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    • 1999
  • For ASME Code pumps in nuclear power plants, inservice test is required to assess the operational readiness in accordance with ASME code and related regulations. The objective of this study therefore, is to develop the technical background of the degradation of pump performances and conditions due to low flow rate operation. In addition. the detection techniques of pump operating conditions are to be developed to enhance the safety and economy of nuclear power plants. A test loop consisted of pump, motor. water tank, flow rate measurements and piping system with flow control devices was established for this study. Two typical pumps, 1-stage volute pump and 3-stage turbine pump, were selected and the test was performed upon two major point of views ; i.e., pump discharge pressure pulsations analysis and pump vibration spectrum analysis. From the test results, it is concluded that (1) the pump vibration affected by the natural frequency of operating pump is significant in the low frequency zone (around 1 Hz) : the vibration amplitude. especially. is an important factor during low flow rate operation. and shall be monitored to ensure that it is within the limit of ASME OM code Part 6, (2) the vibration frequency and pump discharge pressure are affected by vane pass frequency and running speed, (3) the wave phenomena due to the compressiblity of water is anticipated during low flow rate operation. and the pump system shall be designed to prevent it and. finally, (4) the technical background of the degradation of pump performances and conditions due to low flow rate operation is provided.

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Effects of Bioremediation Products on the Oil Degradability (생물정화용 제품의 유류분해능 비교)

  • 김상진;신수경
    • Korean Journal of Microbiology
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    • v.33 no.2
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    • pp.157-162
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    • 1997
  • Recently the bioremediation technology has been widely used to recover the oil contaminated environments The application of bioremediation agents to oil polluted environments became common and thus many kinds of commercial products were imported into domestic market. In Korea, howcver. the standardization of bioremediation products quality is not yet established and results of efficacy test .ire scarce. In this study five oil spill bioremediation commercial products including microbial inoculants and en'cyme agents are tested for the oil degradation rate. From the results most products shows the strong oil emulsifying phenomena due to the contained chemical oil dispersant and the low oil degradation rate. Product D inhibited the oil degradability of microorganisms even in the natural sea water. From these results it could be concluded that in the near future the laboratory protocol and standardization of products quality for bioremediarion agents should be prepared to activate the effective application of bioremediation technology in Korea.

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Effect of $H_2S$ Partial Pressure and pH of Test Solution on Hydrogen Induced Cracking of High Strength Low Alloy Steels

  • Kim, Wan Keun;Koh, Seong Ung;Kim, Kyoo Young;Yang, Boo Young;Jung, Hwan Kyo
    • Corrosion Science and Technology
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    • v.4 no.6
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    • pp.236-241
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    • 2005
  • Hydrogen induced cracking (HIC) is one of the hydrogen degradation phenomena of linepipe steels caused by $H_2S$ gas in the crude oil or natural gas. However, NACE TM0284-96 standard HIC test method is hard to satisfy the steel requirements for sour service application since it uses more severe environmental conditions than actual conditions. Therefore, in order to use steels effectively, it is required to evaluate HIC resistance of steels in the practical range of environmental severity. In this study, HIC resistance of two high strength low alloy (HSLA) steels being used as line pipe steels was evaluated in various test solutions with different $H_2S$ pressures and pH values. The results showed that the key parameter affecting crack area ratio (CAR) is $H_2S$ partial pressure of test solution when the pH value of test solution is not over 4. Hydrogen diffusivity was not a constant value, but it was rather affected by the hydrogen ion concentration (pH value) in the solution.

Accelerated Seaward Growth of Tidal Sand Bar during Giant Dyke Construction off the Mangyung River Mouth, West Coast of Korea

  • Lee, Hee-Jun;Choi, Kang-Won;Eo, Dae-Su;Chu, Yong-Shik
    • Journal of the korean society of oceanography
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    • v.36 no.3
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    • pp.72-82
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    • 2001
  • The progress of giant dyke construction off the Mangyung and Donajin rivers, has yielded enormous impact on the estuarine environment, both hydrodynamically and sedimentologically. Especially the inter-dyke gap in the northern Saemankeum area, 4 km wide between Yamido and Piungdo, has acted as an artificial tidal inlet. Due to such a changed geometry, tidal regime has been reversed from being flood- to ebb-dominated with a directional change from NE-SW to E-W. As a result, a large tongue-like tidal sand bar (named Saemankeum Bar) has conspicuously grown seaward through the artificial tidal inlet. The Saemankeum Bar composed of well-sorted very fine sands (3.0-3.5${\phi}$) has grown at a rate of 1.63 km/yr for the past three yews (1996-1998). Such a rapid growth of the sand bar is attributed to enhanced sediment supply derived from the degradation of former tidal sand bars at the mouth of the Mangyung River. Eventually the reworking of the tidal sand bars also caused the pre-existing tidal channels to be wider, deeper and more straightened. All of these phenomena well examplify the critical effect of artificial modifications on the natural estuarine environments.

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Effect of the Properties of Diesel Engine Oil and Aging on Exhaust Gases and DPF (경유엔진용 윤활유의 성상 및 열화가 배출가스 및 후처리 장치에 미치는 영향 연구)

  • Kim, JeongHwan;Kim, KiHo;Lee, JungMin
    • Tribology and Lubricants
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    • v.34 no.6
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    • pp.292-299
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    • 2018
  • The objective of this research is to investigate the impact of engine oil aging on PM(Particulate Matter), exhaust gases, and DPF. It is widely known that the specification of a lubricant and its consumption in an ICE considerably influences the release of regulated harmful emissions under normal engine operating conditions. Considering DPF clogging phenomena associated with lubricant-derived soot/ash components, a simulated aging mode is designed for DPF to facilitate engine dynamometer testing. A PM/ash accumulation cycle is developed by considering real-world engine operating conditions for the increment of engine oil consumption and natural DPF regeneration for ash accumulation. The test duration for DPF aging is approximately 300 h with high- and low-SAPs engine oils. Detailed engine lubricant properties of new and aged oils are analyzed to evaluate the effect of engine oil degradation on vehicle mileage. Furthermore, physical and chemical analyses are performed using X-CT, ICP, and TGA/DSC to quantify the engine oil contribution on the PM composition. This is achieved by sampling with various filters using specially designed PM sampling equipment. Using high SAPs engine oil causes more PM/ash accumulation compared with low SAPs engine oils and this could accelerate fouling of the EGR in the engine, which results in an increase in harmful exhaust gas emissions. These test results on engine lubricants under operating conditions will assist in the establishment of regulated and unregulated toxic emissions policies and lubricant quality standards.